The microstructures of geomaterials and their evolution under the effects of applied loading and/or environmental conditions can affect the integrity of the solid skeletons and eventually change the mechanical behaviours of the materials at the macroscopic scale. Analyses of geomaterial microstructure and its ‘ageing’ are therefore critical to the understanding of their mechanical behaviour and performance in engineering environments. This process of progressive ageing of the microstructure is mainly related to the interaction between the solid skeleton and the fluids that partially or completely saturate the porous network. Water/rock interaction mechanisms and ageing processes in geomaterials are often slow, leading to structural and textural changes that are generally imperceptible to the naked eye but which can significantly affect matrix integrity and cause sudden collapse. This is a particularly well-known phenomenon in shallow abandoned chalk mines, such as those found in France, where the chalk may remain stable over many tens of years but then suddenly break down, leading to collapse of the openings and the ground above them and subsidence at a macroscopic scale (Sorgi, C. & Watelet, J., 2007). In this chapter we present results from a research program (led by Institut National de l’Environnement Industriel et des Risques (INERIS), France, in collaboration with Ecole des Ponts ParisTech – CERMES, France) that was carried out to evaluate the mechanical behaviour of chalk in the shallow underground mine of Estreux, located in northern France. The study was conducted at three different scales: i. site scale (stability analysis) ii. laboratory scale (standard core testing) iii. microscopic scale (electron scanning environmental microscope (ESEM) observations and micro-testing) In situ characteristics of the Estreux mine are first described, including mine geometry, excavation method, overburden lithology, pillar monitoring, and in situ measurements. Then, petrophysical properties, microstructural characterisation, retention properties, and mechanical behaviour of the chalk investigated at laboratory scale (oedometric and triaxial tests) are presented. A microstructural analysis of the Estreux chalk is also presented. This part of the study was conducted using an ESEM, a recent technology that allows the observation of
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