The Effect of Halloysite Nanotubes as a Novel Nanofiller on Curing Behaviour, Mechanical and Microstructural Properties of Ethylene Propylene Diene Monomer (EPDM) Nanocomposites

Halloysite nanotubes (HNTs) with hollow nanotubular structures were used as a new type of filler for ethylene propylene diene monomer (EPDM) matrix. EPDM/HNT nanocomposites were prepared using a two roll mill by adding 0 to 100 parts per hundred rubber (phr) HNTs. The results show that the tensile properties were increased with the addition of HNTs. The curing time decreased from 0 to 15 phr loading but subsequently increased from 15 to 100 phr, whereas the maximum torque exhibited an increasing trend from 0 to 100 phr. The addition of HNTs reduced the tan δmax and increased the storage modulus especially for the EPDM/HNT nanocomposites at high HNT loading.

[1]  H. Ismail,et al.  Organoclay Filled Natural Rubber Nanocomposites: The Effects of Filler Loading and Mixing Method , 2008 .

[2]  Y. Mai,et al.  Microstructure and properties of highly filled rubber/clay nanocomposites prepared by melt blending , 2007 .

[3]  M. Kokabi,et al.  Shape memory and mechanical properties of cross-linked polyethylene/clay nanocomposites , 2007 .

[4]  Q. Fu,et al.  Effects of clay on phase morphology and mechanical properties in polyamide 6/EPDM-g-MA/organoclay ternary nanocomposites , 2007 .

[5]  M. Frounchi,et al.  Gas barrier properties of PP/EPDM blend nanocomposites , 2006 .

[6]  B. Guo,et al.  Thermal stability and flame retardant effects of halloysite nanotubes on poly(propylene) , 2006 .

[7]  Jian Shen,et al.  Novel preparation and properties of EPDM/montmorillonite nanocomposites , 2006 .

[8]  Bruno Delvaux,et al.  Halloysite clay minerals – a review , 2005, Clay Minerals.

[9]  Lide Zhang,et al.  Simultaneous deposition of Ni nanoparticles and wires on a tubular halloysite template: A novel metallized ceramic microstructure , 2005 .

[10]  Yudong Huang,et al.  Fabrication and physical properties of EPDM–organoclay nanocomposites , 2005 .

[11]  J. Karger‐Kocsis,et al.  Effects of primary and quaternary amine intercalants on the organoclay dispersion in a sulfur-cured EPDM rubber , 2005 .

[12]  J. Fröhlich,et al.  The effect of filler–filler and filler–elastomer interaction on rubber reinforcement , 2005 .

[13]  G. Unnikrishnan,et al.  Cure characteristics and mechanical properties of styrene–butadiene rubber/acrylonitrile butadiene rubber , 2005 .

[14]  Hua Zheng,et al.  Influence of the clay modification and compatibilizer on the structure and mechanical properties of ethylene–propylene–diene rubber/montmorillonite composites , 2004 .

[15]  Hua Zheng,et al.  Influence of clay modification on the structure and mechanical properties of EPDM/montmorillonite nanocomposites , 2004 .

[16]  D. Ratna,et al.  Clay‐reinforced epoxy nanocomposites , 2003 .

[17]  P B Deasy,et al.  Characterisation of halloysite for use as a microtubular drug delivery system. , 2002, International journal of pharmaceutics.

[18]  Makoto Kato,et al.  Preparation and properties of EPDM–clay hybrids , 2002 .

[19]  Thomas Lanzl Charakterisierung von Ruß-Kautschuk-Mischungen mittels dielektrischer Spektroskopie , 2002 .

[20]  H. J. Choi,et al.  Polypyrrole-montmorillonite nanocomposites synthesized by emulsion polymerization , 2001 .

[21]  Hanafi Ismail,et al.  Cure and tear properties of ENR 25/SMR L and ENR 50/SMR L blends , 2000 .

[22]  P. Dubois,et al.  Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials , 2000 .

[23]  H. Ismail,et al.  Palm oil fatty acid as an activator in carbon black filled natural rubber compounds: dynamic properties, curing characteristics, reversion and fatigue studies , 2000 .

[24]  K. Kuroda,et al.  Preparation of Inorganic–Organic Nanocomposites through Intercalation of Organoammonium Ions into Layered Silicates , 1997 .

[25]  Emmanuel P. Giannelis,et al.  Polymer Layered Silicate Nanocomposites , 1996 .

[26]  A. Okada,et al.  The chemistry of polymer-clay hybrids , 1995 .

[27]  Toshio Kurauchi,et al.  Synthesis of nylon 6-clay hybrid , 1993 .

[28]  T. Kurauchi,et al.  Gas permeabilities in rubber-clay hybrid , 1993 .

[29]  B. Theng,et al.  Interactions of halloysites with amides: mineralogical factors affecting complex formation , 1984, Clay Minerals.

[30]  C. Mizota,et al.  Iron-Rich Halloysite(10Å) with Crumpled Lamellar Morphology from Hokkaido, Japan , 1982 .

[31]  G. Brindley,et al.  Crystal Structures of Clay Minerals and their X-ray Identification , 1982 .

[32]  P. S. Santos,et al.  Mineralogical studies of kaolinite-halloysite clays: Part IV. A platy mineral with structural swelling and shrinking characteristics , 1966 .

[33]  Ada Swineford,et al.  Morphology and structure of endellite and halloysite , 1950 .