A method for creating reliable and low-resistance contacts between carbon nanotubes and microelectrodes

An ultrasonic bonding technique has been developed for bonding single wall carbon nanotubes (SWNTs) onto metal microelectrodes. The bonding was formed by pressing SWNTs against the electrodes with a vibrating press at an ultrasonic frequency. With this technology, low-resistance contacts are achieved between both metallic and semiconducting SWNTs and electrodes. After bonding, the effective Schottky barrier height between semiconducting SWNT and Ti electrode is as low as ∼6.6 meV in the ON-state and the barrier width is ∼0.9 nm at Vg = 0. The performance of carbon nanotube field-effect transistors (FETs) fabricated by this ultrasonic bonding technique is also significantly improved, with a transconductance as high as 3.4 μS for solid-state back-gate individual nanotube FETs.

[1]  Jinhee Kim,et al.  Formation of low-resistance ohmic contacts between carbon nanotube and metal electrodes by a rapid thermal annealing method , 2000 .

[2]  T. Ebbesen Carbon Nanotubes: Past, Present and Future , 1996 .

[3]  Jingqi Li,et al.  Fabrication of carbon nanotube field effect transistors by AC dielectrophoresis method , 2004 .

[4]  Saraswati,et al.  Characterisation of intermetallic growth in copper and gold ball bonds on aluminium metallization , 2004, Proceedings of 6th Electronics Packaging Technology Conference (EPTC 2004) (IEEE Cat. No.04EX971).

[5]  Christoph Strunk,et al.  Contacting carbon nanotubes selectively with low-ohmic contacts for four-probe electric measurements , 1998 .

[6]  Supriyo Datta,et al.  A simple, reliable technique for making electrical contact to multiwalled carbon nanotubes , 1999 .

[7]  Kai Xiao,et al.  n-Type field-effect transistors made of an individual nitrogen-doped multiwalled carbon nanotube. , 2005, Journal of the American Chemical Society.

[8]  S. Tans,et al.  Room-temperature transistor based on a single carbon nanotube , 1998, Nature.

[9]  S. Wind,et al.  Carbon nanotube electronics , 2002, Digest. International Electron Devices Meeting,.

[10]  P. Ajayan,et al.  Reliability and current carrying capacity of carbon nanotubes , 2001 .

[11]  C. D. Breach,et al.  New observations on intermetallic compound formation in gold ball bonds: general growth patterns and identification of two forms of Au4Al , 2004, Microelectron. Reliab..

[12]  Changxin Chen,et al.  Manipulation of single-wall carbon nanotubes into dispersively aligned arrays between metal electrodes , 2006 .

[13]  H. Dai,et al.  Can we achieve ultra-low resistivity in carbon nanotube-based metal composites? , 2004 .

[14]  Peter Bøggild,et al.  Soldering of nanotubes onto microelectrodes , 2003 .

[15]  C. Dekker,et al.  Logic Circuits with Carbon Nanotube Transistors , 2001, Science.

[16]  W. Hoenlein,et al.  In-Situ Contacted Single-Walled Carbon Nanotubes and Contact Improvement by Electroless Deposition , 2003 .

[17]  G. Harman Wire Bonding in Microelectronics: Materials, Processes, Reliability, and Yield , 1997 .

[18]  A. Javey Carbon Nanotube Field-Effect Transistors , 2009 .

[19]  S. Datta,et al.  Coupling of Carbon Nanotubes to Metallic Contacts , 1999, cond-mat/9907357.

[20]  Qian Wang,et al.  Ballistic Transport in Metallic Nanotubes with Reliable Pd Ohmic Contacts , 2003 .

[21]  Fabrication of single electron transistors in multi-wall carbon nanotubes using Ar beam irradiation , 2003 .

[22]  Sumio Iijima,et al.  Heterostructures of Single-Walled Carbon Nanotubes and Carbide Nanorods. , 1999 .

[23]  Yung-Cheng Lee,et al.  Studies of thermosonic bonding for flip-chip assembly , 1995 .

[24]  Richard Martel,et al.  Controlling doping and carrier injection in carbon nanotube transistors , 2002 .

[25]  Herbert Shea,et al.  Single- and multi-wall carbon nanotube field-effect transistors , 1998 .

[26]  Qian Wang,et al.  Carbon Nanotube Transistor Arrays for Multistage Complementary Logic and Ring Oscillators , 2002, Nano Letters.

[27]  Phaedon Avouris Carbon nanotube electronics , 2002 .

[28]  H. Henisch Metal-semiconductor Schottky barrier junctions and their applications , 1986, Proceedings of the IEEE.

[29]  Jing Guo,et al.  Carbon Nanotube Field-Effect Transistors with Integrated Ohmic Contacts and High-κ Gate Dielectrics , 2004 .

[30]  J. Tersoff Contact resistance of carbon nanotubes , 1999 .

[31]  M. Radosavljevic,et al.  Carbon nanotubes as potential building blocks for future nanoelectronics , 2002 .

[32]  K. Ng,et al.  The Physics of Semiconductor Devices , 2019, Springer Proceedings in Physics.

[33]  C Lavoie,et al.  Ambipolar electrical transport in semiconducting single-wall carbon nanotubes. , 2001, Physical review letters.

[34]  Alexey Bezryadin,et al.  MULTIPROBE TRANSPORT EXPERIMENTS ON INDIVIDUAL SINGLE-WALL CARBON NANOTUBES , 1998 .

[35]  A. Rinzler,et al.  Single Wall Carbon Nanotubes for p-Type Ohmic Contacts to GaN Light-Emitting Diodes , 2004 .

[36]  Klaus Kern,et al.  Room Temperature Single Electron Transistor by Local Chemical Modification of Carbon Nanotubes , 2002 .