The aluminium-copper system

AbstractA critical assessment is given of the phase equilibria of the AI-Cu system. In the first section, the stable equilibrium diagram is constructed. In the second section, metastable and constrained equilibria are considered. These include metastable solvus curves of the AI-rich side of the diagram; on the Cu-rich side, transformations involving the metastable bcc phase include the order-disorder transition, metastable invariant reactions, and martensitic and massive transformation. In the third section, crystal structure and lattice-parameter data are reviewed. Finally, new calculations of selected phase equilibria are presented which are based on computer optimization of phase-diagram and thermochemical data.

[1]  R. Cahn,et al.  Metastable alloy phases by co-sputtering , 1976 .

[2]  K. Hirano,et al.  Reversion Phenomena in an Aluminium-4% Copper Alloy , 1971 .

[3]  J. Delafond,et al.  Anisotopie de la decomposition spionodale dans l'alliage Al-4% Cu observee par'diffusion centrale des rayons X , 1976 .

[4]  H. Warlimont,et al.  On the structure of 1'Cu-Al martensite , 1963 .

[5]  M. Wechsler,et al.  Neutron-irradiation effects on copper-aluminum alloys , 1958 .

[6]  H. Sato,et al.  Remarks on the structure of martensites in Cu-Al alloys , 1967 .

[7]  J. Hunt,et al.  The measurement of Al-Cu dendrite tip and eutectic interface temperatures and their use for predicting the extent of the eutectic range , 1976 .

[8]  M. Laffitte,et al.  Etude microcalorimetrique de la precipitation apres reversion dans un alliage AlCu 4 , 1974 .

[9]  H. Warlimont,et al.  The isothermal ordering of a β copper-aluminum alloy , 1962 .

[10]  J. Silcock,et al.  The θ' structure in aluminium–copper alloys , 1956 .

[11]  F. d'Heurle,et al.  2.22 The deposition by evaporation of CuAl alloy films , 1977 .

[12]  D. T. Hawkins,et al.  Selected values of the thermodynamic properties of binary alloys , 1973 .

[13]  A. Guinier,et al.  Heterogeneities in Solid Solutions , 1959 .

[14]  O. Kubaschewski,et al.  Heats of formation of transition-metal aluminides , 1960 .

[15]  J. Weertman,et al.  The internal friction of dilute alloys of lead , 1955 .

[16]  A. G. C. Gwyer über die Legierungen des Aluminiums mit Kupfer, Eisen, Nickel, Kobalt, Blei und Cadmium , 1908 .

[17]  D. K. Donald,et al.  INJECTION ELECTROLUMINESCENCE IN CdS BY TUNNELING FILMS , 1963 .

[18]  P. Ramachandrarao,et al.  A metastable phase Al3Cu2 , 1974 .

[19]  A. Yazawa,et al.  Heats of Mixing in Liquid Copper or Gold Binary Alloys , 1975 .

[20]  M. Whelan,et al.  A study of Guinier-Preston zones in aluminium-copper alloys using the weak-beam technique of electron microscopy , 1976 .

[21]  A. Varschavsky,et al.  The kinetics of disperse order development in α-cual alloys , 1983 .

[22]  J. A. Leake,et al.  The formation and decomposition of an aluminium 17.3 at.% copper solid solution , 1975 .

[23]  B. Sjöberg,et al.  Refinement of the gamma-Cu9Al4 Structure. , 1965 .

[24]  J. Cohen,et al.  The structure of GP zones in AlCu alloys , 1982 .

[25]  N. Kuwano,et al.  Period of Antiphase and Tetragonality in the α 2 Phase of Cu–Al Alloys , 1977 .

[26]  G. Weatherly,et al.  An electron microscope investigation of the interfacial structure of semi-coherent precipitates , 1968 .

[27]  S. Sanderson,et al.  A Study of the Stability of Intermediate Precipitates in an AI–4·07 wt.-%Cu Alloy Using Electrical-Resistivity Measurements , 1975 .

[28]  N. Kuwano,et al.  Formation Process of α 2 Phase in Cu–Al Alloys , 1977 .

[29]  K. Toman A note on the structure of Guinier–Preston zones in Al–Cu alloys , 1960 .

[30]  C. J. Sparks,et al.  THE SHORT-RANGE STRUCTURE OF COPPER-16 At.% ALUMINUM , 1964 .

[31]  S. Radcliffe,et al.  Electron microscopic observations of coherent boundaries in γ‐ (Cu‐Al) , 1975 .

[32]  H. Hoffmann,et al.  Crystallization of amorphous Al-Cu films , 1982 .

[33]  J. Mathews,et al.  THE ALLOYS OF ALUMINUM.1 , 1902 .

[34]  H. Warlimont,et al.  The electron-metallography and crystallography of copper-aluminum martensites , 1963 .

[35]  R. Williams Short range order structure in a copper 16 atomic percent aluminum alloy , 1974 .

[36]  G. Kostorz,et al.  Neutron small angle scattering from deformed and annealed Cu and α-phase CuAl alloy single crystals , 1979 .

[37]  L. Delaey,et al.  The long period superlattice phases obtained in tempered copper-aluminium martensite , 1972 .

[38]  Konrad Schubert,et al.  Kristallstruktur von Cu3Al2+ (h) und CuAl (r) , 1972 .

[39]  J. Popplewell,et al.  Order-strengthening in Cu−Al alloys , 1971 .

[40]  R. Kumar,et al.  Structural stability of rapidly solidified AlCu super-saturated solid solutions , 1971 .

[41]  James B. Friauf,et al.  THE CRYSTAL STRUCTURES OF TWO INTERMETALLIC COMPOUNDS , 1927 .

[42]  G. Désarmot,et al.  Observation de la precipitation d'amas de guinier-preston par decanalisation de particules α , 1980 .

[43]  M. Laffitte,et al.  Contribution a l'etude du diagramme des phases metastables dans le systeme aluminium-cuivre du cote riche en aluminium , 1975 .

[44]  V. Phillips,et al.  Lattice resolution measurement of strain fields at Guinier-Preston zones in Al-3.0% Cu , 1973 .

[45]  S. Nagakura,et al.  Structure of Al-Cu Alloy Rapidly Quenched from Liquid State and Precipitation from Enforced Solid Solution , 1968 .

[46]  A. Moreau,et al.  Analyse de clichés de diffraction électronique d'alliages CuAl par la fonction de Patterson , 1978 .

[47]  Katsuya Watanabe,et al.  Interdiffusion in the Al–Cu System , 1971 .

[48]  A. Varschavsky,et al.  An electron microscopic and diffraction study of Cu-9 wt pct Al alloy , 1975 .

[49]  A. Westerdahl,et al.  Phase Analysis at 660 degrees C of the Gamma Region of the Copper-Aluminium System. , 1965 .

[50]  G. D. Preston LXXIV. The diffraction of X-rays by an age-hardening alloy of aluminium and copper. The structure of an intermediate phase , 1938 .

[51]  S. Dahlgren Coherency stresses, composition and dislocation interactions for θ″ precipitates in age-hardened Al-Cu , 1976 .

[52]  J. C. Fisher On the strength of solid solution alloys , 1954 .

[53]  V. Gerold,et al.  The structure of G.P.I. zones in AlCu alloys , 1982 .

[54]  H. Iwasaki,et al.  Calori- and Resistometric Analyses of Ageing and Precipitation in Aluminum-Copper Alloys , 1964 .

[55]  H. Aaronson,et al.  Mechanisms of formation of θ and dissolution of θ′ precipitates in an Al-4% Cu alloy , 1966 .

[56]  W. B. Pearson,et al.  A handbook of lattice spacings and structures of metals and alloys , 1958 .

[57]  K. Toman The structure of Guinier–Preston zones. II. The room‐temperature ageing of the Al–Cu alloy , 1957 .

[58]  V. Phillips High resolution electron microscope observations on precipitation in Al-3.0% Cu alloy , 1975 .

[59]  P. Georgopoulos,et al.  The structure of G.P. I zones in Al-1.7 at.% Cu , 1981 .

[60]  R. S. Toth,et al.  Direct observation of the stacking order in β1′ Cu-Al martensite , 1967 .

[61]  K. Mills The heat capacity of Cu + Al alloys , 1977 .

[62]  N. Kuwano,et al.  Stacking Disorder and Annealing Behavior in the Heavily Deformed α 2 Phase of Cu–Al Alloys , 1980 .

[63]  S. Kajiwara,et al.  Electron Microscope Study of the Crystal Structure of the Martensite in a Copper-Aluminium Alloy , 1963 .

[64]  J. Cohen,et al.  The sequence of phase in AℓCu alloys , 1983 .

[65]  S. Seshadri,et al.  High-temperature lattice parameters of copper-aluminium alloys , 1979 .

[66]  A. Guinier Interprétation de la diffusion anormale des rayons X par les alliages à durcissement structural , 1952 .

[67]  A. Guinier Le mécanisme de la précipitation dans un cristal de solution solide métallique. - Cas des systèmes aluminium-cuivre et aluminium-argent , 1942 .

[68]  E. Matsubara,et al.  Local atomic arrangements in the solid solution Al-1.7 at.% Cu, at 793 K , 1983 .

[69]  R. Rioja,et al.  The early stages of GP zone formation in naturally aged Ai-4 wt pct cu alloys , 1977 .

[70]  A. Varschavsky Differential Scanning Calorimetry Evaluations in αCu-Al Alloys, Energetics , 1982 .

[71]  J. Guillot,et al.  Structure des zones de guinier et preston dans un alliage d'aluminium-cuivre , 1973 .

[72]  M. Hansen,et al.  Constitution of Binary Alloys , 1958 .

[73]  J. B. Hull,et al.  An amorphous pahse in a splat-quenched A1-17.3 at %Cu alloy , 1972 .

[74]  C. Pedersen,et al.  A Redetermination of the Distribution of Atoms in Cu5Zn8, Cu5Cd8, and Cu9Al4. , 1968 .

[75]  D. Cheetham,et al.  Interfacial enthalpy in eutectoid copper aluminium pearlite , 1975 .

[76]  J. Hunt,et al.  Cellular and dendritic growth. I , 1974 .

[77]  G. Weatherly Antiphase domain boundaries in ordered θ' (CuAl2) precipitates in an Al-4% Cu alloy , 1970 .

[78]  W. Hume-rothery,et al.  The lattice spacings of solid solutions of different elements in aluminium , 1948, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.

[79]  R. Mehl,et al.  The free energy of formation and the interfacial enthalpy in pearlite , 1958 .

[80]  W. Cochran,et al.  The structures of pyrimidines and purines. I. A determination of the structures of 2‐amino‐4‐methyl‐6‐chloropyrimidine and 2‐amino‐4,6‐dichloropyrimidine by X‐ray methods , 1948 .

[81]  A. J. Perkins,et al.  Extension of solid solubility during massive transformations , 1972 .

[82]  S. Matsuo,et al.  Short range order in copper-aluminium alloys , 1963 .

[83]  G. D. Preston The diffraction of X-rays by age-hardening aluminium copper alloys. , 1938, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.