Fast Adaptive Thermal Camouflage Based on Flexible VO₂/Graphene/CNT Thin Films.

Adaptive camouflage in thermal imaging, a form of cloaking technology capable of blending naturally into the surrounding environment, has been a great challenge in the past decades. Emissivity engineering for thermal camouflage is regarded as a more promising way compared to merely temperature controlling that has to dissipate a large amount of excessive heat. However, practical devices with an active modulation of emissivity have yet to be well explored. In this letter we demonstrate an active cloaking device capable of efficient thermal radiance control, which consists of a vanadium dioxide (VO2) layer, with a negative differential thermal emissivity, coated on a graphene/carbon nanotube (CNT) thin film. A slight joule heating drastically changes the emissivity of the device, achieving rapid switchable thermal camouflage with a low power consumption and excellent reliability. It is believed that this device will find wide applications not only in artificial systems for infrared camouflage or cloaking but also in energy-saving smart windows and thermo-optical modulators.

[1]  A. Gorodetsky,et al.  Infrared invisibility stickers inspired by cephalopods , 2015 .

[2]  Xian Huang,et al.  Adaptive optoelectronic camouflage systems with designs inspired by cephalopod skins , 2014, Proceedings of the National Academy of Sciences.

[3]  F. Krebs,et al.  Fast Switching ITO Free Electrochromic Devices , 2014 .

[4]  Pooi See Lee,et al.  Stretchable and wearable electrochromic devices. , 2014, ACS nano.

[5]  K. Jiang,et al.  Development of an ultra-thin film comprised of a graphene membrane and carbon nanotube vein support , 2013, Nature Communications.

[6]  Lei Dai,et al.  VO2 thermochromic smart window for energy savings and generation , 2013, Scientific Reports.

[7]  Alon A Gorodetsky,et al.  Reconfigurable Infrared Camouflage Coatings from a Cephalopod Protein , 2013, Advanced materials.

[8]  Yanfeng Gao,et al.  F-doped VO2 nanoparticles for thermochromic energy-saving foils with modified color and enhanced solar-heat shielding ability. , 2013, Physical chemistry chemical physics : PCCP.

[9]  H. Jeong,et al.  Flexible thermochromic window based on hybridized VO2/graphene. , 2013, ACS nano.

[10]  R. Blanchard,et al.  Vanadium Dioxide as a Natural Disordered Metamaterial: Perfect Thermal Emission and Large Broadband Negative Differential Thermal Emittance , 2013, 1305.0033.

[11]  H. Jeong,et al.  Enhanced optical response of hybridized VO₂/graphene films. , 2013, Nanoscale.

[12]  Chen Sihai,et al.  Infrared characteristics of VO2 thin films for smart window and laser protection applications , 2012 .

[13]  Gisia Beydaghyan,et al.  High contrast thermochromic switching in vanadium dioxide (VO2) thin films deposited on indium tin oxide substrates , 2012 .

[14]  Tao Yao,et al.  Unraveling Metal-insulator Transition Mechanism of VO2 Triggered by Tungsten Doping , 2012, Scientific Reports.

[15]  Kai Liu,et al.  Ultra-long, free-standing, single-crystalline vanadium dioxide micro/nanowires grown by simple thermal evaporation , 2012 .

[16]  Roman V. Kruzelecky,et al.  Thermochromic VO2 film deposited on Al with tunable thermal emissivity for space applications , 2011 .

[17]  Shoushan Fan,et al.  Superaligned Carbon Nanotube Arrays, Films, and Yarns: A Road to Applications , 2011, Advanced materials.

[18]  Zhao Hao,et al.  Intrinsic optical properties of vanadium dioxide near the insulator-metal transition. , 2011, Nano letters.

[19]  Xiang-Bai Chen Assignment of the Raman Modes of VO_2 in the Monoclinic Insulating Phase , 2011 .

[20]  Alain Haché,et al.  High contrast optical switching in vanadium dioxide thin films , 2008 .

[21]  Yang Wang,et al.  Flexible, stretchable, transparent carbon nanotube thin film loudspeakers. , 2008, Nano letters.

[22]  X. Sun,et al.  Fast switching electrochromic display using a viologen-modified ZnO nanowire array electrode. , 2008, Nano letters.

[23]  Byung-Gyu Chae,et al.  Mott Transition in VO2 Revealed by Infrared Spectroscopy and Nano-Imaging , 2007, Science.

[24]  Roger Hanlon,et al.  Cephalopod dynamic camouflage , 2007, Current Biology.

[25]  Hongkun Park,et al.  Current-driven phase oscillation and domain-wall propagation in WxV1-xO2 nanobeams. , 2007, Nano letters.

[26]  Mark A. Richardson,et al.  Molybdenum-doped vanadium dioxide coatings on glass produced by the aqueous sol-gel method , 2003 .

[27]  R. Kivaisi,et al.  Optical and electrical properties of vanadium dioxide films prepared under optimized RF sputtering conditions , 1999 .

[28]  Masatoshi Imada,et al.  Metal-insulator transitions , 1998 .

[29]  P. Jin,et al.  Tungsten doping into vanadium dioxide thermochromic films by high-energy ion implantation and thermal annealing , 1998 .

[30]  J. Gavarri,et al.  The thermochromic vanadium dioxide. I. Role of stresses and substitution on switching properties , 1993 .

[31]  A. S. Barker,et al.  Infrared Optical Properties of Vanadium Dioxide Above and Below the Transition Temperature , 1966 .

[32]  F. J. Morin,et al.  Oxides Which Show a Metal-to-Insulator Transition at the Neel Temperature , 1959 .

[33]  A. Thayer The Law Which Underlies Protective Coloration , 1896 .