Perovskite oxides: New candidate materials for low work function electron emitters

Perovskite oxides are promising materials for a new class of electron emitting materials because they possess intrinsically low work functions without the need for an additional surface dipole coating. Density Functional Theory (DFT) was used to examine a series of LaBO3 (B=transition metal) perovskites, and it was found that LaVO3 exhibited the lowest work function of 1.52 eV.

[1]  D. Morgan,et al.  Ab initio investigation of barium-scandium-oxygen coatings on tungsten for electron emitting cathodes , 2010 .

[2]  P. A. Duine,et al.  A model system for scandate cathodes , 1997 .

[3]  Kresse,et al.  Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set. , 1996, Physical review. B, Condensed matter.

[4]  J. Hubbard Electron correlations in narrow energy bands , 1963, Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences.