Trichloroethylene Sensor by Using Electrodeposited Pb-Modified Graphite Strip Electrode

A new trichloroethylene ~TCE! sensor was developed by using a Pb-modified graphite strip electrode in an organic solution. The major factors of preparing electrode or sensing characteristics such as electrolyte concentration, electrodeposition current density, electrodeposition time, and temperature, for preparing electrodes, were explored. The results show that both the electrodeposition current density and time have a major and positive effect on the sensing reaction, while the electrodeposition temperature shows a negative effect. The best electrodeposition condition and electrolyte composition were obtained. Additionally, the optimal sensing condition is 22.10 V sensing potential ~vs. Ag/Ag

[1]  Alberto E. Cassano,et al.  Reaction engineering of suspended solid heterogeneous photocatalytic reactors , 2000 .

[2]  J. Simonet,et al.  A new electrochemically formed, iodide-modified platinum electrode usable to −3 V versus SCE in dimethylformamide. Preliminary studies of the reduction of alkyl bromides and chlorides , 2000 .

[3]  N. Pumford,et al.  Trichloroethylene accelerates an autoimmune response by Th1 T cell activation in MRL +/+ mice. , 2000, Immunopharmacology.

[4]  Franz L. Dickert,et al.  Supramolecular strategies in chemical sensing , 1999 .

[5]  I. Burgess,et al.  Electroanalytical chemistry with zeolites , 1999 .

[6]  C. Petit,et al.  Mechanism of catalytic destruction of 1,2-dichloroethane and trichloroethylene over γ-Al2O3 and γ-Al2O3 supported chromium and palladium catalysts , 1999 .

[7]  J. Bruckner,et al.  Simple method for rapid measurement of trichloroethylene and its major metabolites in biological samples. , 1999, Journal of chromatography. B, Biomedical sciences and applications.

[8]  T. Takayanagi,et al.  Rotational and vibrational energy distributions of HCl produced by three- and four-center eliminations of HCl from halogenated ethanes , 1999 .

[9]  W. Dekant,et al.  Quantitation of Nϵ-(dichloroacetyl)-l-lysine in proteins after perchloroethene exposure by gas chromatography–mass spectrometry using chemical ionization and negative ion detection following immunoaffinity chromatography , 1999 .

[10]  K. Hayes,et al.  Kinetics of the Transformation of Trichloroethylene and Tetrachloroethylene by Iron Sulfide , 1999 .

[11]  A. Cheetham,et al.  Energetics and structures of fluoro- and chlorofluorocarbons in zeolites: Force field development and Monte Carlo simulations , 1999 .

[12]  M. I. Montenegro,et al.  Effect of the medium composition on the current of steady state voltammograms of neutral and charged species in dimethylformamide/toluene mixtures , 1999 .

[13]  J. H. Dane,et al.  Movement and Remediation of Trichloroethylene in a Saturated Heterogeneous Porous Medium 1. Spill Behavior and initial dissolution , 1999 .

[14]  R. Arnold,et al.  Electrolytic oxidation of trichloroethylene using a ceramic anode , 1999 .

[15]  T. Sujatha,et al.  C-mitotic effects of trichloroethylene (TCE) on bone marrow cells of mice. , 1998, Mutation research.

[16]  M. Murabayashi,et al.  Photocatalytic degradation of trichloroethylene in the gas phase over TiO2 sol-gel films: Analysis of products , 1998 .

[17]  F. Milanovich,et al.  Novel use of a fiber-optic-based on-line trichloroethylene sensor in a column retardation experiment. , 1996, Talanta.

[18]  R. Rosset,et al.  Determination of triethylamine content in trichloroethylene by acid-base titration and open-tubular column gas chromatography , 1996 .

[19]  R. Geyer,et al.  Analysis of trichloroacetic acid in the urine of workers occupationally exposed to trichloroethylene by capillary gas chromatography. , 1995, Journal of chromatography. A.

[20]  L. Erickson,et al.  Bioenergetics and bioremediation of contaminated soil , 1995 .

[21]  A. Fry Synthetic organic electrochemistry , 1989 .

[22]  A. Bewick,et al.  Organic Electrochemistry , 1971, Nature.