An EPR Study of the Tetrafluorohydrazine‐Difluoramino Equilibrium
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The EPR spectrum of the difluoramino radical (NF2) was observed to be a single broad line at a pressure of 20–40 mm of N2F4 and a temperature of 340–435°K. The peak‐to‐peak linewidth was observed to be 104 gauss with a g value of 2.010. From the temperature dependence of the line amplitude, the ΔH of dissociation of N2F4 was calculated to be 19.3±1.0.
[1] F. A. Johnson,et al. The Tetrafluorohydrazine-Difluoroamino Radical Equilibrium1 , 1961 .
[2] L. Piette,et al. Steady‐State Studies by EPR on the Photodissociation of Some Alkyl Hydroperoxides , 1960 .
[3] W. Gordy,et al. Electron Spin Resonance Studies of Irradiated Teflon: Effects of Various Gases , 1959 .
[4] J. G. Castle,et al. Microwave Magnetic Resonance Absorption in Nitrogen Dioxide , 1950 .