Seawater Use and Desalination Technology

Desalination processes for treating seawater, brackish water, and wastewater are increasingly used to provide communities with essential water resources. This chapter provides an overview of current desalination technologies, such as seawater treatment by thermal and reverse osmosis processes, brackish water treatment by reverse osmosis and electrodialysis, and wastewater treatment by reverse osmosis. Feed water quality, pretreatment requirements, operational issues, concentrate disposal, and costs are considered, besides emerging improvements for increasing water recovery. Three alternative desalination technologies – membrane distillation, forward osmosis, and capacitive deionization – are also reviewed, and issues surrounding their industrial implementation discussed.

[1]  Y. Cohen,et al.  Diagnostic analysis of RO desalting treated wastewater , 2008 .

[2]  Robert Rautenbach,et al.  High-pressure reverse osmosis and nanofiltration, a “zero discharge” process combination for the treatment of waste water with severe fouling/scaling potential , 1996 .

[3]  R. Semiat,et al.  Seawater and Brackish‐Water Desalination with Membrane Operations , 2009 .

[4]  Yoram Cohen,et al.  A dual-probe approach for evaluation of gypsum crystallization in response to antiscalant treatment , 2004 .

[5]  Frank Stuer-Lauridsen,et al.  Chapter 8 Tool for monitoring hydrophilic contaminants in water: polar organic chemical integrative sampler (POCIS)☆ , 2007 .

[6]  R. Semiat,et al.  The potential of CO2 stripping for pretreating brackish and wastewater desalination feeds , 2008 .

[7]  David Hasson,et al.  Inhibition of CaCO3 scaling on RO membranes by trace amounts of zinc ions , 2005 .

[8]  Alex R. Bartman,et al.  Brackish water reverse osmosis (BWRO) operation in feed flow reversal mode using an ex situ scale observation detector (EXSOD) , 2009 .

[9]  D. Verdoes,et al.  Water treatment in a Membrane-Assisted Crystallizer (MAC)☆ , 1996 .

[10]  Raphael Semiat,et al.  Energy issues in desalination processes. , 2008, Environmental science & technology.

[11]  Ata M. Hassan,et al.  A new approach to membrane and thermal seawater desalination processes using nanofiltration membranes (Part 1) , 1998 .

[12]  R. Semiat,et al.  Limits of RO recovery imposed by calcium phosphate precipitation , 2005 .

[13]  Tzahi Y. Cath,et al.  High recovery of concentrated RO brines using forward osmosis and membrane distillation , 2009 .

[14]  Takashi Asano,et al.  Waste Water Reclamation and Reuse , 2000 .

[15]  Y. Oren,et al.  Improved compact accelerated precipitation softening (CAPS) , 2001 .

[16]  Raphael Semiat,et al.  Osmotic backwash mechanism of reverse osmosis membranes , 2008 .

[17]  M. Chillon,et al.  Influence of pH in the elimination of boron by means of reverse osmosis , 2001 .

[18]  G. Witkamp,et al.  Controlling scaling in membrane filtration systems using a desupersaturation unit , 1999 .

[19]  Jun-de Li,et al.  Performance of new generation membrane distillation membranes , 2009 .

[20]  Nissim Nadav,et al.  Boron removal from seawater reverse osmosis permeate utilizing selective ion exchange resin , 1999 .

[21]  Yoram Cohen,et al.  Reverse osmosis desalting of inland brackish water of high gypsum scaling propensity: kinetics and mitigation of membrane mineral scaling. , 2008, Environmental science & technology.

[22]  Eugene R. Reahl Reclaiming reverse osmosis blowdown with electrodialysis reversal , 1990 .

[23]  D. Hasson,et al.  Calcium sulphate fouling of reverse osmosis membranes: Flux decline mechanism , 1987 .

[24]  Menachem Elimelech,et al.  A novel ammonia-carbon dioxide forward (direct) osmosis desalination process , 2005 .

[25]  Yoram Cohen,et al.  Diagnostic characterization of gypsum scale formation and control in RO membrane desalination of brackish water , 2006 .

[26]  J. Laîné,et al.  Laboratory technique for predicting the scaling propensity of RO feed waters , 2000 .

[27]  A. Mohammad,et al.  Performance of Nanofiltration Membranes in the Treatment of Synthetic and Real Seawater , 2007 .

[28]  E. Drioli,et al.  Membrane Distillation and Related Operations—A Review , 2005 .

[29]  David Hasson,et al.  Inception of CaSO4 scaling on RO membranes at various water recovery levels , 2001 .

[30]  P. Glueckstern,et al.  Optimization of boron removal in old and new SWRO systems , 2003 .

[31]  O. Söhnel,et al.  Precipitation: Basic Principles and Industrial Applications , 1992 .

[32]  Linda Zou,et al.  Using activated carbon electrode in electrosorptive deionisation of brackish water , 2008 .

[33]  Yoram Cohen,et al.  High-recovery reverse osmosis desalination using intermediate chemical demineralization , 2007 .

[34]  Markus Busch,et al.  Boron removal from seawater using FILMTECTM high rejection SWRO membranes , 2003 .

[35]  Raphael Semiat,et al.  Backwash of RO spiral wound membranes , 2005 .

[36]  David Hasson,et al.  Energy aspects in osmotic processes , 2010 .

[37]  R. Semiat,et al.  Desupersaturation of RO Concentrates by Addition of Coagulant and Surfactant , 2007 .

[38]  Raphael Semiat,et al.  Analysis of parameters affecting boron permeation through reverse osmosis membranes , 2004 .

[39]  T. D. Tran,et al.  Electrosorption of inorganic salts from aqueous solution using carbon aerogels. , 2002, Environmental science & technology.

[40]  R. Semiat,et al.  Suppression of CaCO3 scale deposition by anti-scalants , 1998 .

[41]  Panagiotis D. Christofides,et al.  Reverse Osmosis Desalination with High Permeability Membranes - Cost Optimization and Research Needs , 2010 .

[42]  Raymond D. Letterman,et al.  Water quality and treatment : a handbook of community water supplies , 1999 .

[43]  Yoram Cohen,et al.  High recovery membrane desalting of low-salinity brackish water: Integration of accelerated precipitation softening with membrane RO , 2007 .

[44]  R. Semiat,et al.  Scaling of RO membranes from silica supersaturated solutions , 2003 .

[45]  Menachem Elimelech,et al.  In situ monitoring techniques for concentration polarization and fouling phenomena in membrane filtration. , 2003, Advances in colloid and interface science.

[46]  P. Christofides,et al.  Energy Consumption Optimization of Reverse Osmosis Membrane Water Desalination Subject to Feed Salinity Fluctuation , 2009 .

[47]  R. Semiat,et al.  Technique for evaluating silica scaling and its inhibition in RO desalting , 2001 .

[48]  Sidney Loeb,et al.  Sea Water Demineralization by Means of an Osmotic Membrane , 1963 .

[49]  Veronique Bonnelye,et al.  The sensitivity of SDI analysis: from RO feed water to raw water , 2008 .

[50]  Jean-Philippe Croué,et al.  Fouling characteristics of wastewater effluent organic matter (EfOM) isolates on NF and UF membranes , 2002 .

[51]  Robert Rallo,et al.  Coupled 3-D hydrodynamics and mass transfer analysis of mineral scaling-induced flux decline in a laboratory plate-and-frame reverse osmosis membrane module , 2009 .

[52]  R. Semiat,et al.  Induction times induced in an RO system by antiscalants delaying CaSO4 precipitation , 2003 .

[53]  J. Morse,et al.  A literature review of the saturation state of seawater with respect to calcium carbonate and its possible significance for scale formation on OTEC heat exchangers , 1979 .

[54]  V. Grebenyuk,et al.  Electrodialysis: From an Idea to Realization , 2002 .

[55]  Joseph C. Farmer,et al.  Capacitive Deionization of NaCl and NaNO3 Solutions with Carbon Aerogel Electrodes , 1996 .

[56]  Y. Cohen,et al.  Impact of Conventional Water Treatment Coagulants on Mineral Scaling in RO Desalting of Brackish Water , 2009 .

[57]  Maria D. Kennedy,et al.  Applications of the MFI-UF to measure and predict particulate fouling in RO systems , 2003 .

[58]  Amy E. Childress,et al.  Forward osmosis: Principles, applications, and recent developments , 2006 .

[59]  P. Christofides,et al.  Effect of Thermodynamic Restriction on Energy Cost Optimization of RO Membrane Water Desalination , 2009 .

[60]  Awwa,et al.  Membrane Filtration: Reverse osmosis and nanofiltration , 1998 .

[61]  D. Prats,et al.  Analysis of the influence of pH and pressure on the elimination of boron in reverse osmosis , 2000 .

[62]  J. A. López-Ramírez,et al.  Pre-treatment optimisation studies for secondary effluent reclamation with reverse osmosis. , 2003, Water research.

[63]  A. Graveland,et al.  Developments in water softening by means of pellet reactors , 1983 .

[64]  Jae-Hong Kim,et al.  Analysis of CaSO4 scale formation mechanism in various nanofiltration modules , 1999 .

[65]  David Hasson,et al.  Simple technique for measuring the concentration polarization level in a reverse osmosis system , 2000 .

[66]  Yafeng Zhang,et al.  The removal of silicon and boron from ultra-pure water by electrodeionization , 2005 .

[67]  Harry Seah,et al.  New option of MBR-RO process for production of NEWater from domestic sewage , 2006 .

[68]  Jack Gilron,et al.  WAIV — wind aided intensified evaporation for reduction of desalination brine volume , 2003 .

[69]  P.A.C. Bonné,et al.  RO treatment: selection of a pretreatment scheme based on fouling characteristics and operating conditions based on environmental impact , 2000 .

[70]  David Hasson,et al.  Characterization of the effectiveness of silica anti-scalants , 2003 .

[71]  Haiou Huang,et al.  Pretreatment for low pressure membranes in water treatment: a review. , 2009, Environmental science & technology.

[72]  Yoram Cohen,et al.  Numerical study of concentration polarization in a rectangular reverse osmosis membrane channel: Permeate flux variation and hydrodynamic end effects , 2007 .

[73]  Yoram Cohen,et al.  A novel RO ex situ scale observation detector (EXSOD) for mineral scale characterization and early detection , 2007 .

[74]  R. Semiat,et al.  Scaling Salt Removal by Addition of Inorganic Particles , 2008 .

[75]  R Semiat,et al.  Threshold scaling limits of RO concentrates flowing in a long waste disposal pipeline. , 2004, Water science and technology : a journal of the International Association on Water Pollution Research.

[76]  C. F. Schutte,et al.  Capacitive Deionization Technology™: An alternative desalination solution , 2005 .

[77]  A. Henriksen Laboratory studies on the removal of phosphates from sewage by the coagulation process , 1962, Schweizerische Zeitschrift für Hydrologie.

[78]  David L Sedlak,et al.  Formation and fate of chlorination by-products in reverse osmosis desalination systems. , 2010, Water research.

[79]  Sidney Loeb,et al.  The Loeb-Sourirajan Membrane: How It Came About , 1981 .