Development of Highly Repellent Silica Particles for Protection of Hemp Shiv Used as Insulation Materials

New bio-materials have recently gained interest for use in insulation panels in walls, but wider adoption by the building industry is hindered by their intrinsic properties. The fact that such materials are mainly composed of cellulose makes them combustible, and their hydrophilic surface presents a high water uptake, which would lead to faster biodegradation. A hydrophobic treatment with silica particles was successfully synthesised via Stöber process, characterised, and deposited on hemp shiv. The surface of hemp shiv coated several times with 45 and 120 nm particles were uniformly covered, as well as extensively water repellent. Those samples could withstand in humidity chamber without loss of their hydrophobic property and no sign of mould growth after 72 h of exposure.

[1]  Chih-Yuan Hsu,et al.  A novel approach of chemical functionalization on nano-scaled silica particles , 2003 .

[2]  B. Givoni,et al.  A life-cycle energy and carbon analysis of hemp-lime bio-composite building materials , 2017 .

[3]  Michel J M Ebskamp,et al.  Engineering flax and hemp for an alternative to cotton. , 2002, Trends in biotechnology.

[4]  T. Barder,et al.  Controlled Growth of Monodisperse Silica Spheres in the Micron Size Range , 2017 .

[5]  F. Pacheco-Torgal,et al.  Cementitious building materials reinforced with vegetable fibres : a review , 2011 .

[6]  Laurent Arnaud,et al.  Acoustical properties of materials made of vegetable particles with several scales of porosity , 2011 .

[7]  E. Gourlay,et al.  Experimental study of parameters influencing mechanical properties of hemp concretes , 2012 .

[8]  Azra Korjenic,et al.  Development and performance evaluation of natural thermal-insulation materials composed of renewable resources , 2011 .

[9]  A. Evrard,et al.  Hygrothermal Performance of Lime-Hemp Wall Assemblies , 2010 .

[10]  Michèle Queneudec,et al.  Coating of a lignocellulosic aggregate with pectin/polyethylenimin mixtures: Effects on flax shive and cement-shive composite properties , 2012 .

[11]  Etienne Wurtz,et al.  Study of a hempcrete wall exposed to outdoor climate: Effects of the coating , 2017 .

[12]  G. Escadeillas,et al.  Use of plant aggregates in building ecomaterials , 2012 .

[13]  J. Hilborn,et al.  Surface-initiated ring-opening polymerization: A versatile method for nanoparticle ordering. , 2002 .

[14]  R. Kuisma,et al.  WETTING AND WICKING OF FIBRE PLANT STRAW FRACTIONS , 2003 .

[15]  N. Leblanc,et al.  Nouvelles agroressources pour panneaux de particules 100% biosourcés , 2014 .

[16]  A. Sjöberg,et al.  Flax and hemp fibres as raw materials for thermal insulations , 2008 .

[17]  Juliana Calabria-Holley,et al.  Hydrophobicity of Hemp Shiv treated with Sol-gel Coatings , 2018 .

[18]  Raphael M. Ottenbrite,et al.  Surface modification of inorganic oxide particles with silane coupling agent and organic dyes , 2001 .

[19]  M. Vignon,et al.  Steam explosion of woody hemp chènevotte. , 1995, International journal of biological macromolecules.

[20]  M. Nykter MICROBIAL QUALITY OF HEMP (Cannabis sativa L.) AND FLAX (Linum usitatissimum L.) FROM PLANTS TO THERMAL INSULATION , 2006 .

[21]  Peter Walker,et al.  Hygrothermal Performance of an Experimental Hemp-Lime Building , 2012 .

[22]  G. Rizzo,et al.  Thermal and structural properties of a hemp–lime biocomposite , 2013 .

[23]  S. Guessasma,et al.  Microstructure and mechanical performance of modified hemp fibre and shiv mortars: Discovering the optimal formulation , 2015 .

[24]  E. Hirst Characterisation of hemp-line as a composite building material , 2013 .

[25]  Etienne Wurtz,et al.  Transient hygrothermal behaviour of a hemp concrete building envelope , 2010 .

[26]  P. Magusin,et al.  Surface modification of oxidic nanoparticles using 3-methacryloxypropyltrimethoxysilane. , 2004, Journal of colloid and interface science.

[27]  L. T. Zhuravlev Surface characterization of amorphous silica—a review of work from the former USSR , 1993 .