Nanocrystal Photovoltaic Paint Sprayed With a Handheld Airbrush

A complete photovoltaic cell was fabricated using only a handheld airbrush, dilute solutions of CdSe and CdTe nanorods, commercially available silver paint, and transparent-conducting-electrode-coated glass. Produced and stored under ambient conditions, these fully functioning solar cells are stable for months. As a heterojunction cell, the migration of carriers within the CdTe and CdSe layers is polarity-dependent, which directly contributes to the photoinduced voltaic cell response observed. The suitability of a handheld airbrush to create high-quality films by varying solution concentration, air pressure, and nanorod surface functionalization was explored. Notably, ultrasmooth surfaces comparable to spin-coated quality films can be formed from 20 to 500 nm thickness, with continuous, uninterrupted optical domains such that strong light diffraction is observed. While current estimated efficiency is low (<0.01%), this method demonstrates the potential of solar cells that can be incorporated into a variety of devices of unconventional size or design.

[1]  D. Schulz,et al.  CdTe Thin Films from Nanoparticle Precursors by Spray Deposition , 1997 .

[2]  N. E. Coates,et al.  Efficient Tandem Polymer Solar Cells Fabricated by All-Solution Processing , 2007, Science.

[3]  Tobias Vossmeyer,et al.  CdS Nanoclusters: Synthesis, Characterization, Size Dependent Oscillator Strength, Temperature Shift of the Excitonic Transition Energy, and Reversible Absorbance Shift , 1994 .

[4]  Juhwan Kim,et al.  Fabrication of organic bulk heterojunction solar cells by a spray deposition method for low-cost power generation , 2007 .

[5]  Matt Law,et al.  Structural, optical, and electrical properties of self-assembled films of PbSe nanocrystals treated with 1,2-ethanedithiol. , 2008, ACS nano.

[6]  Xiaogang Peng Mechanisms for the Shape‐Control and Shape‐Evolution of Colloidal Semiconductor Nanocrystals , 2003 .

[7]  F. Krebs,et al.  Lifetimes of organic photovoltaics: Using TOF-SIMS and 18O2 isotopic labelling to characterise chemical degradation mechanisms , 2006 .

[8]  Garry Rumbles,et al.  Performance of bulk heterojunction photovoltaic devices prepared by airbrush spray deposition , 2008 .

[9]  K. Teng,et al.  Application of ink jet technology on photovoltaic metallization , 1988, IEEE Electron Device Letters.

[10]  Liberato Manna,et al.  Synthesis of Soluble and Processable Rod-, Arrow-, Teardrop-, and Tetrapod-Shaped CdSe Nanocrystals , 2000 .

[11]  Shuichi Kinoshita,et al.  Structural colors in nature: the role of regularity and irregularity in the structure. , 2005, Chemphyschem : a European journal of chemical physics and physical chemistry.

[12]  Frederik C. Krebs,et al.  A brief history of the development of organic and polymeric photovoltaics , 2004 .

[13]  A. Alivisatos,et al.  Controlling the Morphology of Nanocrystal–Polymer Composites for Solar Cells , 2003 .

[14]  G. Konstantatos,et al.  Solution-processed PbS quantum dot infrared photodetectors and photovoltaics , 2005, Nature materials.

[15]  A Paul Alivisatos,et al.  Air-Stable All-Inorganic Nanocrystal Solar Cells Processed from Solution , 2005, Science.

[16]  A. Alivisatos,et al.  Controlled assembly of hybrid bulk-heterojunction solar cells by sequential deposition. , 2006, The journal of physical chemistry. B.

[17]  A Paul Alivisatos,et al.  Hybrid solar cells with prescribed nanoscale morphologies based on hyperbranched semiconductor nanocrystals. , 2007, Nano letters.

[18]  A. Alivisatos,et al.  Hybrid Nanorod-Polymer Solar Cells , 2002, Science.

[19]  Weidong Yang,et al.  Shape control of CdSe nanocrystals , 2000, Nature.