Crystal structure of trans-dichloro-bis[(E)-2-(1-methoxy-imidazol-2-yl)-2-oxoacetaldehyde O-methyl oxime]palladium(II), PdCl2(C7H9N3O3)2

C14H18Cl2N6O6Pd, triclinic, P1 (no. 2), a = 7.4741(5) Å, b = 8.3215(5) Å, c = 9.1618(6) Å, , = 73.605(3)°, + = 76.146(4)°, ' = 70.823(4)°, V = 509.5 Å, Z = 1, Rgt(F) = 0.020, wRref(F ) = 0.048, T = 233 K.

[1]  V. Kahlenberg,et al.  Crystal structure of (E)-2-(1-methoxyimidazol-2-yl)- 2-oxoacetaldehyde O-methyl oxime, C7H9N3O3 , 2011 .

[2]  M. Hayashi,et al.  Effect of ortho-substituents on the stereochemistry of 2-(o-substituted phenyl)-1H-imidazoline–palladium complexes , 2010 .

[3]  A. Patra,et al.  trans-Dichloro-bis-(arylazoimidazole)palladium(II): synthesis, structure, photoisomerization, and DFT calculation. , 2009, Inorganic chemistry.

[4]  M. Hayashi,et al.  2-Phenylimidazole−PdCl2 and 2-Phenylimidazoline−PdCl2 Complexes: Single-Crystal and Powder X-ray Diffractometry, 1H NMR Spectra, and Comparison of Catalytic Activities in Coupling Reactions† , 2008 .

[5]  G. Sheldrick.  A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[6]  W. Herrmann,et al.  A Palladium(II) Complex Containing Imidazole Moieties. Synthesis and Structural Examination , 2007 .

[7]  M. Hayashi,et al.  Imidazole and Imidazoline Derivatives as N‐Donor Ligands for Palladium‐Catalyzed Mizoroki—Heck Reaction. , 2007 .

[8]  H. Lee,et al.  trans‐Bis(1‐benzyl­imidazole)dichloro­palladium(II) , 2006 .

[9]  S. Materazzi,et al.  Search of structure and ligands exchange for palladium(II) complexes with N-allylimidazole; X-ray and solid-state/solution NMR studies , 2006 .

[10]  B. Bildstein,et al.  Crystal structure of dichlorobis[N-(2,6-diisopropylphenyl)- benzimidimidazolide]palladium(II), PdCl2(C22H25N3)2 , 2006 .

[11]  B. Twamley,et al.  An Ionic Liquid Coordinated Palladium Complex: A Highly Efficient and Recyclable Catalyst for the Heck Reaction. , 2005 .

[12]  I. J. Lin,et al.  Organic–inorganic hybrids of imidazole complexes of palladium(II), copper(II) and zinc(II). Crystals and liquid crystals , 2003 .

[13]  T. Todorov,et al.  Crystal Structure of a New Allotropic Form of trans-Pd(Creat)2Cl2·2H2O , 2002 .

[14]  T. Głowiak,et al.  Palladium(II) Complexes of 1-vinylimidazole , 2002 .

[15]  N. Farrell,et al.  Structures of the nitroimidazole platinum group metal complexes cis -amminedibromo[1-({[(2-hydroxyethyl)amino]carbonyl}methyl)-2-nitroimidazole]platinum(II) and trans -dichlorobis(1-hydroxyethyl-2-methyl-5-nitroimidazole)palladium(II) , 1993 .

[16]  G. Ponticelli,et al.  Crystal and molecular structure oftrans-dichlorobis(N-propylimidazole)palladium(II) , 1985 .

[17]  S. García-Blanco,et al.  Structure of trans-dichlorobis(2-methylimidazole)palladium(II), [Pd(C4H6N2)2Cl2] , 1983 .

[18]  S. García-Blanco,et al.  Structure of trans‐dichlorobis(1‐methylimidazole)palladium(II), [Pd(C4H6N2)2Cl2] , 1983 .