Dipole Moment and Hyperfine Parameters of H35Cl and D35Cl

The molecular‐beam electric resonance spectra of H 35Cl and D 35Cl have been analyzed. The molecular constants obtained in the observed states are as follows (numbers in parentheses are the errors in the final significant figures): H35Clυ = 0, J = 1υ = 0, J = 2υ = 1, J = 1υ = 2, J = 1eqQCl(kHz)− 67 618.93(47)− 67 638.53(15)− 69 272.89(93)− 70 908.1(24)CH(kHz)− 41.80(25)− 41.68(4)− 41.09(24)− 39.94(94)CCl(kHz)+ 53.851(42)+ 53.887(14)+ 58.597(45)+ 63.68(17)μ(D)1.1085(5)1.1085(5)1.1390(10)1.1685(10)D35Clυ = 0, J = 1υ = 0, J = 2υ = 0, J = 3υ = 1, J = 1eqQD(kHz)+ 187.36(30)+ 187.0(28)+ 184.8(38)eqQCl(kHz)− 67 393.38(9)− 67 403.32(29)− 67 418.00(10)− 68 583.1(10)CD(kHz)− 3.295(46)− 3.308(80)CCl(kHz)+ 27.426(7)+ 27.430(28)+ 29.121(62)μ(D)1.1033(5)1.1033(5)1.1256(10) The above dipole moments were used in conjunction with available absolute infrared intensity measurements of vibrational bands to obtain the dipole moment function of the molecule. The derivatives with respect to the internuclear distance R, evaluate...

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