Heterogeneous Catalysis for Tandem Reactions

Financial support by Consolider-Ingenio 2010 (project MULTICAT), Spanish MICINN (Projects MAT2011-28009 and CTQ-2011-27550) and Program Severo Ochoa are gratefully acknowledged.

[1]  T. Tatsumi,et al.  Dealuminated Beta zeolite as effective bifunctional catalyst for direct transformation of glucose to 5-hydroxymethylfurfural , 2014 .

[2]  Yao Fu,et al.  Hydrolysis of cellulose to glucose by solid acid catalysts , 2013 .

[3]  G. Busca.  Acid catalysts in industrial hydrocarbon chemistry. , 2007, Chemical reviews.

[4]  G. Busca,et al.  Selective saccharides dehydration to 5-hydroxymethyl-2-furaldehyde by heterogeneous niobium catalysts , 1999 .

[5]  A. Corma,et al.  One pot catalytic conversion of cellulose into biodegradable surfactants. , 2010, Chemical communications.

[6]  A. Corma,et al.  AlITQ-6 and TiITQ-6: Synthesis, Characterization, and Catalytic Activity We thank the Spanish CICYT for financial support (project MAT97-1016-C02-01 and project MAT97-1207-C03-01). U.D. and M.E.D. thank the M.E.C. and M.E.A., respectively, for funding their doctoral fellowships. , 2000, Angewandte Chemie.

[7]  Horst Surburg,et al.  Common fragrance and flavor materials , 1985 .

[8]  M. Antonietti,et al.  Transfer hydrogenation of levulinic acid under hydrothermal conditions catalyzed by sulfate as a temperature-switchable base , 2010 .

[9]  D. D. De Vos,et al.  Hydrotalcite-like anionic clays in catalytic organic reactions , 2001 .

[10]  A. Corma,et al.  Chemical routes for the transformation of biomass into chemicals. , 2007, Chemical reviews.

[11]  Shusheng Pang,et al.  Ionic liquids and their interaction with cellulose. , 2009, Chemical reviews.

[12]  W. Fabian,et al.  Effects of conformation, substituents and solvent on molecular hyperpolarizabilities of push–pull diaryl-alkenes and -dienes: a computational study , 1995 .

[13]  Michael O’Keeffe,et al.  Exceptional chemical and thermal stability of zeolitic imidazolate frameworks , 2006, Proceedings of the National Academy of Sciences.

[14]  J. Lunsford,et al.  The oxidative dehydrogenation of ethane over chlorine-promoted lithium-magnesium oxide catalysts , 1991 .

[15]  Philip S. Yu,et al.  Aliphatic propargylamines: New antiapoptotic drugs , 1997 .

[16]  K. Wada,et al.  A Novel Production of γ-Butyrolactone Catalyzed by Ruthenium Complexes , 2000 .

[17]  E. Derouane.  Catalysts for Fine Chemical Synthesis: Microporous and Mesoporous Solid Catalysts , 2006 .

[18]  D. T. Mowry.  The Knoevenagel Condensation of Aryl Alkyl Ketones with Malononitrile , 1945 .

[19]  Yuriy Román-Leshkov,et al.  Domino reaction catalyzed by zeolites with Brønsted and Lewis acid sites for the production of γ-valerolactone from furfural. , 2013, Angewandte Chemie.

[20]  Y. Mutoh,et al.  Synthesis of tertiary propargylamines by sequential reactions of in situ generated thioiminium salts with organolithium and -magnesium reagents. , 2004, Journal of the American Chemical Society.

[21]  T. Tatsumi,et al.  A novel titanosilicate with MWW structure: III. Highly efficient and selective production of glycidol through epoxidation of allyl alcohol with H2O2 , 2003 .

[22]  J. Mayoral,et al.  Shift of multiple incompatible equilibriums by a combination of heterogeneous catalysis and membranes. , 2010, Chemistry.

[23]  J. R. Ochoa-Gómez,et al.  Synthesis of glycerol 1,2-carbonate by transesterification of glycerol with dimethyl carbonate using triethylamine as a facile separable homogeneous catalyst , 2012 .

[24]  Avelino Corma,et al.  Inorganic Solid Acids and Their Use in Acid-Catalyzed Hydrocarbon Reactions , 1995 .

[25]  Dmitry Yu. Murzin,et al.  Catalytic Deoxygenation of Fatty Acids and Their Derivatives , 2007 .

[26]  Zhenshan Hou,et al.  Polyoxometalate-Based Solid and Liquid Salts for Catalysis , 2009 .

[27]  I. E. Maxwell,et al.  Recent process- and catalyst-related developments in fluid catalytic cracking , 1990 .

[28]  Michael Renz,et al.  Ketonization of Carboxylic Acids by Decarboxylation: Mechanism and Scope , 2005 .

[29]  A. Corma,et al.  Large pore bifunctional titanium–aluminosilicates: the inorganic non-enzymatic version of the epoxidase conversion of linalool to cyclic ethers , 1995 .

[30]  G. Hutchings,et al.  Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO2 Catalysts , 2006, Science.

[31]  Kimoon Kim,et al.  Tandem catalysis with a bifunctional site-isolated Lewis acid-Brønsted base metal-organic framework, NH2-MIL-101(Al). , 2012, Chemical communications.

[32]  Manuel Moliner,et al.  "One-pot" synthesis of 5-(Hydroxymethyl)furfural from carbohydrates using tin-Beta zeolite , 2011 .

[33]  A. Corma,et al.  Homogeneous and heterogeneous catalysts for multicomponent reactions , 2012 .

[34]  Gerard Avignon,et al.  Dehydration of fructose to 5-hydroxymethylfurfural over H-mordenites , 1996 .

[35]  M. Boudart,et al.  Turnover Rates in Heterogeneous Catalysis , 1995 .

[36]  N. R. Shiju,et al.  Mesoporous Silica with Site-Isolated Amine and Phosphotungstic Acid Groups: A Solid Catalyst with Tunable Antagonistic Functions for One-Pot Tandem Reactions** , 2011, Angewandte Chemie.

[37]  Michalina Bickford,et al.  Concise Encyclopedia of Chemical Technology , 1999 .

[38]  H. V. Bekkum,et al.  Stereoselective Meerwein–Ponndorf–Verley and Oppenauer reactions catalysed by zeolite BEA , 1997 .

[39]  S. Yin,et al.  A mini-review on solid superbase catalysts developed in the past two decades , 2013 .

[40]  Karlheinz Hill,et al.  Alkyl Polyglycosides-Properties and Applications of a new Class of Surfactants. , 1998, Angewandte Chemie.

[41]  A. Corma,et al.  Coupling fatty acids by ketonic decarboxylation using solid catalysts for the direct production of diesel, lubricants, and chemicals. , 2008, ChemSusChem.

[42]  Manuel Moliner,et al.  Mechanism of glucose isomerization using a solid Lewis acid catalyst in water. , 2010, Angewandte Chemie.

[43]  Jean-Paul Lange,et al.  Valeric biofuels: a platform of cellulosic transportation fuels. , 2010, Angewandte Chemie.

[44]  V. Mamedov,et al.  Quinoxaline-benzimidazole rearrangements in the reactions of 3-alkanoylquinoxalin-2-ones with 1,2-phenylenediamines , 2007 .

[45]  A. Corma,et al.  Direct Synthesis and Characterization of Hydrophobic Aluminum-Free Ti−Beta Zeolite , 1998 .

[46]  A. Corma,et al.  Supported gold(III) catalysts for highly efficient three-component coupling reactions. , 2008, Angewandte Chemie.

[47]  Shainaz M. Landge,et al.  Microwave-assisted solid acid-catalyzed one-pot synthesis of isobenzofuran-1(3H)-ones , 2008 .

[48]  B. Wilkinson,et al.  Biosynthesis of Erythromycin and Rapamycin. , 1997, Chemical reviews.

[49]  A. Vaccari,et al.  Chromium-free catalysts for selective vapor phase hydrogenation of maleic anhydride to γ-butyrolactone , 1996 .

[50]  Pallab Pahari,et al.  Regiospecific synthesis of isopestacin, a naturally occurring isobenzofuranone antioxidant , 2004 .

[51]  Avelino Corma,et al.  Heterogeneous catalysts for the one-pot synthesis of chemicals and fine chemicals. , 2011, Chemical reviews.

[52]  M. Messori,et al.  Reaction Pathway in Vapor Phase Hydrogenation of Maleic Anhydride and Its Esters to γ-Butyrolactone , 1994 .

[53]  Y. Iwasawa,et al.  Layered materials with coexisting acidic and basic sites for catalytic one-pot reaction sequences. , 2009, Journal of the American Chemical Society.

[54]  F. Kapteijn,et al.  Synthesis and Characterization of an Amino Functionalized MIL-101(Al): Separation and Catalytic Properties , 2011 .

[55]  Guangxing Li,et al.  One-pot synthesis of glycidol from glycerol and dimethyl carbonate over a highly efficient and easily available solid catalyst NaAlO2 , 2013 .

[56]  B. Kuster,et al.  The influence of the initial and catalyst concentrations on the dehydration of d-fructose , 1977 .

[57]  B. W. Lew,et al.  Physical and functional properties of some higher alkyl polyglucosides , 1970, Journal of the American Oil Chemists' Society.

[58]  A. Corma,et al.  “Nafion”-functionalized mesoporous MCM-41 silica shows high activity and selectivity for carboxylic acid esterification and Friedel–Crafts acylation reactions , 2005 .

[59]  U. R. Pillai,et al.  Selective hydrogenation of maleic anhydride to gamma-butyrolactone over Pd/Al2O3 catalyst using supercritical CO2 as solvent. , 2002, Chemical communications.

[60]  M. Arai,et al.  Simultaneous application of two or more supported liquid-phase organometallic catalysts: heterogeneous multifunctional reaction systems , 2003 .

[61]  István T. Horváth,et al.  γ-Valerolactone—a sustainable liquid for energy and carbon-based chemicals , 2008 .

[62]  G. Emig,et al.  Reaction kinetics of the liquid-phase hydrogenation of succinic anhydride on CuZnO-catalysts with varying copper-to-zinc ratios in a three-phase slurry reactor , 2002 .

[63]  A. Corma,et al.  Designing bifunctional acid–base mesoporous hybrid catalysts for cascade reactions , 2013 .

[64]  M. Harmer,et al.  Solid acid catalysis using ion-exchange resins , 2001 .

[65]  Atsushi Takagaki,et al.  A one-pot reaction for biorefinery: combination of solid acid and base catalysts for direct production of 5-hydroxymethylfurfural from saccharides. , 2009, Chemical communications.

[66]  G. Bellussi,et al.  Production of titanium containing molecular sieves and their application in catalysis , 2001 .

[67]  Angelo Vaccari,et al.  Preparation and catalytic properties of cationic and anionic clays , 1998 .

[68]  J. Valyon,et al.  Activation of Hydrogen and Hexane over Pt,H-Mordenite Hydroisomerization Catalysts , 2009 .

[69]  Hero J. Heeres,et al.  Combined dehydration/(transfer)-hydrogenation of C6-sugars (D-glucose and D-fructose) to γ-valerolactone using ruthenium catalysts , 2009 .

[70]  A. Corma,et al.  Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. , 2006, Chemical reviews.

[71]  Michikazu Hara,et al.  Hydrolysis of cellulose by amorphous carbon bearing SO3H, COOH, and OH groups. , 2008, Journal of the American Chemical Society.

[72]  J. Safari,et al.  A rapid and efficient method for synthesis of new 3-arylideneisobenzofuran-1(3H)-one derivatives catalyzed by acetic anhydride under solvent-free and microwave conditions , 2007 .

[73]  J. Elguero,et al.  New Bis(chalcones) and Their Transformation into Bis(pyrazoline) and Bis(pyrazole) Derivatives , 2003 .

[74]  A. Corma,et al.  Sn-zeolite beta as a heterogeneous chemoselective catalyst for Baeyer–Villiger oxidations , 2001, Nature.

[75]  V. B. Kumbhar,et al.  One‐Pot Synthesis of 3‐Phenacylphthalides , 2005 .

[76]  H. Freeman,et al.  Colour chemistry : the design and synthesis of organic dyes and pigments , 1991 .

[77]  A. Corma,et al.  Gold and gold–platinum as active and selective catalyst for biomass conversion: Synthesis of γ-butyrolactone and one-pot synthesis of pyrrolidone , 2008 .

[78]  A. Corma,et al.  Synthesis of structured porous polymers with acid and basic sites and their catalytic application in cascade-type reactions , 2013 .

[79]  R. Gorte,et al.  Methods for Characterizing Zeolite Acidity , 1995 .

[80]  Avelino Corma,et al.  Catalysis using multifunctional organosiliceous hybrid materials. , 2013, Chemical Society reviews.

[81]  A. Corma,et al.  Chemoselective synthesis of substituted imines, secondary amines, and beta-amino carbonyl compounds from nitroaromatics through cascade reactions on gold catalysts. , 2009, Chemistry.

[82]  N. Zhukova,et al.  A reaction for the synthesis of benzimidazoles and 1H-imidazo[4,5-b]pyridines via a novel rearrangement of quinoxalinones and their aza-analogues when exposed to 1,2-arylenediamines , 2010 .

[84]  G. Huber,et al.  Production of furfural and carboxylic acids from waste aqueous hemicellulose solutions from the pulp and paper and cellulosic ethanol industries , 2011 .

[85]  A. Corma,et al.  Engineering metal organic frameworks for heterogeneous catalysis. , 2010, Chemical reviews.

[86]  Vincenzo Calemma,et al.  Hydroisomerization and hydrocracking of long chain n-alkanes on Pt/amorphous SiO2–Al2O3 catalyst , 2000 .

[87]  S. Jung,et al.  Liquid-phase hydrogenation of maleic anhydride over Pd–Sn/SiO2 , 2003 .

[88]  A. Corma,et al.  Bifunctional Metal Organic Framework Catalysts for Multistep Reactions: MOF‐Cu(BTC)‐[Pd] Catalyst for One‐Pot Heteroannulation of Acetylenic Compounds , 2012 .

[89]  G. Chuah,et al.  Stereoselective cascade hydrogenation of 4-tert-butylphenol and p-cresol over Zr-zeolite beta-supported rhodium , 2007 .

[90]  A. Corma,et al.  Chemicals from biomass: Synthesis of glycerol carbonate by transesterification and carbonylation with urea with hydrotalcite catalysts. The role of acid–base pairs , 2010 .

[91]  A. Corma,et al.  Aluminophosphates Oxynitrides as Base Catalysts: Nature of the Base Sites and Their Catalytic Implications , 1996 .

[92]  A. Corma,et al.  Beta Zeolite as a Catalyst for the Preparation of Alkyl Glucoside Surfactants: The Role of Crystal Size and Hydrophobicity , 1997 .

[93]  G. Seifert,et al.  Enumeration of not-yet-synthesized zeolitic zinc imidazolate MOF networks: a topological and DFT approach. , 2008, The journal of physical chemistry. B.

[94]  Pallab Pahari,et al.  Regiospecific synthesis of 3-(2,6-dihydroxyphenyl)phthalides : application to the synthesis of isopestacin and cryphonectric acid , 2007 .

[95]  M. Jung,et al.  Use of optically active cyclic N,N-dialkyl aminals in asymmetric induction. , 2000, Organic letters.

[96]  R. M. Hanson.  The synthetic methodology of nonracemic glycidol and related 2,3-epoxy alcohols , 1991 .

[97]  M. Malacria,et al.  Chemoselective catalysis with organosoluble Lewis acidic polyoxotungstates. , 2010, Chemistry.

[98]  Zongbao K. Zhao,et al.  Efficient Acid-Catalyzed Hydrolysis of Cellulose in Ionic Liquid , 2007 .

[99]  A. Corma,et al.  MgO nanoparticle-based multifunctional catalysts in the cascade reaction allows the green synthesis of anti-inflammatory agents , 2007 .

[100]  A. Corma,et al.  Multifunctional hybrid organic-inorganic catalytic materials with a hierarchical system of well-defined micro- and mesopores. , 2010, Journal of the American Chemical Society.

[101]  Mark E. Davis,et al.  Design of heterogeneous catalysts via multiple active site positioning in organic-inorganic hybrid materials. , 2003, Journal of the American Chemical Society.

[102]  J. Weitkamp,et al.  Base catalysis on microporous and mesoporous materials: recent progress and perspectives , 2001 .

[103]  D. M. Alonso,et al.  Catalytic conversion of biomass to biofuels , 2010 .

[104]  Carlos A. Henao,et al.  Production of liquid hydrocarbon fuels by catalytic conversion of biomass-derived levulinic acid , 2011 .

[105]  A. Corma,et al.  Water Resistant, Catalytically Active Nb and Ta Isolated Lewis Acid Sites, Homogeneously Distributed by Direct Synthesis in a Beta Zeolite , 2009 .

[106]  E. Novellino,et al.  2-(Benzimidazol-2-yl)quinoxalines: a novel class of selective antagonists at human A(1) and A(3) adenosine receptors designed by 3D database searching. , 2005, Journal of medicinal chemistry.

[107]  A. Corma,et al.  Coupling of two multistep catalytic cycles for the one-pot synthesis of propargylamines from alcohols and primary amines on a nanoparticulated gold catalyst. , 2012, Chemistry.

[108]  J. C. Hernández,et al.  Biomass into chemicals: One-pot two- and three-step synthesis of quinoxalines from biomass-derived glycols and 1,2-dinitrobenzene derivatives using supported gold nanoparticles as catalysts , 2012 .

[109]  G. Kramer,et al.  Reactivity Theory of Zeolitic Broensted Acidic Sites , 1995 .

[110]  R. Mülhaupt,et al.  Hyperbranched Polyether Polyols: A Modular Approach to Complex Polymer Architectures , 2000 .

[111]  A. Corma,et al.  Al-free Sn-Beta zeolite as a catalyst for the selective reduction of carbonyl compounds (Meerwein-Ponndorf-Verley reaction). , 2002, Journal of the American Chemical Society.

[112]  W. Ried,et al.  Über heterocyclische Siebenringsysteme, V. Umsetzung von o‐Phenylendiamin mit α,β‐Ungesättigten Carbonylverbindungen , 1957 .

[113]  T. Baba,et al.  Selective reactions over solid base catalysts , 1997 .

[114]  V. Ballabeni,et al.  1,5-benzodiazepines. Part XIII. Substituted 4H-[1,2,4]triazolo[4,3-a][1,5]benzodiazepin-5-amines and 4H-imidazo[1,2-a][1,5]benzodiazepin-5-amines as analgesic, anti-inflammatory and/or antipyretic agents with low acute toxicity. , 2002, European journal of medicinal chemistry.

[115]  K. Venkataraman.  The chemistry of synthetic dyes , 1952 .

[116]  H. Hattori.  Heterogeneous Basic Catalysis , 1995 .

[117]  C. Buttersack.  Accessibility and catalytic activity of sulfonic acid ion-exchange resins in different solvents☆ , 1989 .

[118]  A. Corma,et al.  Ketonic decarboxylation reaction mechanism: a combined experimental and DFT study. , 2013, ChemSusChem.

[119]  A. Corma,et al.  Synthesis of the Ti-Silicate Form of BEC Polymorph of β-Zeolite Assisted by Molecular Modeling , 2008 .

[120]  W. Fabian,et al.  Syntheses with nitriles. Part 97: Push-Pull diarylbutadienes and diarylpentadienes: Known chromophores—New facts☆ , 1995 .

[121]  D. Vos,et al.  Metal–Organic Frameworks as Catalysts for Organic Reactions , 2011 .

[122]  A. Corma,et al.  Gold-Catalyzed Synthesis of Aromatic Azo Compounds from Anilines and Nitroaromatics , 2008, Science.

[123]  Regina Palkovits,et al.  Development of heterogeneous catalysts for the conversion of levulinic acid to γ-valerolactone. , 2012, ChemSusChem.

[124]  Avelino Corma,et al.  Synthesis of an ultralarge pore titanium silicate isomorphous to MCM-41 and its application as a catalyst for selective oxidation of hydrocarbons , 1994 .

[125]  R. Schultes.  Common Fragrance and Flavor Materials: Preparation, Properties and Uses , 1987, Economic Botany.

[126]  Manuel Moliner,et al.  Tin-containing zeolites are highly active catalysts for the isomerization of glucose in water , 2010, Proceedings of the National Academy of Sciences.

[127]  P. Leadlay,et al.  Combinatorial approaches to polyketide biosynthesis. , 1997, Current opinion in chemical biology.

[128]  C. Townsend.  Structural studies of natural product biosynthetic proteins. , 1997, Chemistry & biology.

[129]  J. Dumesic,et al.  Mechanocatalytic Depolymerization of Dry (Ligno)cellulose As an Entry Process for High-Yield Production of Furfurals , 2013 .

[130]  C. Khosla.  Harnessing the Biosynthetic Potential of Modular Polyketide Synthases. , 1997, Chemical reviews.

[131]  A. Corma,et al.  New one-pot multistep process with multifunctional catalysts: decreasing the E factor in the synthesis of fine chemicals , 2010 .

[132]  Dong Wang,et al.  Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels , 2010, Science.

[133]  Ken Motokura,et al.  An acidic layered clay is combined with a basic layered clay for one-pot sequential reactions. , 2005, Journal of the American Chemical Society.

[134]  J. Büchs,et al.  An integrated catalytic approach to fermentable sugars from cellulose. , 2010, ChemSusChem.

[135]  A. Wagner,et al.  A one-pot synthesis of (E)-disubstituted alkenes by a bimetallic [Rh-Pd]-catalyzed hydrosilylation/hiyama cross-coupling sequence. , 2007, Chemistry.

[136]  M. Miura,et al.  Copper-Catalyzed Reaction of Terminal Alkynes with Nitrones. Selective Synthesis of 1-Aza-1-buten-3-yne and 2-Azetidinone Derivatives , 1995 .

[137]  Robin D. Rogers,et al.  Dissolution of Cellose with Ionic Liquids , 2002 .

[138]  A. Corma,et al.  A general method for the preparation of ethers using water-resistant solid lewis acids. , 2007, Angewandte Chemie.

[139]  K. Tatsuta,et al.  Synthesis and glycosidase inhibitory activities of nagstatin triazole analogs. , 1996, The Journal of antibiotics.

[140]  A. Corma,et al.  Zeolites as base catalysts: Condensation of aldehydes with derivatives of malonic esters , 1990 .

[141]  A. Corma,et al.  Water-resistant solid Lewis acid catalysts: Meerwein–Ponndorf–Verley and Oppenauer reactions catalyzed by tin-beta zeolite , 2003 .

[142]  A. Corma,et al.  Gold Catalysis Opens Up a New Route for the Synthesis of Benzimidazoylquinoxaline Derivatives from Biomass‐Derived Products (Glycerol) , 2013 .

[143]  Qiuyun Zhang,et al.  Solid Acid-Base Bifunctional Catalysts in Organic Transformations , 2013 .

[144]  Mark E. Davis,et al.  Beyond shape selective catalysis with zeolites: Hydrophobic void spaces in zeolites enable catalysis in liquid water , 2013 .

[145]  Regina Palkovits,et al.  Depolymerization of cellulose using solid catalysts in ionic liquids. , 2008, Angewandte Chemie.

[146]  Mark E. Davis,et al.  Hydroformylation by supported aqueous-phase catalysis: a new class of heterogeneous catalysts , 1989, Nature.

[147]  A. Corma,et al.  Transforming nonselective into chemoselective metal catalysts for the hydrogenation of substituted nitroaromatics. , 2008, Journal of the American Chemical Society.

[148]  Joseph J. Bozell,et al.  Connecting Biomass and Petroleum Processing with a Chemical Bridge , 2010, Science.

[149]  V. Rane,et al.  Synthesis of glycidol from glycerol and dimethyl carbonate using ionic liquid as a catalyst , 2012 .

[150]  James A. Dumesic,et al.  Gamma-valerolactone, a sustainable platform molecule derived from lignocellulosic biomass , 2013 .

[151]  E. De Clercq,et al.  1,2,3-Triazole-[2',5'-bis-O-(tert-butyldimethylsilyl)-beta-D- ribofuranosyl]-3'-spiro-5"-(4"-amino-1",2"-oxathiole 2",2"-dioxide) (TSAO) analogues: synthesis and anti-HIV-1 activity. , 1994, Journal of medicinal chemistry.

[152]  Carlos A. Henao,et al.  A sulfuric acid management strategy for the production of liquid hydrocarbon fuels via catalytic conversion of biomass-derived levulinic acid , 2012 .

[153]  Joel Morris,et al.  Substituent effects on the antibacterial activity of nitrogen-carbon-linked (azolylphenyl)oxazolidinones with expanded activity against the fastidious gram-negative organisms Haemophilus influenzae and Moraxella catarrhalis. , 2000, Journal of medicinal chemistry.

[154]  T. Tatsumi,et al.  Extremely high trans selectivity of Ti-MWW in epoxidation of alkenes with hydrogen peroxide , 2001 .

[155]  E. Sastre,et al.  Influence of the alkyl chain length of HSO3-R-MCM-41 on the esterification of glycerol with fatty acids , 2005 .

[156]  G. Emig,et al.  Liquid-Phase Hydrogenation of Maleic-Anhydride and Intermediates on Copper-Based and Noble-Metal Catalysts , 1997 .

[157]  A. Corma,et al.  Bifunctional acid-base ionic liquid organocatalysts with a controlled distance between acid and base sites. , 2010, Chemistry.

[158]  C. Zhou,et al.  Catalytic conversion of lignocellulosic biomass to fine chemicals and fuels. , 2011, Chemical Society reviews.

[159]  Avelino Corma,et al.  From Microporous to Mesoporous Molecular Sieve Materials and Their Use in Catalysis. , 1997, Chemical reviews.

[160]  J. Clardy,et al.  The cytosporones, new octaketide antibiotics isolated from an endophytic fungus. , 2000, Organic letters.

[161]  M. Bañares,et al.  New concepts for process intensification in the conversion of glycerol carbonate to glycidol , 2013 .

[162]  G. Chuah,et al.  Zirconia catalysts in Meerwein-Ponndorf-Verley reduction of citral , 2004 .

[163]  Fabrizio Cavani,et al.  Hydrotalcite-type anionic clays: Preparation, properties and applications. , 1991 .

[164]  A. Corma,et al.  A different reaction pathway for the reduction of aromatic nitro compounds on gold catalysts. , 2007, Angewandte Chemie.

[165]  L. Gaster,et al.  4-(6-Methoxy-2-naphthyl)butan-2-one and related analogues, a novel structural class of antiinflammatory compounds. , 1978, Journal of medicinal chemistry.

[166]  G. Chuah,et al.  Chemo- and regioselective Meerwein–Ponndorf–Verley and Oppenauer reactions catalyzed by Al-free Zr-zeolite beta , 2004 .

[167]  W. Ried,et al.  Über heterocyclische Siebenringsysteme, X. Synthesen kondensierter 5-, 7- und 8-gliedriger Heterocyclen mit 2 Stickstoffatomen , 1959 .

[168]  A. Corma,et al.  Chemoselective Hydrogenation of Nitro Compounds with Supported Gold Catalysts , 2006, Science.

[169]  H. Takaya,et al.  Ruthenium-Catalyzed Reactions for Organic Synthesis. , 1998, Chemical reviews.

[170]  M. Pagliaro,et al.  From glycerol to value-added products. , 2007, Angewandte Chemie.

[171]  A. Corma,et al.  Mechanism of the Meerwein-Ponndorf-Verley-Oppenauer (MPVO) redox equilibrium on Sn- and Zr-beta zeolite catalysts. , 2006, The journal of physical chemistry. B.

[172]  Ferdi Schüth,et al.  Solvent-free catalytic depolymerization of cellulose to water-soluble oligosaccharides. , 2012, ChemSusChem.

[173]  A. Wagner,et al.  Polyionic gels: efficient heterogeneous media for metal scavenging and catalysis. , 2006, Angewandte Chemie.

[174]  Yuriy Román‐Leshkov,et al.  Production of dimethylfuran for liquid fuels from biomass-derived carbohydrates , 2007, Nature.

[175]  Jean-Paul Lange,et al.  Conversion of furfuryl alcohol into ethyl levulinate using solid acid catalysts. , 2009, ChemSusChem.