Silicon-containing ferritic/martensitic steel after exposure to oxygen-containing flowing lead–bismuth eutectic at 450 and 550 °C

Abstract A ferritic/martensitic (f/m) steel with 9 and 3 mass% of chromium (Cr) and silicon (Si), respectively, was tested on performance in flowing lead–bismuth eutectic (LBE) at 450 and 550 °C, each at concentrations of solved oxygen of both 10−7 and 10−6 mass%. The 9Cr–3Si steel generally exhibits the same basic corrosion modes as other f/m materials with 9 mass% Cr and typically lower Si content, namely Steel T91. The Si-rich steel shows an overall improved performance in comparison to T91 at 450 °C and 10−7 mass% solved oxygen, but especially at 450 °C and 10−6 mass% solved oxygen. The advantage of higher Si-content in 9Cr steel is less clear at 550 °C. Especially high oxygen content in flowing LBE at 550 °C, between >10−6 mass% and oxygen saturation, seems detrimental for the high-Si material in respect of the initiation and progress of a solution-based corrosion.