Enhanced performance of ZnO piezotronic pressure sensor through electron-tunneling modulation of MgO nanolayer.

Piezoelectric materials can be applied into electromechanical conversion and attract extensive attention with potential applications in various sensors. Here, we present two types of piezotronic pressure sensors based on ZnO nanoarrays. By introducing an insulating MgO (i-MgO) nanolayer, the "on/off" current ratio of the sensor is significantly improved up to 10(5). Furthermore, the sensor shows a high sensitivity of 7.1 × 10(4) gf(-1), a fast response time of 128 ms. The excellent properties are attributed to the combination of piezoelectric effect of ZnO nanoarrays and electron-tunneling modulation of MgO nanolayer, and the reversible potential barrier height controlled by piezoelectric potential. We further investigate the service behavior of the sensor, which can detect force varying from 3.2 to 27.2 gf. Our research provides a promising approach to boost the performance of nanodevices.

[1]  Markus Mohr,et al.  Flexible piezoelectric nanogenerators based on a fiber/ZnO nanowires/paper hybrid structure for energy harvesting , 2014, Nano Research.

[2]  B. Shirinzadeh,et al.  A wearable and highly sensitive pressure sensor with ultrathin gold nanowires , 2014, Nature Communications.

[3]  Zhong Lin Wang Piezotronic and Piezophototronic Effects , 2010 .

[4]  Pei Lin,et al.  Enhanced photoresponse of Cu2O/ZnO heterojunction with piezo-modulated interface engineering , 2014, Nano Research.

[5]  Gustavo Ardila,et al.  Performance Optimization of Vertical Nanowire‐based Piezoelectric Nanogenerators , 2013 .

[6]  Yue Zhang,et al.  Size effect in a cantilevered ZnO micro/nanowire and its potential as a performance tunable force sensor , 2013 .

[7]  Lars Samuelson,et al.  Tunnel field-effect transistors based on InP-GaAs heterostructure nanowires. , 2012, ACS nano.

[8]  Yue Zhang,et al.  A highly sensitive electrochemical biosensor based on zinc oxide nanotetrapods for L-lactic acid detection. , 2012, Nanoscale.

[9]  Z. Mei,et al.  Controlled Growth of High‐Quality ZnO‐Based Films and Fabrication of Visible‐Blind and Solar‐Blind Ultra‐Violet Detectors , 2009 .

[10]  Sung-hoon Ahn,et al.  A flexible and highly sensitive strain-gauge sensor using reversible interlocking of nanofibres. , 2012, Nature materials.

[11]  X. Bai,et al.  In situ transmission electron microscopy investigation on fatigue behavior of single ZnO wires under high-cycle strain. , 2014, Nano letters (Print).

[12]  S. T. Picraux,et al.  Axial SiGe heteronanowire tunneling field-effect transistors. , 2012, Nano letters.

[13]  Jinhui Song,et al.  ZnO-ZnS heterojunction and ZnS nanowire arrays for electricity generation. , 2009, ACS nano.

[14]  Keith Worden,et al.  An introduction to structural health monitoring , 2007, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences.

[15]  Jun Zhou,et al.  High‐Strain Sensors Based on ZnO Nanowire/Polystyrene Hybridized Flexible Films , 2011, Advanced materials.

[16]  A Fukushima,et al.  Highly sensitive nanoscale spin-torque diode. , 2014, Nature materials.

[17]  Ming-Yen Lu,et al.  Fabrication of a High-Brightness BlueLight-Emitting Diode Using a ZnO-Nanowire Array Grown on p-GaN Thin Film C A T IO , 2009 .

[18]  Vikas Berry,et al.  Electron-tunneling modulation in percolating network of graphene quantum dots: fabrication, phenomenological understanding, and humidity/pressure sensing applications. , 2013, Nano letters.

[19]  Ananth Dodabalapur,et al.  High-speed, inkjet-printed carbon nanotube/zinc tin oxide hybrid complementary ring oscillators. , 2014, Nano letters.

[20]  Youfan Hu,et al.  Designing the electric transport characteristics of ZnO micro/nanowire devices by coupling piezoelectric and photoexcitation effects. , 2010, ACS nano.

[21]  Pooi See Lee,et al.  Highly Stretchable Piezoresistive Graphene–Nanocellulose Nanopaper for Strain Sensors , 2014, Advanced materials.

[22]  Zhong Lin Wang,et al.  Piezoelectric-potential-controlled polarity-reversible Schottky diodes and switches of ZnO wires. , 2008, Nano letters.

[23]  Qibing Pei,et al.  Elastomeric transparent capacitive sensors based on an interpenetrating composite of silver nanowires and polyurethane , 2013 .

[24]  Markus Mohr,et al.  Carbon fiber-ZnO nanowire hybrid structures for flexible and adaptable strain sensors. , 2013, Nanoscale.

[25]  B. Tell,et al.  Raman Effect in Zinc Oxide , 1966 .

[26]  W. C. Walker,et al.  Electronic spectrum and ultraviolet optical properties of crystalline MgO. , 1967 .

[27]  I. Park,et al.  Highly stretchable and sensitive strain sensor based on silver nanowire-elastomer nanocomposite. , 2014, ACS nano.

[28]  A. Javey,et al.  Highly sensitive electronic whiskers based on patterned carbon nanotube and silver nanoparticle composite films , 2014, Proceedings of the National Academy of Sciences.

[29]  Zhong Lin Wang,et al.  Enhanced performance of GaN nanobelt-based photodetectors by means of piezotronic effects , 2013, Nano Research.

[30]  Pei Lin,et al.  Self-powered UV photosensor based on PEDOT:PSS/ZnO micro/nanowire with strain-modulated photoresponse. , 2013, ACS applied materials & interfaces.

[31]  Zhong Lin Wang,et al.  Piezoelectric Nanogenerators Based on Zinc Oxide Nanowire Arrays , 2006, Science.

[32]  Pei Lin,et al.  Functional nanogenerators as vibration sensors enhanced by piezotronic effects , 2014, Nano Research.

[33]  Wen Guo,et al.  Size dependence of dielectric constant in a single pencil-like ZnO nanowire. , 2012, Nano letters.

[34]  L. Ressier,et al.  High-sensitivity strain gauge based on a single wire of gold nanoparticles fabricated by stop-and-go convective self-assembly. , 2011, ACS nano.

[35]  Yonggang Huang,et al.  High performance piezoelectric devices based on aligned arrays of nanofibers of poly(vinylidenefluoride-co-trifluoroethylene) , 2013, Nature Communications.

[36]  G. Heiland,et al.  Electronic Processes in Zinc Oxide , 1959 .

[37]  S. Yao,et al.  Wearable multifunctional sensors using printed stretchable conductors made of silver nanowires. , 2014, Nanoscale.

[38]  Qingliang Liao,et al.  Scanning Probe Study on the Piezotronic Effect in ZnO Nanomaterials and Nanodevices , 2012, Advanced materials.

[39]  Zhong Lin Wang,et al.  Piezotronic effect enhanced Schottky-contact ZnO micro/nanowire humidity sensors , 2014, Nano Research.

[40]  M. Armstrong,et al.  Evaluating the performance of nanostructured materials as lithium-ion battery electrodes , 2013, Nano Research.

[41]  Yan Zhang,et al.  Piezo-phototronics effect on nano/microwire solar cells , 2012 .

[42]  Long Lin,et al.  Strain-gated piezotronic transistors based on vertical zinc oxide nanowires. , 2012, ACS nano.

[43]  K. Hata,et al.  A stretchable carbon nanotube strain sensor for human-motion detection. , 2011, Nature nanotechnology.