Performance and Evaluation of a Fuel Cell–Thermoelectric Generator Hybrid System

A hybrid system consisting of a solid oxide fuel cell, a semiconductor thermoelectric generator and a regenerator is put forward. Expressions for the efficiencies and power outputs of the fuel cell, thermoelectric generator and hybrid system are derived. The relation between the electric currents in the fuel cell and thermoelectric generator is revealed. The maximum efficiency and power output of the hybrid system are calculated numerically. The optimally operating electric currents in the fuel cell and thermoelectric generator are calculated and consequently the optimal region of the hybrid system is determined. The results obtained here will provide some guidance for further understanding the performance and operation of practical fuel cell–thermoelectric generator hybrid systems.

[1]  G. Shen,et al.  Preparation and performance of nanostructured porous thin cathode for low-temperature solid oxide fuel cells by spin-coating method , 2008 .

[2]  Yiwu Weng,et al.  Design and Partial Load Performance of a Hybrid System Based on a Molten Carbonate Fuel Cell and a Gas Turbine , 2006 .

[3]  S. Chan,et al.  A complete polarization model of a solid oxide fuel cell and its sensitivity to the change of cell component thickness , 2001 .

[4]  Juncai Sun,et al.  Electrochemical performances of BSCF cathode materials for ceria-composite electrolyte low temperature solid oxide fuel cells , 2007 .

[5]  Abdellah El Moudni,et al.  Non-linear dynamic modeling of proton exchange membrane fuel cell , 2006 .

[6]  M. C. Williams,et al.  Solid Oxide Fuel Cells: Fundamentals to Systems , 2007 .

[7]  S. Chan,et al.  Fabrication and characterization of large-size electrolyte/anode bilayer structures for low-temperature solid oxide fuel cell stack based on gadolinia-doped ceria electrolyte , 2009 .

[8]  D. Leung,et al.  Parametric study of solid oxide fuel cell performance , 2007 .

[9]  Biao Huang,et al.  Dynamic modeling of solid oxide fuel cell: The effect of diffusion and inherent impedance , 2005 .

[10]  F. Calise,et al.  Design and partial load exergy analysis of hybrid SOFC–GT power plant , 2006 .

[11]  Chih Wu,et al.  Power optimization of an endoreversible stirling cycle with regeneration , 1994 .

[12]  Souvik Bhattacharyya,et al.  Design considerations for a power optimized regenerative endoreversible Stirling cycle , 2000 .

[13]  Ali Volkan Akkaya,et al.  A study on performance of solid oxide fuel cell‐organic Rankine cycle combined system , 2009 .

[14]  C. B. Vining,et al.  Semiconductors are cool , 2001, Nature.

[15]  Osman Sinan Süslü,et al.  On-Board Fuel Processing for a Fuel Cell−Heat Engine Hybrid System† , 2009 .

[16]  J. Van Mierlo,et al.  Fuel Cell or Battery: Electric Cars are the Future , 2007 .

[17]  Jeong L. Sohn,et al.  Performance characteristics of a solid oxide fuel cell/gas turbine hybrid system with various part-load control modes , 2007 .

[18]  S. Chan,et al.  Polarization effects in electrolyte/electrode-supported solid oxide fuel cells , 2002 .

[19]  Ferran Espiell,et al.  Low temperature anode-supported solid oxide fuel cells based on gadolinium doped ceria electrolytes , 2007 .

[20]  M.H. Nehrir,et al.  Dynamic models and model validation for PEM fuel cells using electrical circuits , 2005, IEEE Transactions on Energy Conversion.

[21]  Yingru Zhao,et al.  Modeling and optimization of a typical fuel cell-heat engine hybrid system and its parametric design criteria , 2009 .

[22]  Yingru Zhao,et al.  A new analytical approach to model and evaluate the performance of a class of irreversible fuel cells , 2008 .

[23]  Alberto Traverso,et al.  Modelling of Pressurised Hybrid Systems Based on Integrated Planar Solid Oxide Fuel Cell (IP‐SOFC) Technology , 2005 .

[24]  Ricardo Chacartegui,et al.  Stirling based fuel cell hybrid systems: An alternative for molten carbonate fuel cells , 2009 .

[25]  Bihong Lin,et al.  General Performance Characteristics and Parametric Optimum Criteria of a Braysson-Based Fuel Cell Hybrid System , 2009 .

[26]  Ali Akbar Alemrajabi,et al.  Exergy based performance analysis of a solid oxide fuel cell and steam injected gas turbine hybrid power system , 2009 .

[27]  F. Disalvo,et al.  Thermoelectric cooling and power generation , 1999, Science.

[28]  Stanley J. Watowich,et al.  Optimal current paths for model electrochemical systems , 1986 .

[29]  Brian C. Sales,et al.  Thermoelectric Materials: New Approaches to an Old Problem , 1997 .

[30]  R. Venkatasubramanian,et al.  Thin-film thermoelectric devices with high room-temperature figures of merit , 2001, Nature.

[31]  Pegah Ghanbari Bavarsad Energy and exergy analysis of internal reforming solid oxide fuel cell–gas turbine hybrid system , 2007 .

[32]  Stefano Cordiner,et al.  Analysis of a SOFC energy generation system fuelled with biomass reformate , 2007 .

[33]  D. A. Noren,et al.  Clarifying the Butler–Volmer equation and related approximations for calculating activation losses in solid oxide fuel cell models , 2005 .

[34]  Keith Scott,et al.  Power loss and its effect on fuel cell performance , 2005 .

[35]  R. Kee,et al.  A general mathematical model for analyzing the performance of fuel-cell membrane-electrode assemblies , 2003 .

[36]  Yan Ji,et al.  Effects of transport scale on heat/mass transfer and performance optimization for solid oxide fuel cells , 2006 .

[37]  K. Hassmann SOFC Power Plants, the Siemens‐Westinghouse Approach , 2001 .

[38]  Vinod M. Janardhanan,et al.  Modeling Elementary Heterogeneous Chemistry and Electrochemistry in Solid-Oxide Fuel Cells , 2005 .

[39]  Kyeongmin Oh,et al.  Analysis of the design of a pressurized SOFC hybrid system using a fixed gas turbine design , 2007 .

[40]  David A. Blank Universal power optimized work for reciprocating internally reversible Stirling-like heat engine cycles with regeneration and linear external heat transfer , 1998 .

[41]  Thameur Aloui,et al.  Analytical modeling of polarizations in a solid oxide fuel cell using biomass syngas product as fuel , 2007 .

[42]  I. Dincer,et al.  Performance comparison of two combined SOFC–gas turbine systems , 2007 .

[43]  H. Ho,et al.  Multi-level modeling of SOFC–gas turbine hybrid system , 2003 .

[44]  Dennis Y.C. Leung,et al.  An Electrochemical Model of a Solid Oxide Steam Electrolyzer for Hydrogen Production , 2006 .