Sustainable metal catalysis in CH activation
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G. Vougioukalakis | Nikolaos V. Tzouras | Ioannis Stamatopoulos | Argyro T. Papastavrou | Aggeliki A. Liori | Georgios C. Vougioukalakis | Ioannis Stamatopoulos | A. Liori
[1] M. M. Díaz‐Requejo,et al. Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp(2) )-H Bonds by Carbene Insertion. , 2016, Angewandte Chemie.
[2] Changsheng Yao,et al. One-pot solvent-free synthesis of quinolines by C–H activation/C–C Bond formation catalyzed by recyclable iron(III) triflate , 2012 .
[3] K. Mochida,et al. Activation of C-H bonds of heterocyclic and alicyclic compounds using calcium atoms. , 1987 .
[4] Yugen Zhang,et al. Copper catalysed alkynylation of tertiary amines with CaC2via sp3 C–H activation , 2016 .
[5] P. Macfaul,et al. THE ROLE OF ALKOXYL RADICALS IN GIF (GOAGGV) CHEMISTRY , 1996 .
[6] J. Mascareñas,et al. Metal-Catalyzed Annulations through Activation and Cleavage of C-H Bonds. , 2016, Angewandte Chemie.
[7] A. Chan,et al. Copper(I)-catalyzed enantioselective alkynylation of α-imino esters: ligand-to-metal ratio effects and mechanistic studies , 2010 .
[8] Shunsuke Murahashi. SYNTHESIS OF PHTHALIMIDINES FROM SCHIFF BASES AND CARBON MONOXIDE , 1955 .
[9] E. Nakamura,et al. Iron‐Catalyzed Directed Alkylation of Alkenes and Arenes with Alkylzinc Halides , 2015 .
[10] S. W. Youn,et al. Activation : A Complementary Tool in the Total Synthesis of Complex Natural Products , 2012 .
[11] T. Cundari,et al. Reaction of Cu(I) with dialkyl peroxides: Cu(II)-alkoxides, alkoxy radicals, and catalytic C-H etherification. , 2012, Journal of the American Chemical Society.
[12] A. Borovik. Role of metal-oxo complexes in the cleavage of C-H bonds. , 2011, Chemical Society reviews.
[13] Su Jin Kwon,et al. Organo- and Organometallic-Catalytic Intramolecular [1,5]-Hydride Transfer/Cyclization Process through C(sp(3) )-H Bond Activation. , 2016, Chemical record.
[14] E. Manoni,et al. Manganese-Catalyzed C-H Alkynylation: Expedient Peptide Synthesis and Modification. , 2017, Angewandte Chemie.
[15] Jin‐Pei Cheng,et al. The Essential Role of Bond Energetics in C-H Activation/Functionalization. , 2017, Chemical reviews.
[16] D. Doller,et al. The selective functionalization of saturated hydrocarbons: Gif chemistry , 1992 .
[17] Alison E Wendlandt,et al. Copper-catalyzed aerobic oxidative C-H functionalizations: trends and mechanistic insights. , 2011, Angewandte Chemie.
[18] U. Schuchardt,et al. Gif chemistry: new evidence for a non-radical process , 2001 .
[19] T. Hatanaka,et al. C-H bond activation/borylation of furans and thiophenes catalyzed by a half-sandwich iron N-heterocyclic carbene complex. , 2010, Chemistry, an Asian journal.
[20] Chen Zhang,et al. Catalytic enantioselective intramolecular redox reactions: ring-fused tetrahydroquinolines. , 2009, Journal of the American Chemical Society.
[21] Cong-Hui Wang,et al. Manganese-catalyzed dehydrogenative [4+2] annulation of N-H imines and alkynes by C-H/N-H activation. , 2014, Angewandte Chemie.
[22] Zhengxing Wu,et al. Copper-catalyzed C-H functionalization reactions: efficient synthesis of heterocycles. , 2015, Chemical reviews.
[23] B. Mahoney,et al. Trimethylsilyl trifluoromethanesulfonate-accelerated addition of catalytically generated zinc acetylides to aldehydes. , 2009, The Journal of organic chemistry.
[24] C. Vanderwal,et al. Stereoselective Halogenation in Natural Product Synthesis. , 2016, Angewandte Chemie.
[25] M. Periasamy,et al. Zinc Salt Promoted Diastereoselective Synthesis of Chiral Propargylamines Using Chiral Piperazines and Their Enantioselective Conversion into Chiral Allenes , 2014 .
[26] N. Miyaura,et al. Metal-catalyzed reactions of diborons for synthesis of organoboron compounds. , 2004, Chemical record.
[27] J. Groves,et al. Manganese porphyrins catalyze selective C-H bond halogenations. , 2010, Journal of the American Chemical Society.
[28] J. Okuda,et al. Calcium-mediated dearomatization, C-H bond activation, and allylation of alkylated and benzannulated pyridine derivatives. , 2011, Chemistry.
[29] A. Lei,et al. Iron-catalyzed direct arylation of unactivated arenes with aryl halides. , 2010, Angewandte Chemie.
[30] Chao‐Jun Li,et al. Copper‐Catalyzed Cross‐Dehydrogenative Coupling (CDC) of Alkynes and Benzylic CH Bonds , 2010 .
[31] Hiroyuki Nakamura,et al. Synthesis of 2-Indolyltetrahydroquinolines by Zinc(II)-Catalyzed Intramolecular Hydroarylation-Redox Cross-Dehydrogenative Coupling of N-Propargylanilines with Indoles. , 2016, Angewandte Chemie.
[32] M. Varonka,et al. Catalytic C-H amination with unactivated amines through copper(II) amides. , 2010, Angewandte Chemie.
[33] T. H. Warren,et al. Catalytic C-H amination with aromatic amines. , 2012, Angewandte Chemie.
[34] J. Petrignet,et al. Short and convenient synthesis of two natural phthalides by a copper(I) catalysed Sonogashira/oxacyclisation copper(I) process , 2014 .
[35] Bing Yu,et al. Copper(I)-based ionic liquid-catalyzed carboxylation of terminal alkynes with CO2 at atmospheric pressure , 2015 .
[36] T. Cundari,et al. Copper(II) anilides in sp³ C-H amination. , 2014, Journal of the American Chemical Society.
[37] J. Davidson,et al. 154. The tautomerism of arene and ditertiary phosphine complexes of ruthenium(0), and the preparation of new types of hydrido-complexes of ruthenium(II) , 1965 .
[38] Zhengwang Chen,et al. Copper-Catalyzed Direct Amination of 1,2,3-Triazole N-Oxides by C–H Activation and C–N Coupling , 2015 .
[39] E. Nakamura,et al. Iron-catalyzed nitrogen-directed coupling of arene and aryl bromides mediated by metallic magnesium , 2012 .
[40] E. Nakamura,et al. Synthesis of anthranilic acid derivatives through iron-catalyzed ortho amination of aromatic carboxamides with N-chloroamines. , 2014, Journal of the American Chemical Society.
[41] M. Gómez-Gallego,et al. Kinetic isotope effects in the study of organometallic reaction mechanisms. , 2011, Chemical reviews.
[42] R. Jana,et al. Ligand-Enabled, Copper-Promoted Regio- and Chemoselective Hydroxylation of Arenes, Aryl Halides, and Aryl Methyl Ethers. , 2016, The Journal of organic chemistry.
[43] Jing Xiang,et al. Synthesis, Characterization, and Catalytic Activity of Iron(II) and Nickel(II) Complexes Containing the Rigid Pentadentate Ligand PY5Me2 , 2014 .
[44] Hartwig,et al. Catalytic, Regiospecific End-Functionalization of Alkanes: Rhenium-Catalyzed Borylation under Photochemical Conditions. , 1999, Angewandte Chemie.
[45] Liang‐Nian He,et al. Efficient iron(III)-catalyzed three-component coupling reaction of alkynes, CH2Cl2 and amines to propargylamines. , 2012, Chemical communications.
[46] L. Ackermann,et al. Manganese-Catalyzed C–H Activation , 2016 .
[47] S. Rout,et al. Terminal aryl alkenes and alkynes as arylcarboxy surrogates toward o-benzoxylation of 2-phenylpyridine catalyzed by copper. , 2014, Organic letters.
[48] Xuri Huang,et al. Analysis of an alternative to the H-atom abstraction mechanism in methane C-H bond activation by nonheme iron(IV)-oxo oxidants. , 2013, Dalton transactions.
[49] M. Asadullah,et al. Calcium-catalyzed selective and quantitative transformation of CH4 and CO into acetic acid , 2000 .
[50] Chinpiao Chen,et al. Manganese(II) chloride catalyzed highly efficient one-pot synthesis of propargylamines and fused triazoles via three-component coupling reaction under solvent-free condition , 2014 .
[51] L. Ackermann,et al. Cobalt-Catalyzed C―H Activation , 2016 .
[52] Mats Tilset,et al. Mechanistic aspects of C-H activation by Pt complexes. , 2005, Chemical reviews.
[53] O. Daugulis,et al. A general method for copper-catalyzed arylation of arene C-H bonds. , 2008, Journal of the American Chemical Society.
[54] S. Nakagaki,et al. New highly brominated Mn-porphyrin: a good catalyst for activation of inert C–H bonds , 2015 .
[55] Y. Kuninobu,et al. Manganese- and Borane-Mediated Synthesis of Isobenzofuranones from Aromatic Esters and Oxiranes via C-H Bond Activation. , 2016, Organic letters.
[56] R. Samanta,et al. Copper-Catalyzed Regioselective Cascade Alkylation and Cyclocondensation of Quinoline N-Oxides with Diazo Esters: Direct Access to Conjugated π-Systems. , 2016, Chemistry.
[57] Jidan Liu,et al. Copper‐Mediated Tandem C(sp2)–H Sulfenylation and Annulation of Arenes with 2‐Mercaptoimidazoles: Regio‐ and Site‐selective Access to Polycyclic Fused Imidazo[2,1‐b][1,3]thiazinones , 2016 .
[58] E. Nakamura,et al. Iron-catalyzed directed alkylation of aromatic and olefinic carboxamides with primary and secondary alkyl tosylates, mesylates, and halides. , 2014, Journal of the American Chemical Society.
[59] Z. Xi,et al. Calcium-Mediated C–H and C–F Bond Cleavage: Synthesis of Indenes and Perfluorodibenzopentalenes from 1,4-Dilithio-1,3-butadienes , 2016 .
[60] Sukbok Chang,et al. Transition Metal-Catalyzed C-H Amination: Scope, Mechanism, and Applications. , 2017, Chemical reviews.
[61] N. Yoshikai. Cp*CoIII‐Catalyzed CH Activation of (Hetero)arenes: Expanding the Scope of Base‐Metal‐Catalyzed CH Functionalizations , 2015 .
[62] S. Adimurthy,et al. Copper(I) Iodide Catalyzed Aerobic Oxidative CN and CS bond formations through CH Activation: Synthesis of Functionalized Imidazo[1,2‐a]pyridines , 2014 .
[63] L. Ackermann,et al. Iron-catalyzed C(sp(2))-H and C(sp(3))-H methylations of amides and anilides. , 2015, Chemistry.
[64] John J. Sirois,et al. Iron-Catalyzed Arylation of Heterocycles via Directed C–H Bond Activation , 2014, Organic letters.
[65] jin-quan yu,et al. A Simple and Versatile Amide Directing Group for C-H Functionalizations. , 2016, Angewandte Chemie.
[66] H. Dalton,et al. Methane activation by methane monooxygenase: free radicals, Fe-C bonding, substrate dependent pathways and the role of the regulatory protein , 1998, JBIC Journal of Biological Inorganic Chemistry.
[67] H. Ohmiya,et al. Copper-catalyzed enantioselective allylic alkylation of terminal alkyne pronucleophiles. , 2014, Journal of the American Chemical Society.
[68] Maneesh K. Gupta,et al. Cu(I)-catalyzed tandem decarboxylative/C–H activation coupling of cyclic diketones, proline and alkynes: synthesis of α-alkynylated pyrrolidine-oxyindoles , 2014 .
[69] H. Ohmiya,et al. Regio- and stereocontrolled introduction of secondary alkyl groups to electron-deficient arenes through copper-catalyzed allylic alkylation. , 2012, Angewandte Chemie.
[70] Yuanyuan Hu,et al. Manganese-Catalyzed Direct Nucleophilic C(sp(2))-H Addition to Aldehydes and Nitriles. , 2015, Angewandte Chemie.
[71] S. Kundu,et al. Copper Catalyzed sp3 C-H Etherification with Acyl Protected Phenols. , 2016, Journal of the American Chemical Society.
[72] H. Shinokubo. Transition metal catalyzed borylation of functional π-systems , 2014, Proceedings of the Japan Academy. Series B, Physical and biological sciences.
[73] K. Itami,et al. Synthesis of extended π-systems through C-H activation. , 2015, Angewandte Chemie.
[74] Yugen Zhang,et al. Copper- and copper–N-heterocyclic carbene-catalyzed C─H activating carboxylation of terminal alkynes with CO2 at ambient conditions , 2010, Proceedings of the National Academy of Sciences.
[75] M. Yasuda,et al. Zn(II) chloride-catalyzed direct coupling of various alkynes with acetals: facile and inexpensive access to functionalized propargyl ethers. , 2013, Chemical communications.
[76] J. Wang,et al. Cu(I)-catalyzed cross-coupling of conjugated ene-yne-ketones and terminal alkynes: synthesis of furan-substituted allenes. , 2014, Organic letters.
[77] B. K. Nicholson,et al. Preparation of η5-pyranyltricarbonylmanganese complexes and pyrylium triiodide salts from cyclomanganated chalcones and alkynes , 1996 .
[78] S. Bahekar,et al. Zn(OTf) 2 -mediated C H activation: An expeditious and solvent-free synthesis of aryl/alkyl substituted quinolines , 2016 .
[79] J. Shaw,et al. Zinc-catalyzed silylation of terminal alkynes. , 2008, The Journal of organic chemistry.
[80] Martina Nardi,et al. C-H Bond Oxidation Catalyzed by an Imine-Based Iron Complex: A Mechanistic Insight. , 2015, Inorganic chemistry.
[81] K. Hwang,et al. Photoinduced Copper-Catalyzed Regioselective Synthesis of Indoles: Three-Component Coupling of Arylamines, Terminal Alkynes, and Quinones. , 2015, Angewandte Chemie.
[82] T. H. Warren,et al. Mechanistic insights into C-H amination via dicopper nitrenes. , 2013, Journal of the American Chemical Society.
[83] F. Glorius,et al. Formal SN‐Type Reactions in Rhodium(III)‐Catalyzed CH Bond Activation , 2014 .
[84] Yang Zheng,et al. Cu-Catalyzed direct cyanation of terminal alkynes with AMBN or AIBN as the cyanation reagent. , 2015, Chemical communications.
[85] Jidan Liu,et al. Copper-Mediated ortho-Arylation of Benzamides with Arylboronic Acid , 2016 .
[86] Liang‐Nian He,et al. Carboxylation of terminal alkynes at ambient CO2 pressure in ethylene carbonate , 2013 .
[87] G. Georg,et al. Synthesis of Strained 1,3-Diene Macrocycles via Copper-Mediated Castro-Stephens Coupling/Alkyne Reduction Tandem Reactions. , 2015, Organic letters.
[88] S. Enthaler. Rise of the Zinc Age in Homogeneous Catalysis , 2013 .
[89] K. Hirano,et al. Unexpected cyclization of tritylamines promoted by copper salt through C-H and C-N bond cleavages to produce acridine derivatives. , 2014, Chemistry.
[90] O. Daugulis,et al. Copper-catalyzed arylation of heterocycle C-H bonds. , 2007, Journal of the American Chemical Society.
[91] J. Pei,et al. Intramolecular C–F and C–H bond cleavage promoted by butadienyl heavy Grignard reagents , 2014, Nature Communications.
[92] E. Nakamura,et al. Ortho-allylation of 1-arylpyrazoles with allyl phenyl ether via iron-catalyzed C-H bond activation under mild conditions , 2014 .
[93] L. Ackermann,et al. Iron-catalyzed C(sp(2))-H and C(sp(3))-H arylation by triazole assistance. , 2014, Angewandte Chemie.
[94] Haijun Li,et al. Iron-catalyzed C-C bond formation by direct functionalization of C-H bonds adjacent to heteroatoms. , 2008, Angewandte Chemie.
[95] E. Nakamura,et al. Iron‐Catalyzed ortho Monoarylation of Benzamide Derivatives , 2012 .
[96] Charlette M. Felton,et al. Activation of sp3 and sp2 CH bonds of oxygen containing heterocyclic molecules for alkylation and arylation reactions catalyzed by an iron complex , 2014 .
[97] F. Qing,et al. Copper-catalyzed direct C-H oxidative trifluoromethylation of heteroarenes. , 2012, Journal of the American Chemical Society.
[98] K. Sun,et al. Copper(I)‐Catalyzed Dehydrogenative Amidation of Arenes Using Air as the Oxidant , 2015 .
[99] E. Carreira,et al. First synthesis of optically pure propargylic N-hydroxylamines by direct, highly diastereoselective addition of terminal alkynes to nitrones. , 2002, Angewandte Chemie.
[100] E. Nakamura,et al. Iron-catalyzed allylic arylation of olefins via C(sp3)-H activation under mild conditions. , 2013, Organic letters.
[101] J. Marrot,et al. Copper-catalyzed oxidative alkynylation of diaryl imines with terminal alkynes: a facile synthesis of ynimines. , 2012, Organic Letters.
[102] D. Morton,et al. Recent Advances in C-H Functionalization. , 2016, The Journal of organic chemistry.
[103] A. Chan,et al. Copper(I)-Catalyzed Asymmetric Addition of Terminal Alkynes to β-Imino Esters: An Efficient and Direct Method in the Synthesis of Chiral β3-Alkynyl β2,2-Dimethyl Amino Acid Derivatives , 2009 .
[104] M. Mihovilovic,et al. Ligand‐Assisted Iron Catalysis in the Direct Functionalization of CH Bonds , 2014 .
[105] E. Suresh,et al. Chemoselective and biomimetic hydroxylation of hydrocarbons by non-heme micro-oxo-bridged diiron(III) catalysts using m-CPBA as oxidant. , 2009, Dalton transactions.
[106] S. Gorelsky. Origins of regioselectivity of the palladium-catalyzed (aromatic)CH bond metalation–deprotonation , 2013 .
[107] E. Nakamura,et al. Iron/Zinc-Co-catalyzed Directed Arylation and Alkenylation of C(sp3)–H Bonds with Organoborates , 2017 .
[108] W. Cao,et al. Diastereo- and enantioselective propargylation of benzofuranones catalyzed by pybox-copper complex. , 2014, Organic letters.
[109] Yalin Tang,et al. A copper-catalyzed domino reaction to construct functionalized indolizinones , 2015 .
[110] Liping Li,et al. An ultra-stable nanosized Ce0.9Fe0.1O2solid solution with an excellent catalytic performance towards CH4oxidation , 2013 .
[111] R. Varma,et al. Magnetic graphitic carbon nitride: its application in the C-H activation of amines. , 2015, Chemical communications.
[112] C. Krebs,et al. myo-Inositol oxygenase: a radical new pathway for O(2) and C-H activation at a nonheme diiron cluster. , 2009, Dalton transactions.
[113] Lili Lin,et al. Copper/Guanidine-Catalyzed Asymmetric Alkynylation of Isatins. , 2016, Angewandte Chemie.
[114] E. Nakamura,et al. Oxidative C-H Activation Approach to Pyridone and Isoquinolone through an Iron-Catalyzed Coupling of Amides with Alkynes. , 2016, Chemistry, an Asian journal.
[115] R. Staples,et al. Functional Aspects of Gif-type Oxidation of Hydrocarbons Mediated by Iron Picolinate H₂O₂-dependent Systems: Evidence for the Generation of Carbon- and Oxygen-centered Radicals , 2000 .
[116] Mun Yee Wong,et al. Iron-catalyzed directed C2-alkylation and alkenylation of indole with vinylarenes and alkynes. , 2015, Organic letters.
[117] Frank Glorius,et al. C-H bond activation enables the rapid construction and late-stage diversification of functional molecules. , 2013, Nature chemistry.
[118] M. Ehara,et al. Methane activation on Fe- and FeO-embedded graphene and boron nitride sheet: role of atomic defects in catalytic activities , 2015 .
[119] E. Nakamura,et al. β-Arylation of carboxamides via iron-catalyzed C(sp3)-H bond activation. , 2013, Journal of the American Chemical Society.
[120] E. P. Talsi,et al. Active sites and mechanisms of bioinspired oxidation with H2O2, catalyzed by non-heme Fe and related Mn complexes , 2014 .
[121] Hu Li,et al. Direct functionalization of benzylic C-Hs with vinyl acetates via Fe-catalysis. , 2009, Chemical communications.
[122] K. Ohkubo,et al. Light-driven, proton-controlled, catalytic aerobic C-H oxidation mediated by a Mn(III) porphyrinoid complex. , 2015, Journal of the American Chemical Society.
[123] Xian‐Ming Zhang,et al. Efficient and environmentally friendly Glaser coupling of terminal alkynes catalyzed by multinuclear copper complexes under base-free conditions , 2016 .
[124] Long-Fei Wu,et al. Ferrous iron and α-ketoglutarate-dependent dioxygenases in the biosynthesis of microbial natural products. , 2016, Biochimica et biophysica acta.
[125] E. Nakamura,et al. Iron-catalyzed chemoselective ortho arylation of aryl imines by directed C-H bond activation. , 2009, Angewandte Chemie.
[126] S. Blanksby,et al. Bond dissociation energies of organic molecules. , 2003, Accounts of chemical research.
[127] K. Itami,et al. Catalytic Methods for Aromatic C–H Amination: An Ideal Strategy for Nitrogen-Based Functional Molecules , 2016 .
[128] Jie Wu,et al. Route to pyrazolo[5,1-a]isoquinolines via a copper-catalyzed tandem reaction of 2-alkynylbromobenzene with pyrazole. , 2013, The Journal of organic chemistry.
[129] Y. Shao,et al. Iron-Catalyzed Cyclization of Nitrones with Geminal-Substituted Vinyl Acetates: A Direct [4 + 2] Assembly Strategy Leading to 2,4-Disubstituted Quinolines. , 2016, The Journal of organic chemistry.
[130] Ji Zhang,et al. Iron-mediated direct arylation of unactivated arenes. , 2008, Angewandte Chemie.
[131] L. Ackermann,et al. Manganese-catalyzed synthesis of cis-β-amino acid esters through organometallic C-H activation of ketimines. , 2015, Angewandte Chemie.
[132] S. Adapa,et al. Zn(OAc)2·2H2O: a versatile catalyst for the one-pot synthesis of propargylamines , 2007 .
[133] R. O'hair,et al. C-H bond activation of methanol and ethanol by a high-spin Fe(IV)O biomimetic complex. , 2011, Angewandte Chemie.
[134] Chao‐Jun Li,et al. Fe(III)-Catalyzed Cross-Dehydrogenative Arylation (CDA) between Oxindoles and Arenes under an Air Atmosphere. , 2015, Chemistry.
[135] J. Groves,et al. Manganese-catalyzed late-stage aliphatic C-H azidation. , 2015, Journal of the American Chemical Society.
[136] Jincheng Mao,et al. [Cu(acac)2]·H2O-catalyzed Sonogashira-type couplings of aryl halides and terminal alkynes. , 2011, Chemistry, an Asian journal.
[137] L. Tran,et al. Bidentate, monoanionic auxiliary-directed functionalization of carbon-hydrogen bonds. , 2015, Accounts of chemical research.
[138] J. Wang,et al. Synthesis of phenanthrenes through copper-catalyzed cross-coupling of N-tosylhydrazones with terminal alkynes. , 2014, The Journal of organic chemistry.
[139] Mingliang Wang,et al. Divergent copper-mediated dimerization and hydroxylation of benzamides involving C-H bond functionalization. , 2016, Organic & biomolecular chemistry.
[140] Marisa C. Kozlowski,et al. Aerobic copper-catalyzed organic reactions. , 2013, Chemical reviews.
[141] D. Srinivas,et al. Benzylic oxidation with H2O2 catalyzed by Mn complexes of N,N′,N″-trimethyl-1,4,7-triazacyclononane: spectroscopic investigations of the active Mn species , 2002 .
[142] M. Yasuda,et al. Direct synthesis of alkynylstannanes: ZnBr2 catalyst for the reaction of tributyltin methoxide and terminal alkynes. , 2011, Angewandte Chemie.
[143] A. Ghanem,et al. Rhodium‐Catalysed Enantioselective C–H Functionalization in Asymmetric Synthesis , 2016 .
[144] Yoshinori Yamamoto,et al. Synthesis of imidazoles through the copper-catalyzed cross-cycloaddition between two different isocyanides. , 2006, Journal of the American Chemical Society.
[145] Clyde W. Cady,et al. Evidence for a precursor complex in C-H hydrogen atom transfer reactions mediated by a manganese(IV) oxo complex. , 2011, Angewandte Chemie.
[146] B. Bhanage,et al. Copper catalyzed oxidative ortho-C-H benzoxylation of 2-phenylpyridines with benzyl alcohols and benzyl amines as benzoxylation sources. , 2014, Organic & biomolecular chemistry.
[147] Ming Zhang. Copper-catalyzed/mediated aromatic CH bond functionalization , 2010 .
[148] Samuel Inack Ngi,et al. Regioselective copper-mediated synthesis of thieno[2,3-c]pyrane-7-one, indolo[2,3-c]pyrane-1-one, and indolo[3,2-c]pyrane-1-one. , 2011, The Journal of organic chemistry.
[149] Xin‐Yan Wu,et al. Enantioselective Synthesis of 3-Alkynyl-3-hydroxyindolin-2-ones by Copper-Catalyzed Asymmetric Addition of Terminal Alkynes to Isatins. , 2016, Organic letters.
[150] A. Studer,et al. Zinc triflate catalyzed aerobic cross-dehydrogenative coupling (CDC) of alkynes with nitrones: a new entry to isoxazoles. , 2011, Organic letters.
[151] B. Jiang,et al. Highly enantioselective alkynylation of alpha-keto ester: an efficient method for constructing a chiral tertiary carbon center. , 2002, Organic letters.
[152] P. Stavropoulos,et al. The gif paradox. , 2001, Accounts of chemical research.
[153] B. Movassagh,et al. A General and Highly Efficient Protocol for the Synthesis of Chalcogenoacetylenes by Copper(I)-Terpyridine Catalyst , 2014 .
[154] P. Knochel,et al. Preparations and reactions of SF5-substituted aryl and heteroaryl derivatives via Mg and Zn organometallics. , 2012, Chemistry.
[155] Cong-Hui Wang. Manganese-Mediated C–C Bond Formation via C–H Activation: From Stoichiometry to Catalysis , 2013 .
[156] E. Carreira,et al. Diastereoselective zinc-catalyzed conjugate addition of alkynes. , 2004, Organic letters.
[157] H. Golchoubian,et al. Selective and efficient C–H oxidation of alkanes with hydrogen peroxide catalyzed by a manganese(III) Schiff base complex , 2006 .
[158] J. Hartwig. Borylation and silylation of C-H bonds: a platform for diverse C-H bond functionalizations. , 2012, Accounts of chemical research.
[159] Y. Nishina,et al. Rhenium-catalyzed insertion of nonpolar and polar unsaturated molecules into an olefinic C-H bond. , 2009, Organic letters.
[160] M. J. González,et al. Zinc reagents as non-noble catalysts for alkyne activation , 2015 .
[161] A. Tlili,et al. Functionalization of remote C-H bonds: expanding the frontier. , 2014, Angewandte Chemie.
[162] E. Carreira,et al. Asymmetric autocatalysis enables an improved synthesis of efavirenz. , 2011, Angewandte Chemie.
[163] K. Mashima,et al. Organomagnesium-catalyzed isomerization of terminal alkynes to allenes and internal alkynes. , 2015, Chemistry.
[164] L. Ackermann,et al. Synergistic Heterobimetallic Manifold for Expedient Manganese(I)-Catalyzed C-H Cyanation. , 2016, Chemistry.
[165] L. Field,et al. Reaction of ethylene with a coordinatively unsaturated iron complex Fe(DEPE)2: sp2 carbon-hydrogen bond activation without prior formation of a .pi.-complex , 1986 .
[166] Qiang Zhu,et al. Synthesis of 10‐Methylacridin‐9(10H)‐ones through Cu‐Catalyzed Intramolecular Oxidative C(sp2)–H Amination of 2‐(Methylamino)benzophenones , 2013 .
[167] Garima Singh,et al. Alkaline-Earth-Catalyzed sp3 C–H Functionalization of Methyl Azaarenes and Its Use in a One-Pot Four-Component Synthesis of Azaarenyl Benzylpyrazolones , 2015 .
[168] B. Plietker,et al. Biorelevant Metals in Sustainable Metal Catalysis—A Survey , 2013 .
[169] D. Prajapati,et al. A copper-catalyzed one-pot, three-component tandem conjugative alkynylation/6-endo cyclization sequence: access to pyrano[2,3-d]-pyrimidines. , 2015, Organic & biomolecular chemistry.
[170] L. Ackermann,et al. Iron-Catalyzed C-H Alkynylation through Triazole Assistance: Expedient Access to Bioactive Heterocycles. , 2017, Chemistry.
[171] N. Chatani,et al. Nickel Catalysts/N,N′-Bidentate Directing Groups: An Excellent Partnership in Directed C–H Activation Reactions , 2015 .
[172] Yugen Zhang,et al. Copper‐Catalyzed Three‐Component Coupling of Terminal Alkyne, Dihalomethane and Amine to Propargylic Amines , 2011 .
[173] Parthasarathi Subramanian,et al. Copper-Catalyzed Cascade Amination Route to N-Aryl Benzimidazoquinazolinones. , 2016, The Journal of organic chemistry.
[174] S. Bahekar,et al. Zn(OTf)2-Mediated Expeditious and Solvent-Free Synthesis of Propargylamines via C–H Activation of Phenylacetylene , 2016 .
[175] E. Negishi,et al. Palladium-catalyzed alkynylation. , 2003, Chemical reviews.
[176] Joseph P. Adams,et al. Sustainable synthesis of enantiopure fluorolactam derivatives by a selective direct fluorination – amidase strategy , 2016 .
[177] M. Costas. Selective C–H oxidation catalyzed by metalloporphyrins , 2011 .
[178] Wan-li Chen,et al. Copper-Catalyzed Tandem Reactions of 2-Iodobenzamides with Sodium Azide: An Efficient Synthesis of [1,2,3]Triazolo[1,5-a][1,4]-benzodiazepin-6(5H)-ones , 2015, Synlett.
[179] M. Pal,et al. Pd/ligand-free synthesis of thienopyranones via Cu-catalyzed coupling-cyclization in PEG 400 under ultrasound , 2014 .
[180] A. Janowicz,et al. Carbon-hydrogen activation in completely saturated hydrocarbons: direct observation of M + R-H .fwdarw. M(R)(H) , 1982 .
[181] O. Daugulis,et al. A general method for copper-catalyzed arene cross-dimerization. , 2011, Journal of the American Chemical Society.
[182] G. Rajaraman,et al. Oxidation of methane by an N-bridged high-valent diiron-oxo species: electronic structure implications on the reactivity. , 2015, Dalton transactions.
[183] A. Aponick,et al. Enantioselective Copper-Catalyzed Quinoline Alkynylation. , 2015, Angewandte Chemie.
[184] E. V. Van der Eycken,et al. Copper-catalyzed direct secondary and tertiary C-H alkylation of azoles through a heteroarene-amine-aldehyde/ketone coupling reaction. , 2013, Angewandte Chemie.
[185] Liang‐Nian He,et al. Copper(I)@Carbon-Catalyzed Carboxylation of Terminal Alkynes with CO2 at Atmospheric Pressure , 2015 .
[186] Jason M. Lynam,et al. Manganese(I)‐Catalyzed C−H Activation: The Key Role of a 7‐Membered Manganacycle in H‐Transfer and Reductive Elimination , 2016, Angewandte Chemie.
[187] Xiaoxu Yang,et al. Manganese‐Catalyzed ortho‐C−H Alkenylation of Aromatic N−H Imidates with Alkynes: Versatile Access to Mono‐Alkenylated Aromatic Nitriles , 2016 .
[188] E. Carreira,et al. A simple, mild, catalytic, enantioselective addition of terminal acetylenes to aldehydes. , 2001, Journal of the American Chemical Society.
[189] A. Barrett,et al. Intramolecular hydroamination of aminoalkenes by calcium and magnesium complexes: a synthetic and mechanistic study. , 2009, Journal of the American Chemical Society.
[190] B. K. Nicholson,et al. β-Cyclomanganated 1,5-diphenylpenta-1,4-dien-3-ones and their reactions with alkynes: routes to η5-pyranyl and η5-oxocycloheptadienylMn(CO)3 complexes , 2001 .
[191] L. Ackermann,et al. Manganese(I)-Catalyzed Substitutive C-H Allylation. , 2016, Angewandte Chemie.
[192] J. Parrain,et al. Copper(I)‐Catalysed Multicomponent Reaction: Straightforward Access to 5‐Hydroxy‐1H‐pyrrol‐2(5H)‐ones , 2016 .
[193] Hanmin Huang,et al. Iron-catalyzed direct alkenylation of 2-substituted azaarenes with N-sulfonyl aldimines via C-H bond activation. , 2011, Organic letters.
[194] Bing Yu,et al. Copper(I)/phosphine-catalyzed tandem carboxylation/annulation of terminal alkynes under ambient pressure of CO2: one-pot access to 3a-hydroxyisoxazolo[3,2-a]isoindol-8(3aH)-ones , 2015 .
[195] L. Ackermann,et al. Manganese(I)-Catalyzed C-H Aminocarbonylation of Heteroarenes. , 2015, Angewandte Chemie.
[196] S. Dasgupta,et al. Enantioselective Copper(I)-Catalyzed Alkynylation of Oxocarbenium Ions to Set Diaryl Tetrasubstituted Stereocenters. , 2015, Angewandte Chemie.
[197] Zhiyong Wang,et al. A tandem reaction of 2-alkynylbenzaldoximes with cyclic ethers co-catalyzed by silver(I) triflate and copper(II) acetate , 2014 .
[198] Aaron Petronico,et al. A manganese catalyst for highly reactive yet chemoselective intramolecular C(sp3)–H amination , 2015, Nature Chemistry.
[199] Chao‐Jun Li,et al. Iron-catalyzed three-component coupling of aldehyde, alkyne, and amine under neat conditions in air , 2009 .
[200] M. Gao,et al. Oxidative Coupling between Two Hydrocarbons: An Update of Recent C-H Functionalizations. , 2015, Chemical reviews.
[201] C. Bolm,et al. Copper-catalyzed oxidative cross-coupling of sulfoximines and alkynes. , 2013, Angewandte Chemie.
[202] L. Cavallo,et al. NHC-Copper(I) Halide-Catalyzed Direct Alkynylation of Trifluoromethyl Ketones on Water. , 2016, Chemistry.
[203] Kazunari Yoshizawa,et al. Two-step concerted mechanism for alkane hydroxylation on the ferryl active site of methane monooxygenase , 1998, JBIC Journal of Biological Inorganic Chemistry.
[204] Alejandro López-Moreno,et al. Non-heme iron catalysis in CC, C–H, and CH2 oxidation reactions. Oxidative transformations on terpenoids catalyzed by Fe(bpmen)(OTf)2 , 2013 .
[205] K. Hirano,et al. Recent Advances in Copper-mediated Direct Biaryl Coupling , 2015 .
[206] W. Jones,et al. Catalytic thermal carbon-hydrogen activation with manganese complexes: evidence for .eta.2-H2 coordination in a neutral manganese complex and its role in carbon-hydrogen activation , 1992 .
[207] Arianna Bassan,et al. A density functional study on a biomimetic non-heme iron catalyst: insights into alkane hydroxylation by a formally HO-FeV=O oxidant. , 2005, Chemistry.
[208] M. Rueping,et al. Copper catalyzed oxidative coupling reactions for trifluoromethylselenolations--synthesis of R-SeCF3 compounds using air stable tetramethylammonium trifluoromethylselenate. , 2015, Chemical communications.
[209] S. Ma,et al. Identifying a Highly Active Copper Catalyst for KA(2) Reaction of Aromatic Ketones. , 2016, Chemistry.
[210] S. Herres‐Pawlis,et al. Bis(pyrazolyl)methane Copper Complexes as Robust and Efficient Catalysts for Sonogashira Couplings , 2015 .
[211] Sandra Pinet,et al. Dialkylzinc-assisted alkynylation of nitrones. , 2002, Organic letters.
[212] Bingwei Zhou,et al. Mn-catalyzed aromatic C-H alkenylation with terminal alkynes. , 2013, Journal of the American Chemical Society.
[213] Chang-Liang Sun,et al. Direct C-H transformation via iron catalysis. , 2011, Chemical reviews.
[214] Huayu Qiu,et al. Direct C-N coupling of imidazoles and benzylic compounds via iron-catalyzed oxidative activation of C-H bonds. , 2011, The Journal of organic chemistry.
[215] W. Xu,et al. Copper-catalyzed C(sp2)–C(sp) Sonogashira-type cross-coupling reactions accelerated by polycyclic aromatic hydrocarbons , 2015 .
[216] Wajid Ali,et al. Benzylic ethers as arylcarboxy surrogates in substrate directed ortho C–H functionalisation catalysed by copper , 2015 .
[217] F. Hong,et al. Recent developments in the preparation of N-heterocycles using Pd-catalysed C–H activation , 2016 .
[218] C. Bruneau,et al. Ruthenium(II)-catalyzed C-H bond activation and functionalization. , 2012, Chemical reviews.
[219] B. Das,et al. Copper-catalyzed direct cross coupling of 1,3,4-oxadiazoles with trans-β-halostyrenes: synthesis of 2-E-vinyl 1,3,4-oxadiazoles , 2012 .
[220] W. Lamanna,et al. PREPARATION AND REACTIVITY OF THE (CYCLOHEXADIENE)MANGANESE TRICARBONYL ANION. POTENTIALLY USEFUL METHODS OF ARENE AND CARBON-HYDROGEN BOND ACTIVATION , 1981 .
[221] E. Carreira,et al. Enantioselective total synthesis of (R)-strongylodiols A and B , 2003 .
[222] Junxiang Zhang,et al. C–H Arylation Reaction: Atom Efficient and Greener Syntheses of π-Conjugated Small Molecules and Macromolecules for Organic Electronic Materials , 2013 .
[223] S. Noji,et al. Catalytic Enantioselective Oxidation of Alkanes and Alkenes Using (Salen)Manganese Complexes Bearing a Chiral Binaphthyl Strapping Unit , 2004 .
[224] Michael T. Green,et al. Significantly shorter Fe-S bond in cytochrome P450-I is consistent with greater reactivity relative to chloroperoxidase , 2015, Nature chemistry.
[225] K. Takai,et al. Manganese-catalyzed synthesis of hydantoin derivatives from terminal alkynes and isocyanates , 2008 .
[226] U. Flörke,et al. C−H Activation of Imines by Trimethylphosphine-Supported Iron Complexes and Their Reactivities , 2009 .
[227] F. Fontana,et al. Free-radical mechanisms in the oxidation and halogenation of alkanes, alkenes and alkylbenzenes by t-BuOOH under Gif-Barton catalysis , 1996 .
[228] Stephen P. Thomas,et al. Recent Advances of Manganese Catalysis for Organic Synthesis , 2016 .
[229] Weak O-Assistance Outcompeting Strong N,N-Bidentate Directing Groups in Copper-Catalyzed C-H Chalcogenation. , 2016, Chemistry.
[230] M. Tian,et al. Copper porphyrin-catalyzed aerobic oxidative coupling of terminal alkynes with high TON , 2016 .
[231] S. Harder,et al. From limestone to catalysis: application of calcium compounds as homogeneous catalysts. , 2010, Chemical reviews.
[232] B. Trost,et al. Recent Advances on the Total Syntheses of Communesin Alkaloids and Perophoramidine. , 2015, Chemistry.
[233] C. Bolm,et al. Iron-catalysed carbon-heteroatom and heteroatom-heteroatom bond forming processes. , 2008, Chemical Society reviews.
[234] T Gensch,et al. Mild metal-catalyzed C-H activation: examples and concepts. , 2016, Chemical Society reviews.
[235] Xiao-hua Cai,et al. Recent advances on nickel-catalyzed C–H bonds functionalized reactions , 2015 .
[236] Xinglin Yang,et al. Some recent advances in transition-metal-catalyzed ortho SP2 C-H functionalization using Ru, Rh, and Pd , 2014, Science China Chemistry.
[237] S. Stahl,et al. Copper-catalyzed aerobic oxidative amidation of terminal alkynes: efficient synthesis of ynamides. , 2008, Journal of the American Chemical Society.
[238] J. Groves,et al. Manganese Catalyzed C-H Halogenation. , 2015, Accounts of chemical research.
[239] K. Hirano,et al. Stereospecific copper-catalyzed C-H allylation of electron-deficient arenes with allyl phosphates. , 2011, Angewandte Chemie.
[240] Jianbo Wang,et al. Cu(I)-catalyzed reaction of diazo compounds with terminal alkynes: a direct synthesis of trisubstituted furans , 2014 .
[241] Yu Yuan,et al. Transition-metal-catalyzed Chelation-assisted C-H Functionalization of Aromatic Substrates. , 2016, Chemical record.
[242] L. Ackermann. Carboxylate-assisted transition-metal-catalyzed C-H bond functionalizations: mechanism and scope. , 2011, Chemical reviews.
[243] Garima Singh,et al. C(sp3)–H functionalization of methyl azaarenes: a calcium-catalyzed facile synthesis of (E)-2-styryl azaarenes and 2-aryl-1,3-bisazaarenes , 2015 .
[244] Lei Liu,et al. Copper-Catalyzed Aerobic Enantioselective Cross-Dehydrogenative Coupling of N-Aryl Glycine Esters with Terminal Alkynes. , 2016, Organic letters.
[245] E. Derat,et al. Tandem C-H activation/arylation catalyzed by low-valent iron complexes with bisiminopyridine ligands. , 2014, Chemistry.
[246] F. Glorius,et al. Towards mild metal-catalyzed C-H bond activation. , 2011, Chemical Society reviews.
[247] Bing‐Feng Shi,et al. Copper-catalyzed direct acyloxylation of C(sp2)-H bonds with Benzoic acids , 2015, Science China Chemistry.
[248] L. Ackermann,et al. Catalyst-Guided C=Het Hydroarylations by Manganese-Catalyzed Additive-Free C-H Activation. , 2016, Chemistry.
[249] U. Flörke,et al. Cyclometalation of substrates containing imine and pyridyl anchoring groups by iron and cobalt complexes. , 2005, Angewandte Chemie.
[250] E. Nakamura,et al. Iron-catalyzed ortho-allylation of aromatic carboxamides with allyl ethers. , 2013, Journal of the American Chemical Society.
[251] Jidan Liu,et al. Copper-Catalyzed or -Mediated CH Bond Functionalizations Assisted by Bidentate Directing Groups , 2016 .
[252] C. Bolm,et al. Copper-Catalyzed Direct Sulfoximination of Heteroaromatic N-Oxides by Dual C-H/N-H Dehydrogenative Cross-Coupling. , 2016, Chemistry, an Asian journal.
[253] P. Knochel,et al. Enantioselective, copper(I)-catalyzed three-component reaction for the preparation of propargylamines. , 2003, Angewandte Chemie.
[254] F. Launay,et al. The selective functionalization of saturated hydrocarbons. Part 44. Measurement of size of reagent by variation of steric demands of competing substrates using Gif chemistry , 1998 .
[255] C. Bolm,et al. Iron‐Catalyzed Benzylic Oxidation with Aqueous tert‐Butyl Hydroperoxide , 2007 .
[256] K. Mochida,et al. Activation of carbon-hydrogen bonds of aromatic rings using calcium atoms , 1987 .
[257] K. Hirano,et al. Copper-Catalyzed Intramolecular Benzylic C-H Amination for the Synthesis of Isoindolinones. , 2016, The Journal of organic chemistry.
[258] M. Baltas,et al. Synthesis of α‐Keto‐1,2,3‐triazoles Through Copper Iodide Catalyzed Oxygenation , 2014 .
[259] J. Bercaw,et al. Understanding and exploiting C–H bond activation , 2002, Nature.
[260] E. Nakamura,et al. Iron-catalyzed C-H bond activation for the ortho-arylation of aryl pyridines and imines with Grignard reagents. , 2011, Chemistry, an Asian journal.
[261] Hao Xu,et al. Copper-Catalyzed Aerobic C–H Trifluoromethylation of Phenanthrolines , 2014, Synlett.
[262] Laure Vendier,et al. Iron-catalyzed C-H borylation of arenes. , 2015, Journal of the American Chemical Society.
[263] S. Messaoudi,et al. Stereoretentive Copper-Catalyzed Directed Thioglycosylation of C(sp2 )-H Bonds of Benzamides. , 2016, Chemistry.
[264] M. Ehara,et al. Direct oxidation of methane to methanol on Fe–O modified graphene , 2014 .
[265] Anne Galarneau,et al. Catalytic, mild, and selective oxyfunctionalization of linear alkanes: current challenges. , 2012, Angewandte Chemie.
[266] Zhangjie Shi,et al. Exploration of earth-abundant transition metals (Fe, Co, and Ni) as catalysts in unreactive chemical bond activations. , 2015, Accounts of chemical research.
[267] W. Frank,et al. Consecutive Three-Component Synthesis of 2,6-Disubstituted Pyrimid-4(3H)-ones and 1,5-Disubstituted 3-Hydroxypyrazoles Initiated by Copper(I)-Catalyzed Carboxylation of Terminal Alkynes , 2014 .
[268] T. Satoh. Recent Advances in the Chemistry and Synthetic Uses of Magnesium Carbenoids , 2012 .
[269] T. Satoh,et al. Oxidative coupling of aromatic substrates with alkynes and alkenes under rhodium catalysis. , 2010, Chemistry.
[270] J. Hartwig,et al. C-H activation for the construction of C-B bonds. , 2010, Chemical reviews.
[271] H. Ohmiya,et al. Copper-catalyzed γ-selective and stereospecific direct allylic alkylation of terminal alkynes: synthesis of skipped enynes. , 2013, Angewandte Chemie.
[272] Wantai Yang,et al. Surface chemoselective phototransformation of C-H bonds on organic polymeric materials and related high-tech applications. , 2013, Chemical reviews.
[273] S. Rout,et al. Benzylamine as an arylcarboxy surrogate: a copper catalysed o-benzoxylation of 2-phenylpyridines using benzyl amines , 2014 .
[274] O. Eisenstein,et al. C-H bond activation in transition metal species from a computational perspective. , 2010, Chemical reviews.
[275] S. Shaik,et al. Two-State Reactivity in Low-Valent Iron-Mediated C-H Activation and the Implications for Other First-Row Transition Metals. , 2016, Journal of the American Chemical Society.
[276] E. Nakamura,et al. Iron-catalyzed C-C bond formation at alpha-position of aliphatic amines via C-H bond activation through 1,5-hydrogen transfer. , 2010, Journal of the American Chemical Society.
[277] Xuri Huang,et al. Recent Advances in Iron-Catalyzed C-H Bond Activation Reactions , 2012 .
[278] D. Truhlar,et al. Mechanism of Oxidation of Ethane to Ethanol at Iron(IV)-Oxo Sites in Magnesium-Diluted Fe2(dobdc). , 2015, Journal of the American Chemical Society.
[279] T. H. Warren,et al. Copper-Catalyzed sp3 C–H Amination , 2012 .
[280] C. Yeung,et al. Catalytic dehydrogenative cross-coupling: forming carbon-carbon bonds by oxidizing two carbon-hydrogen bonds. , 2011, Chemical reviews.
[281] G. C. Fu,et al. A straightforward and mild synthesis of functionalized 3-alkynoates. , 2004, Angewandte Chemie.
[282] A. Lei,et al. Zinc-Catalyzed Dehydrogenative Cross-Coupling of Terminal Alkynes with Aldehydes: Access to Ynones. , 2015, Angewandte Chemie.
[283] C. Pan,et al. Iron-Catalyzed Direct C-H Thiolation of Trimethoxybenzene with Disulfides , 2012 .
[284] S. Murai. Transition metal catalyzed manipulation of non-polar carbon–hydrogen bonds for synthetic purpose , 2011, Proceedings of the Japan Academy. Series B, Physical and biological sciences.
[285] Haitao Zhao,et al. Benchmark study on methanol C-H and O-H bond activation by bare [Fe(IV)O](2+). , 2014, The journal of physical chemistry. A.
[286] J. Okuda,et al. Insertion of pyridine into the calcium allyl bond: regioselective 1,4-dihydropyridine formation and C-H bond activation. , 2010, Angewandte Chemie.
[287] F. Tureček,et al. Hydrocarbon oxidation by Bis-mu-oxo manganese dimers: electron transfer, hydride transfer, and hydrogen atom transfer mechanisms. , 2002, Journal of the American Chemical Society.
[288] Haiyan Ma,et al. Unprecedented Reaction Pathway of Sterically Crowded Calcium Complexes: Sequential C-N Bond Cleavage Reactions Induced by C-H Bond Activations. , 2017, Chemistry, an Asian journal.
[289] N. Maulide,et al. The redox-neutral approach to C-H functionalization. , 2013, Chemistry.
[290] D. Blackmond,et al. Innate C-H trifluoromethylation of heterocycles , 2011, Proceedings of the National Academy of Sciences.
[291] F. Qing,et al. Copper-mediated oxidative difluoromethylation of terminal alkynes with TMSCF2H , 2015 .
[292] M. White,et al. Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation , 2010, Science.
[293] Sean C. Smith,et al. Theoretical study of two states reactivity of methane activation on iron atom and iron dimer , 2012 .
[294] T. Cundari,et al. Copper-nitrene complexes in catalytic C-H amination. , 2008, Angewandte Chemie.
[295] R. Jana,et al. Copper(II)-Mediated Intermolecular C(sp(2))-H Amination of Benzamides with Electron-Rich Anilines. , 2016, The Journal of organic chemistry.
[296] Chung‐Ming Sun,et al. Copper catalyzed aerobic oxidative cyclization and ketonization: one pot synthesis of benzoimidazo[1,2-a]imidazolones. , 2016, Chemical communications.
[297] M. Cokoja,et al. Iron-catalyzed oxidation of unreactive CH bonds: Utilizing bio-inspired axial ligand modification to increase catalyst stability , 2015 .
[298] Corinne Fruit,et al. Pd-Catalyzed and Copper Assisted Regioselective Sequential C2 and C7 Arylation of Thiazolo[5,4-f]quinazolin-9(8H)-one with Aryl Halides. , 2016, Organic letters.
[299] I. Yavari,et al. Formation of N-sulfonylamidines by copper-catalyzed coupling of sulfonyl azides, terminal alkynes, and trialkylamines , 2011 .
[300] Chandra M. R. Volla,et al. Chemoselective C-H bond activation: ligand and solvent free iron-catalyzed oxidative C-C cross-coupling of tertiary amines with terminal alkynes. Reaction scope and mechanism. , 2009, Organic letters.
[301] M. Bruce,et al. ortho-Metalation reactions. Part I. Reactions of azobenzene with some metal carbonyl complexes of sub-groups VI, VII, and VIII , 1970 .
[302] Yuanyuan Hu,et al. Manganese-catalyzed bicyclic annulations of imines and α,β-unsaturated esters via C−H activation , 2016, Science China Chemistry.
[303] K. Hirano,et al. Copper-mediated oxidative direct C-C (hetero)aromatic cross-coupling. , 2012, Chemical communications.
[304] M. Kanai,et al. Mg-catalyzed enantioselective benzylic C-H bond functionalization of isoindolinones: addition to imines. , 2012, Chemistry.
[305] Ramachandra Reddy Donthiri,et al. Copper(I) Iodide‐Catalysed Aerobic Oxidative Synthesis of Imidazo[1,2‐a]pyridines from 2‐Aminopyridines and Methyl Ketones , 2013 .
[306] T. Cundari,et al. Computational study of methane C-H activation by first-row late transition metal L(n)M=E (M: Fe, Co, Ni) complexes. , 2010, Inorganic chemistry.
[307] J. Wang,et al. Cu(I)-Catalyzed Cross-Coupling of Terminal Alkynes with Trifluoromethyl Ketone N-Tosylhydrazones: Access to 1,1-Difluoro-1,3-enynes. , 2015, Organic letters.
[308] S. Ma,et al. One-pot synthesis of 1,3-disubstituted allenes from 1-alkynes, aldehydes, and morpholine. , 2010, Journal of the American Chemical Society.
[309] Melanie S Sanford,et al. Palladium-catalyzed ligand-directed C-H functionalization reactions. , 2010, Chemical reviews.
[310] Peng-Ju Ma,et al. Amine-accelerated manganese-catalyzed aromatic C-H conjugate addition to α,β-unsaturated carbonyls. , 2014, Chemical communications.
[311] G. Erker,et al. Ruthenium Carbene Complexes Featuring a Tridentate Pincer-type Ligand , 2005 .
[312] J. Wang,et al. Coupling of N-tosylhydrazones with terminal alkynes catalyzed by copper(I): synthesis of trisubstituted allenes. , 2010, Angewandte Chemie.
[313] Erick M. Carreira,et al. Catalytic in Situ Generation of Zn(II)-Alkynilides under Mild Conditions: A Novel CN Addition Process Utilizing Terminal Acetylenes , 1999 .
[314] Long Zhang,et al. Catalytic enantioselective tert-aminocyclization by asymmetric binary acid catalysis (ABC): stereospecific 1,5-hydrogen transfer. , 2012, Chemistry.
[315] E. Nakamura,et al. Iron-catalyzed stereospecific activation of olefinic C-H bonds with Grignard reagent for synthesis of substituted olefins. , 2011, Journal of the American Chemical Society.
[316] C. A. Tolman,et al. Chemistry of 2-naphthyl bis[bis(dimethylphosphino)ethane] hydride complexes of iron, ruthenium, and osmium. 3. Cleavage of sp2 carbon-hydrogen bonds , 1979 .
[317] J. Wang,et al. Copper(I)-catalyzed alkylation of polyfluoroarenes through Direct C-H bond functionalization. , 2015, Angewandte Chemie.
[318] C. Cazin,et al. A cooperative Pd-Cu system for direct C-H bond arylation. , 2014, Chemical communications.
[319] O. Daugulis,et al. A General Method for Aminoquinoline-Directed, Copper-Catalyzed sp(2) C-H Bond Amination. , 2016, Journal of the American Chemical Society.
[320] K. Takai,et al. Organic reactions catalyzed by rhenium carbonyl complexes. , 2011, Chemical reviews.
[321] jin-quan yu,et al. Developing ligands for palladium(II)-catalyzed C-H functionalization: intimate dialogue between ligand and substrate. , 2013, The Journal of organic chemistry.
[322] Trevor Platt,et al. Biological control of surface temperature in the Arabian Sea , 1991, Nature.
[323] B. K. Nicholson,et al. Preparation of cyclomanganated chalcones and their reactions with methyl acrylate and other α, β-unsaturated carbonyl compounds , 1995 .
[324] E. Nakamura,et al. Iron-catalyzed C(sp(2))-H bond functionalization with organoboron compounds. , 2014, Journal of the American Chemical Society.
[325] Xiaoyan Li,et al. Activation of sp3 Carbon−Hydrogen Bonds by Cobalt and Iron Complexes and Subsequent C−C Bond Formation , 2009 .
[326] Y. Nishina,et al. Manganese-catalyzed insertion of aldehydes into a C-H bond. , 2007, Angewandte Chemie.
[327] Q. Zhang,et al. Copper-catalyzed dehydrogenative cross-coupling reactions of N-para-tolylamides through successive C-H activation: synthesis of 4H-3,1-benzoxazines. , 2011, Angewandte Chemie.
[328] Xiuling Cui,et al. Copper(I)-catalyzed homo-coupling of terminal alkynes at room temperature under solvent and base free conditions using O2 as an oxidant , 2014 .
[329] G. S. Kumar,et al. CuBr/FeCl3 Catalysis: a Novel and Efficient Method for the Preparation of New Aryl (Iminomethyl)propargyl Ether Derivatives via CH Activation of Aryl Propargyl Ethers , 2011 .
[330] Chao‐Jun Li,et al. The cross-dehydrogenative coupling of C(sp3)-H bonds: a versatile strategy for C-C bond formations. , 2014, Angewandte Chemie.
[331] O. Staszewska-Krajewska,et al. Diastereoselective synthesis of propargylic N-hydroxylamines via NHC-copper(I) halide-catalyzed reaction of terminal alkynes with chiral nitrones on water. , 2015, Chemical communications.
[332] Y. Tu,et al. Iron-catalyzed C(sp3)-C(sp3) bond formation through C(sp3)-H functionalization: a cross-coupling reaction of alcohols with alkenes. , 2009, Angewandte Chemie.
[333] J. Ellman,et al. Rhodium catalyzed chelation-assisted C-H bond functionalization reactions. , 2012, Accounts of chemical research.
[334] K. Towe. Aerobic respiration in the Archaean? , 1990, Nature.
[335] E. Nakamura,et al. Iron-catalyzed direct arylation through directed C-H bond activation. , 2008, Journal of the American Chemical Society.
[336] F. Glorius,et al. Beyond directing groups: transition-metal-catalyzed C-H activation of simple arenes. , 2012, Angewandte Chemie.
[337] Felix J R Klauck,et al. Manganese-catalyzed allylation via sequential C–H and C–C/C–Het bond activation , 2017, Chemical science.
[338] G. Vougioukalakis,et al. Using sustainable metals to carry out “green” transformations: Fe- and Cu-catalyzed CO2 monetization , 2015 .
[339] S. Ma,et al. Copper (I) Iodide-Catalyzed One-Step Preparation of Functionalized Allenes from Terminal Alkynes: Amine Effect , 2012 .
[340] J. Wang,et al. Iron(II)-catalyzed direct cyanation of arenes with aryl(cyano)iodonium triflates. , 2014, Angewandte Chemie.
[341] Samir K. Patel,et al. Diastereoselective addition of terminal alkynes to chiral nitrones: asymmetric synthesis of propargylic N-hydroxylamines , 2003 .
[342] W. Cao,et al. Copper-catalyzed C–H Alkynylation / Intramolecular Cyclization Cascade for the First Synthesis of Trifluoromethylated Pyrrolo[1,2-a]quinolines , 2016 .
[343] S. Cook,et al. A unified strategy for iron-catalyzed ortho-alkylation of carboxamides. , 2014, Journal of the American Chemical Society.
[344] Z. Lei,et al. Manganese catalyzed C-H functionalization of indoles with alkynes to synthesize bis/trisubstituted indolylalkenes and carbazoles: the acid is the key to control selectivity. , 2015, Chemical communications.
[345] S. Harder. Intramolecular C-H activation in alkaline-earth metal complexes. , 2003, Angewandte Chemie.
[346] Hiroyuki Nakamura,et al. Zinc(II)-catalyzed redox cross-dehydrogenative coupling of propargylic amines and terminal alkynes for synthesis of N-tethered 1,6-enynes. , 2012, Journal of the American Chemical Society.
[347] S. Cook,et al. Iron-catalyzed C(sp²)-H alkylation of carboxamides with primary electrophiles. , 2014, Angewandte Chemie.