Aging behavior of the localization length in a colloidal glass

Abstract The localization length rloc associated with a fast secondary relaxation in glassy Laponite is determined by X-ray photon correlation spectroscopy (XPCS) through a Debye–Waller fit of the non-ergodicity parameter. Quantitative differences are observed between the time dependence (aging) of rloc in spontaneously aged and rejuvenated samples. This behavior is also reflected in the calculated shear modulus which matches well with data obtained by rheological measurements.

[1]  Dudley W. Thompson,et al.  The nature of laponite and its aqueous dispersions , 1992 .

[2]  Michael Sprung,et al.  Beyond simple exponential correlation functions and equilibrium dynamics in x-ray photon correlation spectroscopy , 2010 .

[3]  J. Harden,et al.  Aging processes and scale dependence in soft glassy colloidal suspensions. , 2003, Physical review. E, Statistical, nonlinear, and soft matter physics.

[4]  Hongyu Guo,et al.  Connecting nanoscale motion and rheology of gel-forming colloidal suspensions. , 2010, Physical review. E, Statistical, nonlinear, and soft matter physics.

[5]  F. Sciortino,et al.  Observation of empty liquids and equilibrium gels in a colloidal clay. , 2010, Nature materials.

[6]  Galina Yatsenko,et al.  Collisions, caging, thermodynamics, and jamming in the barrier hopping theory of glassy hard sphere fluids. , 2007, The Journal of chemical physics.

[7]  J. Munch,et al.  Diagram of the aging dynamics in laponite suspensions at low ionic strength. , 2006, Physical review. E, Statistical, nonlinear, and soft matter physics.

[8]  G. Ruocco,et al.  Competing interactions in arrested States of colloidal clays. , 2010, Physical review letters.

[9]  Evolution of particle-scale dynamics in an aging clay suspension. , 2004, Physical review letters.

[10]  Slow, nondiffusive dynamics in concentrated nanoemulsions. , 2007, Physical review. E, Statistical, nonlinear, and soft matter physics.

[11]  M. Springborg Electronic properties, stability, and length scales of clusters , 1999 .

[12]  W. Gotze,et al.  Relaxation processes in supercooled liquids , 1992 .

[13]  Wolfgang Götze,et al.  REVIEW ARTICLE: Recent tests of the mode-coupling theory for glassy dynamics , 1999 .

[14]  E. Zaccarelli Colloidal gels: equilibrium and non-equilibrium routes , 2007, 0705.3418.

[15]  Robert L. Leheny,et al.  XPCS: Nanoscale motion and rheology , 2012 .

[16]  L Cipelletti,et al.  Atomic-scale relaxation dynamics and aging in a metallic glass probed by x-ray photon correlation spectroscopy. , 2012, Physical review letters.

[17]  J. Tanaka,et al.  Aging of a colloidal “Wigner” glass , 1999 .

[18]  J. Dhont,et al.  Experimental Phase Diagram of a Binary Colloidal Hard-Sphere Mixture with a Large Size Ratio. , 1995, Physical review letters.

[19]  D A Weitz,et al.  Universal aging features in the restructuring of fractal colloidal gels. , 2000, Physical review letters.

[20]  Irreversible aging dynamics and generic phase behavior of aqueous suspensions of Laponite. , 2010, Langmuir : the ACS journal of surfaces and colloids.

[21]  P. Pusey,et al.  Phase behaviour of concentrated suspensions of nearly hard colloidal spheres , 1986, Nature.

[22]  Giancarlo Ruocco,et al.  Dichotomic aging behaviour in a colloidal glass , 2013, 2308.14425.

[23]  S. Manley,et al.  Universal non-diffusive slow dynamics in aging soft matter. , 2003, Faraday discussions.

[24]  E. Zaccarelli,et al.  A fresh look at the Laponite phase diagram , 2011 .

[25]  D. Weitz,et al.  Gelation of particles with short-range attraction , 2008, Nature.

[26]  P. Levitz,et al.  Probing the Morphology of Laponite Clay Colloids by Atomic Force Microscopy , 2003 .

[27]  R. Sprik,et al.  Dynamic light scattering studies on the sol-gel transition of a suspension of anisotropic colloidal particles. , 1996, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics.