Development of a Photo-Acoustic Trace Gas Sensor

The work presented in this paper addresses the problem of creating a low-cost, intrinsically safe, low-level gas sensor for mining and transportation applications. The system is to have no electrical connection to the remote sensor head, and as such relies on optical transmission via fibre. An integral component is the acoustically resonant chamber, which is excited by an appropriate laser excitation. The laser is modulated at the resonant frequency of the chamber to create a periodic heating and cooling, which translates into a periodic pressure wave. The pressure wave is amplified in the resonant chamber, and then measured using an optical microphone approach. This makes the sensor implicitly safe, as there are no electronics at the sensor head nor electrical connections required. A particular challenge associated with this approach is the acoustic signal generation and extraction from very high levels of noise. This paper gives a background on the photoacoustic method, and describes our approaches to the development of physical hardware and processing algorithms required for an embedded sensor.

[1]  A. Miklós,et al.  Application of acoustic resonators in photoacoustic trace gas analysis and metrology , 2001 .

[2]  F. Harren,et al.  Automatically tunable continuous-wave optical parametric oscillator for high-resolution spectroscopy and sensitive trace-gas detection , 2006 .

[3]  J. Pelzl,et al.  Frequency dependence of resonant photoacoustic cells: The extended Helmholtz resonator , 1981 .

[4]  Impedance-optimized photo-acoustic spectroscopy , 2006 .

[5]  Vilasrao J. Kadam,et al.  Photoacoustic Spectroscopy and Its Applications – A Tutorial Review , 2010 .

[6]  Robert E. Apfel Acoustic Lumped Elements from First Principles , 2007 .

[7]  F. Karai The Analogous Acoustical Impedance for Discontinuities and Constrictions of Circular Cross Section * , 2011 .

[8]  M. Sigrist Trace gas monitoring by laser photoacoustic spectroscopy and related techniques (plenary) , 2003 .

[9]  Markus W. Sigrist,et al.  Investigation and optimisation of a multipass resonant photoacoustic cell at high absorption levels , 2005 .

[10]  M. Sigrist,et al.  Modulated resonant versus pulsed resonant photoacoustics in trace gas detection , 2009 .

[11]  Luc Thévenaz,et al.  Near-infrared laser photoacoustic detection of methane: the impact of molecular relaxation , 2006 .

[12]  Near-infrared resonant photoacoustic gas measurement using simultaneous dual-frequency excitation , 2010 .

[13]  B. V. L’vov,et al.  Atomic‐Absorption Spectrochemical Analysis , 1972 .

[14]  Thomas Schmid,et al.  Photoacoustic spectroscopy for process analysis , 2006, Analytical and bioanalytical chemistry.

[15]  M. Sigrist,et al.  Simultaneous dual-frequency excitation of a resonant photoacoustic cell , 2008 .

[16]  Stephen E. Bialkowski,et al.  Photothermal spectroscopy methods for chemical analysis , 1995 .

[17]  V. Slezak Signal processing in pulsed photoacoustic detection of traces by means of a fast Fourier transform-based method , 2003 .

[18]  M. Taheri,et al.  Design, simulation and structural optimization of a longitudinal acoustic resonator for trace gas detection using laser photoacoustic spectroscopy (LPAS) , 2010 .