THE CHEMISTRY OF OPTICALLY ACTIVE SULFUR COMPOUNDS. PART IV

Abstract This paper constitutes the fourth part1a,b,c of a continuing series of reviews on the chemistry of optically active sulfur compounds. In addition to the chiral sulfur compounds described previously, five new classes of optically active sulfur compounds have been prepared: Sulfuranes; sulfodiimides, amidothiosulfites; halosulfuranes; thiabenzenes. Although intensive research continues on the various chiral sulfur compounds described thus far, the overwhelming effort has been devoted to chiral sulfur compounds derived from the penicillins and cephalosporins. It is expected that in the future these compounds will continue to constitute the single most active area of chiral sulfur research. This review covers articles published up to January 1977. Reference 1 lists general papers and review articles in this field.

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[57]  E. Roets,et al.  Isomerisation of benzyl 6-phenoxyacetoxypenicillanates and their S-oxides. , 1976, Journal of the Chemical Society. Perkin transactions 1.

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[59]  D. Jones,et al.  Steroidal sulphur compounds. Part XII. Regiospecific formation of steroidal olefins by thermolysis of sulphoxides. , 1976, Journal of the Chemical Society. Perkin transactions 1.

[60]  P. Hodge,et al.  Oxidation of some penicillins and other sulphides by use of a polymer-supported peroxy-acid. , 1976, Journal of the Chemical Society. Perkin transactions 1.

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[85]  G. Johnson,et al.  Reactions of methyl 6β phenoxyacetamidopenicillanate S and R oxides with N chloro N sodiourethane leading to new penams and cephems , 1975 .

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[90]  S. Colonna,et al.  Mechanism and stereochemistry of nucleophilic substitutions in alkoxysulphonium salts. Part II. Competitive attack at sulphur and carbon in the reaction of alkoxydiarylsulphonium salts with halide ions , 1975 .

[91]  R. J. Stoodley,et al.  Studies related to dihydro-1,4-thiazines. Part VII. Reaction of methyl (4S,6S)-5,5,9,9-tetramethyl-7-oxo-8-oxa-4-thia-1-azabicyclo-[4.3.0]non-2-ene-3-carboxylate 4-oxide with acetyl chloride , 1975 .

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[100]  G. Johnson,et al.  Conversion of secopenicillanic acid derivatives into beta-lactam sulphimides and oxazolines. , 1975, Journal of the Chemical Society. Perkin transactions 1.

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[111]  S. Campbell,et al.  The Synthesis and Reactions of Chiral Sulfonium Ylids , 1974 .

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[115]  SatoYoshiyasu,et al.  ASYMMETRIC OXIDATION OF SULFIDES TO SULFOXIDES BY N-BROMO-ε-CAPROLACTAM IN THE PRESENCE OF OPTICALLY ACTIVE ALCOHOLS , 1974 .

[116]  J. Nokami,et al.  STEREOSELECTIVE REACTIONS OF (+)-(R)-α(p-TOLYLSULFINYL)ACETOPHENONE WITH ALKYL GRIGNARD REAGENTS IN ETHYL ETHER , 1974 .

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