Tetraethylammonium bis(benzene-1,2-dithiolato)(2-disulfanylbenzenethiolato)niobate
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The title compound, (C8H20N)[Nb(C6H4S2)2(C6H4S3)], is the major product of the reaction of (Et4N)4[Nb2S4(NCS)8] and disodium benzene-1,2-dithiolate. The coordination environment of the Nb atom contains seven S atoms, viz. four S atoms from two benzene-1,2-dithiolate ligands and three S atoms from 2-disulfanylbenzenethiolate. The Nb—S distances are in the range 2.4391 (6)–2.5932 (7) A.
[1] V. Fedorov,et al. Nb2S44+ Complexes with 1,1-Dithioacid Ligands , 1994 .