Spiral Magnets as Magnetoelectrics

AbstractMagnetoelectric multiferroics is an old but emerging class of materials that combine coupled electric and magnetic dipole order. In these materials, ferroelectric and magnetic (ferromagnetic or antiferromagnetic) states coexist or compete with each other. The interaction leads to a so-called magnetoelectric effect, which is the induction of magnetization by an electric field or electric polarization by a magnetic field. In the past few years, a new set of magnetoelectric multiferroics such as TbMnO3 and Ni3V2O8 has been discovered. In these magnetoelectric multiferroics, ferroelectric order develops upon a magnetic phase transition into a spiral magnetic ordered phase. In addition, these systems show large magnetoelectric effects accompanied by metamagnetic transitions. Noncollinear spiral magnetism is the key to understanding the magnetoelectric properties in these systems. Here I discuss the magnetoelectric coupling in spiral magnets and review recent advances in the understanding of ferroelectr...

[1]  N. Nagaosa,et al.  Spin current and magnetoelectric effect in noncollinear magnets. , 2004, Physical review letters.

[2]  G. Smolensky,et al.  New ferroelectrics of complex composition. IV , 1961 .

[3]  J. Kaczér,et al.  Some Properties of Ferromagnetoelectric Nickel Iodine Boracite , 1968 .

[4]  R. Ramesh,et al.  Epitaxial BiFeO3 Multiferroic Thin Film Heterostructures , 2003, Science.

[5]  K. Mizushima,et al.  Ferrimagnetic ferroelectricity of Fe3O4 , 1983 .

[6]  N. Momozawa,et al.  Field-induced commensurate intermediate phases in Helimagnet (Ba1-xSrx)2Zn2Fe12O22 (x=0.748) , 1993 .

[7]  T. Moriya Anisotropic Superexchange Interaction and Weak Ferromagnetism , 1960 .

[8]  R. Newnham,et al.  Neutron Diffraction Investigation of the Spiral Magnetic Structure in Cr2BeO4 , 1969 .

[9]  S. Kato,et al.  Ferroelectricity of holmium manganese oxide HoMn2O5 with helical spin ordering , 1997 .

[10]  J. Scott,et al.  Ferroelectrically induced ferromagnetism , 1977 .

[11]  C. L. Zhang,et al.  Magnetic inversion symmetry breaking and ferroelectricity in TbMnO3. , 2005, Physical review letters.

[12]  J. Scott,et al.  Magnetoelectric phenomena in BaMnF4 and BaMn0.99Co0.01F4 , 1980 .

[13]  E. Dagotto,et al.  Role of the Dzyaloshinskii-Moriya interaction in multiferroic perovskites , 2005, cond-mat/0508075.

[14]  A. Prokhorov,et al.  New orthorhombic multiferroics R1–x Yx MnO3 (R = Eu, Gd) , 2006 .

[15]  K. Aizu Possible Species of Ferromagnetic, Ferroelectric, and Ferroelastic Crystals , 1970 .

[16]  Multiferroics: different ways to combine magnetism and ferroelectricity , 2006, cond-mat/0601696.

[17]  N. Iwata,et al.  Magnetic-field-induced transition of thulium manganese oxide TmMn2O5 , 1997 .

[18]  P. Lunkenheimer,et al.  Relaxor ferroelectricity and colossal magnetocapacitive coupling in ferromagnetic CdCr2S4 , 2005, Nature.

[19]  M. Lukina,et al.  Effect of Gd-Mn exchange on phase transitions in GdMn2O5 induced by a strong magnetic field , 2003 .

[20]  K. Saito,et al.  Magnetoelectric effect and low-temperature phase transitions of TbMn2O5 , 1995 .

[21]  A. Krauss,et al.  Composition-control of magnetron-sputter-deposited (BaxSr1−x)Ti1+yO3+z thin films for voltage tunable devices , 2000 .

[22]  Hans Schmid,et al.  Multi-ferroic magnetoelectrics , 1994 .

[23]  Y. Tokura,et al.  Ferroelectricity and giant magnetocapacitance in perovskite rare-earth manganites. , 2004, Physical review letters.

[24]  N. Mathur,et al.  Multiferroic and magnetoelectric materials , 2006, Nature.

[25]  S. Cheong,et al.  Electric polarization reversal and memory in a multiferroic material induced by magnetic fields , 2004, Nature.

[26]  Y. Tokura,et al.  Control of the ferroelectric properties of Dy Mn 2 O 5 by magnetic fields , 2004 .

[27]  T. Shrout,et al.  Ultrahigh strain and piezoelectric behavior in relaxor based ferroelectric single crystals , 1997 .

[28]  H. Kitazawa,et al.  Field-Induced Magnetic Phase Transitions in a Triangular Lattice Antiferromagnet CuFeO 2 up to 14.5 T , 2000 .

[29]  R. Newnham,et al.  Magnetoferroelectricity in Cr2BeO4 , 1978 .

[30]  H. Suzuki,et al.  Magnetic short-range order and reentrant-spin-glass-like behavior in Co Cr 2 O 4 and Mn Cr 2 O 4 by means of neutron scattering and magnetization measurements , 2004 .

[31]  A. Freeman,et al.  Magnetoelectric Interaction Phenomena in Crystals , 1975 .

[32]  T. Kimura,et al.  Electric polarization rotation in a hexaferrite with long-wavelength magnetic structures. , 2005, Physical review letters.

[33]  J. Akimitsu,et al.  A Method of Controlling the Sense of the Screw Spin Structure , 1980 .

[34]  Y. Tokura,et al.  Magnetic-field-induced transition in the lattice modulation of colossal magnetoelectric GdMnO3 and TbMnO3 compounds , 2005 .

[35]  E. Ascher,et al.  Some Properties of Ferromagnetoelectric Nickel‐Iodine Boracite, Ni3B7O13I , 1966 .

[36]  J. Speck,et al.  Realization of high tunability barium strontium titanate thin films by rf magnetron sputtering , 1999 .

[37]  K. Knížek,et al.  Electronic structure and conductivity of ferroelectric hexaferrite: Ab initio calculations , 2006 .

[38]  K. Kohn,et al.  Magnetoelectric effect of rare earth manganese oxide RMn2O5 , 1997 .

[39]  T. Kimura,et al.  Inversion-symmetry breaking in the noncollinear magnetic phase of the triangular-lattice antiferromagnet Cu Fe O 2 , 2005, cond-mat/0510701.

[40]  E. Kita,et al.  Magnetoelectric Effect in ZnCr2Se4 with Screw Spin Structure , 1980 .

[41]  I. Kagomiya,et al.  Reinvestigation of Simultaneous Magnetic and Ferroelectric Phase Transitions in YMn2O5 , 2004 .

[42]  Y. Tokura,et al.  Magnetic control of ferroelectric polarization , 2003, Nature.

[43]  Youichi Murakami,et al.  Ferroelectricity from iron valence ordering in the charge-frustrated system LuFe2O4 , 2005, Nature.

[44]  M. Fiebig Revival of the magnetoelectric effect , 2005 .

[45]  J. Rossat-Mignod,et al.  Magnetic structure of the perovskite-like compound tbmno3 , 1977 .

[46]  Hans Schmid,et al.  Magnetoelectric effects in insulating magnetic materials , 2000, Optics & Photonics.

[47]  T. Palstra,et al.  University of Groningen Ferroelectricity in the cycloidal spiral magnetic phase of MnWO4 , 2006 .

[48]  Vogt,et al.  Magnetic phase transitions of MnWO4 studied by the use of neutron diffraction. , 1993, Physical review. B, Condensed matter.

[49]  T. Arima,et al.  Ferroelectric polarization flop in a frustrated magnet MnWO4 induced by a magnetic field. , 2006, Physical review letters.

[50]  I. Dzyaloshinsky A thermodynamic theory of “weak” ferromagnetism of antiferromagnetics , 1958 .

[51]  G. Shirane,et al.  A magnetic and neutron diffraction study of the Cr2O3-Fe2O3 system , 1962 .

[52]  Per Bak,et al.  Ising model with solitons, phasons, and "the devil's staircase" , 1980 .

[53]  Y. Tokura,et al.  Distorted perovskite witheg1configuration as a frustrated spin system , 2002, cond-mat/0211568.

[54]  Anthony K. Cheetham,et al.  Evidence for the likely occurrence of magnetoferroelectricity in the simple perovskite, BiMnO3 , 2002 .

[55]  A new multiferroic material: MnWO4 , 2006, cond-mat/0608498.

[56]  A. Aharony,et al.  Magnetically driven ferroelectric order in Ni3V2O8. , 2005, Physical review letters.

[57]  Robert Gerson,et al.  Dielectric hysteresis in single crystal BiFeO3 , 1970 .

[58]  Competing magnetic phases on a kagomé staircase. , 2004, Physical review letters.

[59]  G. Shirane,et al.  Polarization rotation via a monoclinic phase in the piezoelectric 92% PbZn(1/3)Nb(2/3)O3-8% PbTiO3. , 2000, Physical review letters.

[60]  Maxim Mostovoy,et al.  Ferroelectricity in spiral magnets. , 2005, Physical review letters.

[61]  A. P. Ramirez,et al.  Magnetoelectric phase diagrams of orthorhombic R MnO 3 ( R = Gd , Tb, and Dy) , 2005 .

[62]  Yakir Aharonov,et al.  Topological Quantum Effects for Neutral Particles , 1984 .

[63]  Y. Tokura,et al.  Magnetic reversal of the ferroelectric polarization in a multiferroic spinel oxide. , 2006, Physical review letters.

[64]  Y. Sun,et al.  Coupling between the ferroelectric and antiferromagnetic orders in YMnO 3 , 1997 .

[65]  D. Argyriou,et al.  Melting of incommensurate-ferroelectric phase with magnetic field in multiferroic TbMnO 3 , 2007 .

[66]  N. Iwata,et al.  Electric and Magnetic Low-Temperature Phase Transitions of YbMn 2O 5 , 1996 .

[67]  Y. Tokura,et al.  Magnetic structure of TbMnO3 by neutron diffraction , 2004 .

[68]  S. Cheong,et al.  Structural anomalies and multiferroic behavior in magnetically frustrated TbMn2O5. , 2004, Physical review letters.

[69]  Nicola A. Hill,et al.  Why Are There so Few Magnetic Ferroelectrics , 2000 .

[70]  Ronald E. Cohen,et al.  Polarization rotation mechanism for ultrahigh electromechanical response in single-crystal piezoelectrics , 2000, Nature.

[71]  T. O'dell The Electrodynamics Of Magneto-Electric Media , 1970 .

[72]  K. Kohn,et al.  Low-temperature phase transition in ErMn2O5 , 1997 .