The use of nanoparticles in electroanalysis: an updated review

The use of nanoparticles in electroanalysis is an area of research which is continually expanding. A wealth of research is available discussing the synthesis, characterization and application of nanoparticles. The unique properties of nanoparticulate materials (e.g. enhanced mass transport, high surface area, improved signal-to-noise ratio) can often be advantageous in electroanalytical techniques. The aim of this paper is to provide an updated overview of the work in this field. In this review we have concentrated on the advances with regards to silver, gold, platinum, palladium, ruthenium, copper and nickel. The synthesis, characterization and practical application of these materials are discussed. We have also identified the conditions under which each metal is likely to be stable, which is likely to be a useful tool for those practising in the field. Furthermore, we have provided a theoretical overview of advances in the theoretical modelling and simulation of nanoparticle behaviour.

[1]  Shen-Ming Chen,et al.  Electrochemical Analysis of H2O2 and Nitrite Using Copper Nanoparticles/Poly(o-phenylenediamine) Film Modified Glassy Carbon Electrode , 2009 .

[2]  M. Zawadzki,et al.  Synthesis and structure characterization of Ru nanoparticles stabilized by PVP or γ-Al2O3 , 2008 .

[3]  Itamar Willner,et al.  Electrochemical, photoelectrochemical, and piezoelectric analysis of tyrosinase activity by functionalized nanoparticles. , 2008, Analytical chemistry.

[4]  D. Ghosh,et al.  Dithiocarbamate-protected ruthenium nanoparticles: Synthesis, spectroscopy, electrochemistry and STM studies , 2007 .

[5]  J. Dahn,et al.  Templated Ru/Se/C electrocatalysts for oxygen reduction , 2009 .

[6]  S. Bergens,et al.  Electro-oxidation of 2-propanol and acetone over platinum, platinum–ruthenium, and ruthenium nanoparticles in alkaline electrolytes , 2008 .

[7]  Itamar Willner,et al.  Nucleic acid-functionalized Pt nanoparticles: Catalytic labels for the amplified electrochemical detection of biomolecules. , 2006, Analytical chemistry.

[8]  C. Korzeniewski,et al.  A study of formaldehyde formation during methanol oxidation over PtRu bulk alloys and nanometer scale catalyst , 2007 .

[9]  Wanzhi. Wei,et al.  Nano-silver/multi-walled carbon nanotube composite films for hydrogen peroxide electroanalysis , 2008 .

[10]  Jun‐Jie Zhu,et al.  A Pd/SBA-15 composite: synthesis, characterization and protein biosensing , 2008, Nanotechnology.

[11]  J. Rehspringer,et al.  Synthesis of palladium nanoparticles by sonochemical reduction of palladium(II) nitrate in aqueous solution. , 2006, The journal of physical chemistry. B.

[12]  Alexander Pyatenko,et al.  Synthesis of Spherical Silver Nanoparticles with Controllable Sizes in Aqueous Solutions , 2007 .

[13]  G. Hu,et al.  Electrocatalytic oxidation and simultaneous determination of uric acid and ascorbic acid on the gold nanoparticles-modified glassy carbon electrode , 2008 .

[14]  M. Pourbaix Atlas of Electrochemical Equilibria in Aqueous Solutions , 1974 .

[15]  José M. Pingarrón,et al.  Development and Characterization of Colloidal Gold‐Cysteamine‐Carbon Paste Electrodes , 2004 .

[16]  P. Yáñez‐Sedeño,et al.  Gold nanoparticle-based electrochemical biosensors , 2005, Analytical and bioanalytical chemistry.

[17]  R. Compton,et al.  The use of nanoparticles in electroanalysis: a review , 2006, Analytical and bioanalytical chemistry.

[18]  A. Salimi,et al.  Immobilization of glucose oxidase on electrodeposited nickel oxide nanoparticles: direct electron transfer and electrocatalytic activity. , 2007, Biosensors & bioelectronics.

[19]  Guo-Li Shen,et al.  Successively amplified electrochemical immunoassay based on biocatalytic deposition of silver nanoparticles and silver enhancement. , 2007, Biosensors & bioelectronics.

[20]  R. Compton,et al.  Development of an Electrochemical Sensor Nanoarray for Hydrazine Detection Using a Combinatorial Approach , 2007 .

[21]  T. Jones,et al.  The electroanalytical detection of hydrazine: a comparison of the use of palladium nanoparticles supported on boron-doped diamond and palladium plated BDD microdisc array. , 2006, The Analyst.

[22]  Wen-Yin Ko,et al.  Highly electrocatalytic reduction of nitrite ions on a copper nanoparticles thin film , 2009 .

[23]  Erkang Wang,et al.  Synthesis and electrochemical applications of gold nanoparticles. , 2007, Analytica chimica acta.

[24]  Minghui Zhang,et al.  Synthesis of nickel nanoparticles supported on metal oxides using electroless plating: controlling the dispersion and size of nickel nanoparticles. , 2009, Journal of colloid and interface science.

[25]  N. Jeong,et al.  Electrochemical deposition of Pt nanoparticles on CNTs for fuel cell electrode , 2008 .

[26]  Y. Ye,et al.  Synthesis of nickel nanoparticles and carbon encapsulated nickel nanoparticles supported on carbon nanotubes , 2006 .

[27]  R. Compton,et al.  Diffusion-Limited Currents to Nanoparticles of Various Shapes Supported on an Electrode; Spheres, Hemispheres, and Distorted Spheres and Hemispheres , 2007 .

[28]  R. Yu,et al.  Attachment of nickel hexacyanoferrates nanoparticles on carbon nanotubes: preparation, characterization and bioapplication. , 2006, Analytica chimica acta.

[29]  G. Somorjai,et al.  Colloidally Synthesized Monodisperse Rh Nanoparticles Supported on SBA-15 for Size- and Pretreatment-Dependent Studies of CO Oxidation , 2009 .

[30]  M. L. Mena,et al.  Development of a tyrosinase biosensor based on gold nanoparticles-modified glassy carbon electrodes: Application to the measurement of a bioelectrochemical polyphenols index in wines , 2005 .

[31]  R. Compton,et al.  Magnetically moveable bimetallic (nickel/silver) nanoparticle/carbon nanotube composites for methanol oxidation , 2009 .

[32]  Yanxi Zhao,et al.  Microwave-assisted synthesis of nickel nanoparticles , 2008 .

[33]  R. Compton,et al.  Apparent 'electrocatalytic' activity of multiwalled carbon nanotubes in the detection of the anaesthetic halothane: occluded copper nanoparticles. , 2006, The Analyst.

[34]  G. Shi,et al.  A water-soluble cationic oligopyrene derivative : Spectroscopic studies and sensing applications , 2009 .

[35]  P. He,et al.  A New Technique for Chemical Deposition of Pt Nanoparticles and its Applications on Biosensor Design , 2007 .

[36]  W. Schreiner,et al.  Nickel nanoparticles obtained by a modified polyol process: synthesis, characterization, and magnetic properties. , 2007, Journal of colloid and interface science.

[37]  Y. Hua,et al.  Electro-deposition of platinum nanoparticles on 4-mercaptobenzene-functionalized multi-walled carbon nanotubes , 2008 .

[38]  K. Philippot,et al.  Synthesis of Ruthenium Nanoparticles Stabilized by Heavily Fluorinated Compounds , 2006 .

[39]  Ting Zhang,et al.  Palladium Nanoparticles Decorated Single-Walled Carbon Nanotube Hydrogen Sensor , 2007 .

[40]  Hui Yang,et al.  Boron-Doped Palladium Nanoparticles on Carbon Black as a Superior Catalyst for Formic Acid Electro-oxidation , 2009 .

[41]  Jian-Feng Li,et al.  An Effective Strategy for Room-Temperature Synthesis of Single-Crystalline Palladium Nanocubes and Nanodendrites in Aqueous Solution , 2009 .

[42]  Jing An,et al.  A convenient approach to synthesize stable silver nanoparticles and silver/polystyrene nanocomposite particles , 2008 .

[43]  R. Compton,et al.  Combinatorial electrochemistry using metal nanoparticles: from proof-of-concept to practical realisation for bromide detection. , 2007, Analytica chimica acta.

[44]  J. Dahn,et al.  Fuel cell performance of templated Ru/Se/C-based catalysts , 2009 .

[45]  M. Haruta,et al.  Reduction of 4-nitrophenol to 4-aminophenol over Au nanoparticles deposited on PMMA , 2009 .

[46]  C. Banks,et al.  Novel methods for the production of silver microelectrode-arrays: their characterisation by atomic force microscopy and application to the electro-reduction of halothane. , 2005, Analytical sciences : the international journal of the Japan Society for Analytical Chemistry.

[47]  Qiying Liu,et al.  Dual roles of stearic acid in the synthesis of Co nanomaterials in polyol , 2009 .

[48]  John T. Vaughey,et al.  Bimetallic Pd–Cu Oxygen Reduction Electrocatalysts , 2008 .

[49]  Xiaobo Ji,et al.  AFM studies of metal deposition: instantaneous nucleation and the growth of cobalt nanoparticles on boron-doped diamond electrodes. , 2006, Chemphyschem : a European journal of chemical physics and physical chemistry.

[50]  J. Yang,et al.  Synthesis and Self-Assembly of One-Dimensional Sub-10 nm Ag Nanoparticles with Cyclodextrin , 2008 .

[51]  H. Ju,et al.  Electrodeposition of silver-DNA hybrid nanoparticles for electrochemical sensing of hydrogen peroxide and glucose , 2006 .

[52]  C. Hsieh,et al.  Fabrication and electrochemical activity of carbon nanotubes decorated with PtRu nanoparticles in acid solution , 2008 .

[53]  Yang Liu,et al.  Simultaneous electrochemical determination of dopamine, uric acid and ascorbic acid using palladium nanoparticle-loaded carbon nanofibers modified electrode. , 2008, Biosensors & bioelectronics.

[54]  A. Erdem,et al.  Electrochemical sensing of silver tags labelled DNA immobilized onto disposable graphite electrodes , 2007 .

[55]  Kathleen Shordt,et al.  Arsenic in drinking water. , 2001, Journal of environmental health.

[56]  S. Dubas,et al.  Humic acid assisted synthesis of silver nanoparticles and its application to herbicide detection , 2008 .

[57]  Xuni Cao,et al.  Colloidal silver nanoparticles modified electrode and its application to the electroanalysis of Cytochrome c , 2008 .

[58]  H. Varela,et al.  Electrocatalytic Reduction of Nitrate over Palladium Nanoparticle Catalysts A Temperature-Dependent Study , 2007 .

[59]  Chien-Cheng Chen,et al.  Synthesis of silver nanoparticles using surfactin: A biosurfactant as stabilizing agent , 2009 .

[60]  J. Bao,et al.  Novel Dendritic Palladium Nanostructure and Its Application in Biosensing , 2007 .

[61]  R. Compton,et al.  The contrasting behaviour of polycrystalline bulk gold and gold nanoparticle modified electrodes towards the underpotential deposition of thallium , 2008 .

[62]  M. Bäumer,et al.  Ligand-capped Pt nanocrystals as oxide-supported catalysts: FTIR spectroscopic investigations of the adsorption and oxidation of CO. , 2007, Angewandte Chemie.

[63]  S. Berchmans,et al.  Electrochemical preparation of copper–dendrimer nanocomposites: picomolar detection of Cu2+ ions , 2008, Analytical and bioanalytical chemistry.

[64]  Guangwu Yang,et al.  Simple synthesis of Pt nanoparticles on noncovalent functional MWNT surfaces : Application in ethanol electrocatalysis , 2007 .

[65]  Eric Lesniewska,et al.  Nano-pH sensor for the study of reactive materials. , 2007, Analytical chemistry.

[66]  Richard G. Compton,et al.  Arsenite Determination in Phosphate Media at Electroaggregated Gold Nanoparticle Deposits , 2008 .

[67]  G. Shen,et al.  Surface attached-poly(acrylic acid) network as nanoreactor to in-situ synthesize palladium nanoparticles for H2O2 sensing , 2009 .

[68]  Sachin Kumar,et al.  Electroreduction of O2 on uniform arrays of Pt and PtCo nanoparticles , 2006 .

[69]  E. Ticianelli,et al.  Silver-cobalt bimetallic particles for oxygen reduction in alkaline media , 2006 .

[70]  Ruo-Fei Hu,et al.  Electrochemical study of brucine on an electrode modified with magnetic carbon-coated nickel nanoparticles , 2007, Analytical and bioanalytical chemistry.

[71]  J. Hao,et al.  Size- and shape-controlled synthesis of monodisperse Co nanoparticles from cobalt acetate by thermal decomposition , 2009 .

[72]  Min Han,et al.  Synthesis of perfect silver nanocubes by a simple polyol process , 2007 .

[73]  Malcolm L. H. Green,et al.  Copper oxide nanoparticle impurities are responsible for the electroanalytical detection of glucose seen using multiwalled carbon nanotubes , 2008 .

[74]  T. Jones,et al.  Nano-electrochemical detection of hydrogen or protons using palladium nanoparticles: distinguishing surface and bulk hydrogen. , 2006, Chemphyschem : a European journal of chemical physics and physical chemistry.

[75]  A. Baiker,et al.  Beneficial Interaction of Gold and Palladium in Bimetallic Catalysts for the Selective Oxidation of Benzyl Alcohol , 2009 .

[76]  R. Compton,et al.  Hydrogen Peroxide Electroreduction at a Silver-Nanoparticle Array: Investigating Nanoparticle Size and Coverage Effects , 2009 .

[77]  Wei‐De Zhang,et al.  Electrocatalytic Oxidation of Glucose at Carbon Nanotubes Supported PtRu Nanoparticles and Its Detection , 2008 .

[78]  G. K. Budnikov,et al.  Electrooxidation of oxalic acid at a carbon-paste electrode with deposited palladium nanoparticles , 2006 .

[79]  J. Savéant,et al.  Charge transfer at partially blocked surfaces , 1983 .

[80]  T. Kauffeldt,et al.  Thermodynamic-Controlled Gas Phase Process for the Synthesis of Nickel Nanoparticles of Adjustable Size and Morphology , 2006 .

[81]  R. Compton,et al.  Particle Size and Surface Coverage Effects in the Stripping Voltammetry of Silver Nanoparticles: Theory and Experiment , 2008 .

[82]  A. Wiȩckowski,et al.  Aqueous-based synthesis of ruthenium-selenium catalyst for oxygen reduction reaction. , 2008, Faraday discussions.

[83]  Xiaobo Ji,et al.  Palladium Sub‐Nanoparticle Decorated ‘Bamboo’ Multi‐Walled Carbon Nanotubes Exhibit Electrochemical Metastability: Voltammetric Sensing in Otherwise Inaccessible pH Ranges , 2006 .

[84]  E. Scavetta,et al.  Electrodeposition of a nickel-based hydrotalcite on Pt nanoparticles for ethanol and glucose sensing , 2007 .

[85]  Hu-lin Li,et al.  Electrocatalytic oxidation of methanol on Pt modified single-walled carbon nanotubes , 2006 .

[86]  P. Bogdanoff,et al.  On the structure of carbon-supported selenium-modified ruthenium nanoparticles as electrocatalysts for oxygen reduction in fuel cells. , 2007, Angewandte Chemie.

[87]  R. Compton,et al.  Detection of As(III) via oxidation to As(V) using platinum nanoparticle modified glassy carbon electrodes: arsenic detection without interference from copper. , 2006, The Analyst.

[88]  A. Grace,et al.  One pot synthesis of polymer protected Pt, Pd, Ag and Ru nanoparticles and nanoprisms under reflux and microwave mode of heating in glycerol—A comparative study , 2007 .

[89]  Meng Zhang,et al.  Microwave-assisted rapid facile "Green" synthesis of uniform silver nanoparticles: Self-assembly into multilayered films and their optical properties , 2008 .

[90]  G. Hutchings,et al.  Direct synthesis of hydrogen peroxide from H 2 and O 2 using TiO 2-supported AuPd catalysts , 2005 .

[91]  R. Compton,et al.  Voltammetry at Nanoparticle and Microparticle Modified Electrodes: Theory and Experiment , 2007 .

[92]  Zhenhui Wang,et al.  Electrocatalytic oxidation of formic acid on platinum nanoparticle electrode deposited on the nichrome substrate , 2006 .

[93]  Peixiang Cai,et al.  A sensitive nonenzymatic glucose sensor in alkaline media with a copper nanocluster/multiwall carbon nanotube-modified glassy carbon electrode. , 2007, Analytical biochemistry.

[94]  B. Jena,et al.  Enzyme-free amperometric sensing of glucose by using gold nanoparticles. , 2006, Chemistry.

[95]  Richard G. Compton,et al.  The Fabrication and Characterization of a Bismuth Nanoparticle Modified Boron Doped Diamond Electrode and Its Application to the Simultaneous Determination of Cadmium(II) And Lead(II) , 2008 .

[96]  Olga Domínguez-Renedo,et al.  Electrochemical determination of chromium(VI) using metallic nanoparticle-modified carbon screen-printed electrodes. , 2008, Talanta.

[97]  S. Jiang,et al.  Kinetics of ethanol electrooxidation at Pd electrodeposited on Ti , 2007 .

[98]  K. Zhao,et al.  Electrochemical DNA Biosensors Based on Palladium Nanoparticles Combined with Carbon Nanotubes , 2008 .

[99]  Genxi Li,et al.  Self-assembled multilayer of gold nanoparticles for amplified electrochemical detection of cytochrome c. , 2008, The Analyst.

[100]  I. Casella,et al.  The Electrochemical Reduction of Nitrophenols on Silver Globular Particles Electrodeposited under Pulsed Potential Conditions , 2007 .

[101]  P. Yáñez‐Sedeño,et al.  Amperometric biosensor for hypoxanthine based on immobilized xanthine oxidase on nanocrystal gold–carbon paste electrodes , 2006 .

[102]  Jinshan Lu Effect of surface modifications on the decoration of multi-walled carbon nanotubes with ruthenium nanoparticles , 2007 .

[103]  Q. Gao,et al.  Electrochemical Detection of DNA Hybridization Based on the Probe Labeled with Carbon‐Nanotubes Loaded with Silver Nanoparticles , 2008 .

[104]  C. Tsai,et al.  Electrodeposition of platinum-ruthenium nanoparticles on carbon nanotubes directly grown on carbon cloths for methanol oxidation , 2008 .

[105]  Y. Ikushima,et al.  Morphology and size-controlled synthesis of silver nanoparticles in aqueous surfactant polymer solutions , 2008 .

[106]  T. Boyle,et al.  Synthesis and Activity of Heterogeneous Pd/Al2O3 and Pd/ZnO Catalysts Prepared from Colloidal Palladium Nanoparticles , 2008 .

[107]  C. Werth,et al.  Catalytic Nitrate and Nitrite Reduction with Pd−Cu/PVP Colloids in Water: Composition, Structure, and Reactivity Correlations , 2009 .

[108]  Jon R. Kirchhoff,et al.  An acetylcholinesterase enzyme electrode stabilized by an electrodeposited gold nanoparticle layer , 2007 .

[109]  L. Bai,et al.  Synthesis of nickel nanoparticles with uniform size via a modified hydrazine reduction route , 2008 .

[110]  Shui-Tong Lee,et al.  Surface-Enhanced Raman Scattering from Uniform Gold and Silver Nanoparticle-Coated Substrates , 2009 .

[111]  B. Jena,et al.  Highly sensitive and selective electrochemical detection of sub-ppb level chromium(VI) using nano-sized gold particle. , 2008, Talanta.

[112]  K. More,et al.  Alkylamine Stabilized Ruthenium Nanocrystals: Faceting and Branching , 2008 .

[113]  R. Compton,et al.  The Hydrogen Evolution Reaction at a Silver Nanoparticle Array and a Silver Macroelectrode Compared: Changed Electrode Kinetics between the Macro- and Nanoscales , 2009 .

[114]  Jingkun Xu,et al.  Size-Controlled Synthesis of Palladium Nanoparticles , 2008 .

[115]  Hongying Liu,et al.  Self-assembly of a silver nanoparticles modified electrode and its electrocatalysis on neutral red , 2009 .

[116]  Haitao Wang,et al.  Synthesis of Ru/multiwalled carbon nanotubes by microemulsion for electrochemical supercapacitor , 2008 .

[117]  R. Compton,et al.  Oxidation of Electrodeposited Copper on Boron Doped Diamond in Acidic Solution: Manipulating the Size of Copper Nanoparticles Using Voltammetry , 2006 .

[118]  Xiujian Zhao,et al.  The evidence for synthesis of truncated triangular silver nanoplates in the presence of CTAB , 2008 .