论文信息 - Kinetics of the conversion of bicarbonate to carbon dioxide

Kinetics of the conversion of bicarbonate to carbon dioxide

Himmelblau and Babb 1 added bicarbonate labelled with C-14 to solutions containing unlabelled bicarbonate and CO 2 . They measured the rate at which C-14 appeared in the CO 2 and deduced values of the rate-constant for the reaction between CO 2 and OH - . These values were up to 130 times as high as those found by other workers. A new reaction-mechanism is proposed to account for their experimental results, involving an exchange reaction between carbon-containing compounds.

P. V. Danckwerts | K. Melkersson

[1] J. Toft,et al. Kinetics of the Carbon Dioxide Hydration under Conditions of Enforced Stationarity. , 1961 .

[2] D. Himmelblau,et al. Kinetic studies of carbonation reactions using radioactive tracers , 1958 .

[3] L. Pearson,et al. The kinetics of combination of carbon dioxide with hydroxide ions , 1956 .

[4] F. Roughton,et al. The catalytic effect of buffers on the reaction CO2+H2O⇌H2CO3 , 1938 .