Computational fluid dynamic (CFD) simulation of a pilot-scale annular bubble column photocatalytic reactor

The behavior of an 18-l pilot-scale photocatalytic reactor has been investigated using a computational fluid dynamic (CFD) approach. The granular Eulerian model was used to describe the multiphase flow system. Solid recirculation was predicted while liquid velocity vectors were influenced by the gas flow. The companion radiation transport equation was iteratively solved using a finite-volume-based discrete ordinate method. The first-order photodegradation kinetics of spent Bayer liquor previously studied in the same reactor was used to evaluate the CFD simulation. A Pearson correlation coefficient 0.974 between simulated and experimental data is indicative of model adequacy.

[1]  Vishnu Pareek,et al.  Continuous Process for Photodegradation of Industrial Bayer Liquor , 2001 .

[2]  D. Gidaspow,et al.  Hydrodynamics of circulating fluidized beds: Kinetic theory approach , 1991 .

[3]  G. D. Raithby Evaluation of discretization errors in finite-volume radiant heat transfer predictions , 1999 .

[4]  Faïçal Larachi,et al.  Trajectory length and residence-time distributions of the solids in three-phase fluidized beds , 1997 .

[5]  E. Pelizzetti Solar Water Detoxification. Current Status and Perspectives , 1999 .

[6]  D. Jeffrey,et al.  Kinetic theories for granular flow: inelastic particles in Couette flow and slightly inelastic particles in a general flowfield , 1984, Journal of Fluid Mechanics.

[7]  P. Yue Oxidation reactors for water and wastewater treatment , 1997 .

[8]  Alberto E. Cassano,et al.  Photoreactor Analysis and Design: Fundamentals and Applications , 1995 .

[9]  T. Farias,et al.  Modelling of Heat Transfer in Radiating and Combusting Systems , 1998 .

[10]  G. Spadoni,et al.  Scattering effects in photosensitized reactions , 1978 .

[11]  Alberto E. Cassano,et al.  Reaction engineering of suspended solid heterogeneous photocatalytic reactors , 2000 .

[12]  H. Inoue,et al.  GAS HOLDUP IN BUBBLE COLUMNS , 1975 .

[13]  Alberto E. Cassano,et al.  Cylindrical photocatalytic reactors. Radiation absorption and scattering effects produced by suspended fine particles in an annular space , 1997 .

[14]  Shantanu Roy,et al.  Numerical simulation of gas}liquid dynamics in cylindrical bubble column reactors , 1999 .

[15]  Jayathi Y. Murthy,et al.  RADIATIVE HEAT TRANSFER IN AXISYMMETRIC GEOMETRIES USING AN UNSTRUCTURED FINITE-VOLUME METHOD , 1998 .

[16]  S. Asai,et al.  Gas hold-up in bubble columns , 1980 .

[17]  Vivek V. Ranade,et al.  Computational Flow Modeling for Chemical Reactor Engineering , 2001 .

[18]  G. Camera-Roda,et al.  Discrete ordinate method in the analysis of radiative transfer in photocatalytically reacting media , 1998 .