Simulating CO2 Storage in Deep Saline Aquifers

This chapter presents the results of compositional reservoir simulation of a prototypical CO 2 storage project in a deep saline aquifer. The objective of the investigation was to better understand and quantify estimates of the most important CO 2 storage mechanisms under realistic physical conditions. Simulations of a few decades of CO 2 injection followed by 10 3 -10 5 years of natural gradient flow were done. The impact of several parameters was reviewed, including average permeability, the ratio of vertical to horizontal permeability, residual gas saturation, salinity, temperature, aquifer dip angle, permeability heterogeneity and mineralization. The storage of CO 2 in residual gas emerges as a potentially very significant issue meriting further study. Under some circumstances this form of immobile storage can be larger than storage in brine and minerals.

[1]  T. P. Wellman,et al.  Evaluation of CO2-Brine-Reservoir Rock Interaction with Laboratory Flow Tests and Reactive Transport Modeling , 2003 .

[2]  W. Wagner,et al.  The IAPWS Formulation 1995 for the Thermodynamic Properties of Ordinary Water Substance for General and Scientific Use , 2002 .

[3]  Ho Teng,et al.  Solubility of Liquid CO2 in Synthetic Sea Water at Temperatures from 278 K to 293 K and Pressures from 6.44 MPa to 29.49 MPa, and Densities of the Corresponding Aqueous Solutions , 1998 .

[4]  Lincoln Paterson,et al.  Role of Convective Mixing in the Long-Term Storage of Carbon Dioxide in Deep Saline Formations , 2003 .

[5]  L. Lake,et al.  Enhanced Oil Recovery , 2017 .

[6]  C. Doughty,et al.  Modeling supercritical CO2 injection in heterogeneous porous media , 2003 .

[7]  N. D. Nevers,et al.  Partial molal volume of carbon dioxide in water solutions , 1969 .

[8]  Karsten Pruess,et al.  CO2-H2O mixtures in the geological sequestration of CO2. I. Assessment and calculation of mutual solubilities from 12 to 100°C and up to 600 bar , 2003 .

[9]  D. H. Bacon,et al.  STEAM TABLES IN SI UNITS , 1973 .

[10]  K. Pruess,et al.  Analysis of mineral trapping for CO2 disposal in deep aquifers , 2001 .

[11]  H. Teng,et al.  Solubility of liquid CO2in water at temperatures from 278 K to 293 K and pressures from 6.44 MPa to 29.49 MPa and densities of the corresponding aqueous solutions , 1997 .

[12]  Julio E. Garcia Density of aqueous solutions of CO2 , 2001 .

[13]  K. Pruess,et al.  Numerical Modeling of Aquifer Disposal of CO2 , 2003 .

[14]  B. Rumpf,et al.  Solubility of carbon dioxide in aqueous solutions of sodium chloride: Experimental results and correlation , 1994 .

[15]  L. Nghiem,et al.  Phase equilibria of oil, gas and water/brine mixtures from a cubic equation of state and henry's law , 1986 .

[16]  Mark H. Holtz,et al.  Residual Gas Saturation to Aquifer Influx: A Calculation Method for 3-D Computer Reservoir Model Construction , 2002 .

[17]  R. Bodnar,et al.  Densities of NaCl(aq) to the temperature 523 K at pressures to 40 MPa measured with a new vibrating-tube densitometer , 1994 .

[18]  V. Majer,et al.  Volumes of aqueous solutions of CH4, CO2, H2S and NH3at temperatures from 298.15 K to 705 K and pressures to 35 MPa , 1996 .

[19]  Ivan Dmitrievich Zaĭt︠s︡ev,et al.  Properties of Aqueous Solutions of Electrolytes , 1992 .

[20]  K. Aziz,et al.  EOS predictions of compressibility and phase behavior in systems containing water, hydrocarbons, and CO2 , 1988 .

[21]  Stefan Bachu,et al.  Aquifer disposal of CO2: Hydrodynamic and mineral trapping , 1994 .

[22]  W. Gunter,et al.  Aquifer disposal of CO2-rich greenhouse gases: Extension of the time scale of experiment for CO2-sequestering reactions by geochemical modelling , 1997 .