Design and analysis of biodiesel production from algae grown through carbon sequestration

This paper addresses the design and techno-economic analysis of an integrated system for the production of biodiesel from algal oil produced via the sequestration of carbon dioxide from the flue gas of a power plant. The proposed system provides an efficient way to the reduction in greenhouse gas emissions and yields algae as a potential alternative to edible oils currently used for biodiesel production. Algae can be processed into algal oil by various pathways. The algal oil can then be used to produce biodiesel. A flowsheet of the integrated system is synthesized. Then, process simulation using ASPEN Plus is carried out to model a two-stage alkali catalyzed transesterification reaction for converting microalgal oil of Chlorella species to biodiesel. Cost estimation is carried out with the aid of ICARUS software. Further economic analysis is performed to determine profitability of the algal oil to biodiesel process. The results suggest that, for the algal oil to biodiesel process analyzed in this study, factors such as choosing the right algal species, using the appropriate pathway for converting algae to algal oil, selling the resulting biodiesel and glycerol at a favorable market selling prices, and attaining high levels of process integration can collectively render algal oil to be a competitive alternative to food-based plant oils.

[1]  Yusuf Chisti,et al.  Response to Reijnders: Do biofuels from microalgae beat biofuels from terrestrial plants? , 2008 .

[2]  Graeme A. Dunstan,et al.  Biochemical composition of microalgae from the green algal classes Chlorophyceae and Prasinophyceae. 2. Lipid classes and fatty acids , 1992 .

[3]  Ignacio E. Grossmann,et al.  A structural optimization approach in process synthesis—I: Utility systems , 1983 .

[4]  Jin-Suk Lee,et al.  CO2 fixation by Chlorella sp. KR-1 and its cultural characteristics , 1999 .

[5]  Q. Hu,et al.  Microalgal triacylglycerols as feedstocks for biofuel production: perspectives and advances. , 2008, The Plant journal : for cell and molecular biology.

[6]  Isao Karube,et al.  Tolerance of microalgae to high CO2 and high temperature , 1992 .

[7]  D. Avlonitis,et al.  Conventional and in situ transesterification of sunflower seed oil for the production of biodiesel , 2008 .

[8]  Y. Chisti Biodiesel from microalgae. , 2007, Biotechnology advances.

[9]  B. Linnhoff,et al.  The pinch design method for heat exchanger networks , 1983 .

[10]  T Leevijit,et al.  Performance test of a 6-stage continuous reactor for palm methyl ester production. , 2008, Bioresource technology.

[11]  Jane Kinkus Alternative Fuels and Advanced Vehicles Data Center , 2009 .

[12]  Y. Chisti Biodiesel from microalgae beats bioethanol. , 2008, Trends in biotechnology.

[13]  E. Belarbi,et al.  A process for high yield and scaleable recovery of high purity eicosapentaenoic acid esters from microalgae and fish oil. , 2000, Enzyme and microbial technology.

[14]  Ignacio E. Grossmann,et al.  A structural optimization approach in process synthesis. II: Heat recovery networks , 1983 .

[15]  D. Leung,et al.  Transesterification of neat and used frying oil : Optimization for biodiesel production , 2006 .

[16]  X. Miao,et al.  Biodiesel production from heterotrophic microalgal oil. , 2006, Bioresource technology.

[17]  Mahmoud M. El-Halwagi,et al.  Process analysis and optimization of biodiesel production from soybean oil , 2009 .

[18]  Samia Ashraf,et al.  Production of sunflower oil methyl esters by optimized alkali-catalyzed methanolysis. , 2008 .

[19]  L. C. Meher,et al.  Technical aspects of biodiesel production by transesterification—a review , 2006 .

[20]  Dennis P. Wiesenborn,et al.  PROCESS MODEL FOR BIODIESEL PRODUCTION FROM VARIOUS FEEDSTOCKS , 2005 .

[21]  Bodo Linnhoff,et al.  Distillation column targets , 1993 .

[22]  E. Molina Grima,et al.  Comparison between extraction of lipids and fatty acids from microalgal biomass , 1994 .

[23]  Choo Yuen May,et al.  KINETICS STUDY ON TRANSESTERIFICATION OF PALM OIL , 2004 .

[24]  Hama Otsuka CHANGES OF LIPID AND CARBOHYDRATE CONTENTS IN CHLORELLA CELLS DURING THE SULFUR STARVATION, AS STUDIED BY THE TECHNIQUE OF SYNCHRONOUS CULTURE , 1961 .

[25]  Mahmoud M. El-Halwagi,et al.  Pollution prevention through process integration , 1997 .

[26]  Pavan Kumar Meka,et al.  Synthesis of biodiesel fuel from safflower oil using various reaction parameters. , 2006, Journal of oleo science.

[27]  Mahmoud M. El-Halwagi Process Integration, Volume 7 (Process Systems Engineering) (Process Systems Engineering) , 2006 .

[28]  Lucas Reijnders,et al.  Do biofuels from microalgae beat biofuels from terrestrial plants? , 2008, Trends in biotechnology.

[29]  Farooq Anwar,et al.  Production of Biodiesel through Base-Catalyzed Transesterification of Safflower Oil Using an Optimized Protocol , 2008 .

[30]  E. Grima,et al.  Lipid extraction from the microalga Phaeodactylum tricornutum , 2007 .