The Dynamics of Three-Phase Triple Junction and Contact Points

We use the method of matched asymptotic expansions to study the sharp interface limit of the three-phase system modeled by the Cahn--Hilliard equations with the relaxation boundary condition. The dynamic laws for the interfaces, the triple junction, and the contact points are derived at different time scales. In particular, we show, at $O(t)$ time scale, the dynamic of the triple junction is determined by the balance of the chemical potential gradient along the three interfaces meeting at the triple junction. At faster time scale $O(\epsilon t)$, the motion of the triple junction is controlled by the contact point motions and geometric constraints.

[1]  Harald Garcke,et al.  A singular limit for a system of degenerate Cahn-Hilliard equations , 2000, Advances in Differential Equations.

[2]  Edward Bormashenko,et al.  The rigorous derivation of Young, Cassie–Baxter and Wenzel equations and the analysis of the contact angle hysteresis phenomenon , 2008 .

[3]  Qian Zhang,et al.  Phase field modeling and simulation of three-phase flow on solid surfaces , 2016, J. Comput. Phys..

[4]  Franck Boyer,et al.  Study of a three component Cahn-Hilliard flow model , 2006 .

[5]  Thomas Young,et al.  An Essay on the Cohesion of Fluids , 1800 .

[6]  Shibin Dai,et al.  Weak Solutions for the Cahn–Hilliard Equation with Degenerate Mobility , 2016 .

[7]  R. V. KoRN On three-phase boundary motion and the singular limit of a vector-valued Ginzburg-Landau equation , 2004 .

[8]  Ping Sheng,et al.  Molecular scale contact line hydrodynamics of immiscible flows. , 2003, Physical review. E, Statistical, nonlinear, and soft matter physics.

[9]  J. E. Hilliard,et al.  Free Energy of a Nonuniform System. I. Interfacial Free Energy , 1958 .

[10]  Robert L. Pego,et al.  Front migration in the nonlinear Cahn-Hilliard equation , 1989, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[11]  Irena Pawlow,et al.  A mathematical model of dynamics of non-isothermal phase separation , 1992 .

[12]  J. Keller,et al.  Fast reaction, slow diffusion, and curve shortening , 1989 .

[13]  Qiang Du,et al.  Motion of Interfaces Governed by the Cahn-Hilliard Equation with Highly Disparate Diffusion Mobility , 2012, SIAM J. Appl. Math..

[14]  Qiang Du,et al.  Coarsening Mechanism for Systems Governed by the Cahn-Hilliard Equation with Degenerate Diffusion Mobility , 2014, Multiscale Model. Simul..

[15]  Ping Sheng,et al.  Power-law slip profile of the moving contact line in two-phase immiscible flows. , 2004, Physical review letters.

[16]  David J. Eyre,et al.  Systems of Cahn-Hilliard Equations , 1993, SIAM J. Appl. Math..

[17]  Harald Garcke,et al.  Diffusional phase transitions in multicomponent systems with a concentration dependent mobility matrix , 1997 .

[18]  Xianmin Xu,et al.  Analysis of the Cahn–Hilliard Equation with a Relaxation Boundary Condition Modeling the Contact Angle Dynamics , 2014, Archive for Rational Mechanics and Analysis.

[19]  C. M. Elliott,et al.  On the Cahn-Hilliard equation with degenerate mobility , 1996 .

[20]  Xianmin Xu,et al.  Analysis of Wetting and Contact Angle Hysteresis on Chemically Patterned Surfaces , 2011, SIAM J. Appl. Math..

[21]  Qiang Du,et al.  Computational studies of coarsening rates for the Cahn-Hilliard equation with phase-dependent diffusion mobility , 2016, J. Comput. Phys..

[22]  J. Rubinstein,et al.  Minimizers and gradient flows for singularly perturbed bi-stable potentials with a Dirichlet condition , 1990, Proceedings of the Royal Society of London. A. Mathematical and Physical Sciences.

[23]  Amy Novick-Cohen,et al.  Triple-junction motion for an Allen-Cahn/Cahn-Hilliard system , 2000 .

[24]  J. Cahn,et al.  Evolution equations for phase separation and ordering in binary alloys , 1994 .

[25]  Ping Sheng,et al.  Moving contact line on chemically patterned surfaces , 2008, Journal of Fluid Mechanics.

[26]  Martin Z Bazant,et al.  Theory of chemical kinetics and charge transfer based on nonequilibrium thermodynamics. , 2012, Accounts of chemical research.

[27]  E. Bruce Nauman,et al.  Nonlinear diffusion and phase separation , 2001 .