Bifurcation analysis of chemical reactors and reacting flows.

In this work we review the local bifurcation techniques for analyzing and classifying the steady-state and dynamic behavior of chemical reactor models described by partial differential equations (PDEs). First, we summarize the formulas for determining the derivatives of the branching equation and the coefficients in the amplitude equations for the most common singularities. We also illustrate the procedure for the numerical computation of these coefficients. Next, the application of these local results to various reactor models described by PDEs is discussed. Specifically, we review the recent literature on the bifurcation features of convection-reaction and convection-diffusion-reaction models in one and more spatial dimensions, with emphasis on the features introduced due to coupling between the flow, heat and mass diffusion and chemical reaction. Finally, we illustrate the use of dynamical systems concepts in developing low dimensional (effective or pseudohomogeneous) models of reactors and reacting flows, and discuss some problems of current interest. (c) 1999 American Institute of Physics.

[1]  V. Balakotaiah,et al.  Modeling of reaction-induced flow maldistributions in packed beds , 1991 .

[2]  The effect of flow velocity on ignition and extinction in homogeneous-heterogeneous combustion , 1994 .

[3]  V. Balakotaiah,et al.  Transverse concentration and temperature nonuniformities in adiabatic packed-bed catalytic reactors , 1999 .

[4]  S. Shvartsman,et al.  One- and two-dimensional spatiotemporal thermal patterns in a fixed-bed reactor , 1995 .

[5]  W. Harmon Ray,et al.  The Bifurcation Behavior of Tubular Reactors. , 1982 .

[6]  A. J. Roberts,et al.  A centre manifold description of containment dispersion in channels with varying flow properties , 1990 .

[7]  Yoshiki Kuramoto,et al.  Chemical Oscillations, Waves, and Turbulence , 1984, Springer Series in Synergetics.

[8]  Rutherford Aris,et al.  An analysis of chemical reactor stability and control—I: The possibility of local control, with perfect or imperfect control mechanisms , 1958 .

[9]  Rovinsky,et al.  Self-organization induced by the differential flow of activator and inhibitor. , 1993, Physical review letters.

[10]  Milan Kubíček,et al.  Book-Review - Computational Methods in Bifurcation Theory and Dissipative Structures , 1983 .

[11]  Rovinsky,et al.  Chemical instability induced by a differential flow. , 1992, Physical review letters.

[12]  A. Poore A model equation arising from chemical reactor theory , 1973 .

[13]  F. W. Schneider,et al.  Chemical oscillations, chaos, and fluctuations in flow reactors , 1991 .

[14]  Rutherford Aris,et al.  Bifurcation behavior in homogeneous-heterogeneous combustion: II. Computations for stagnation-point flow☆ , 1991 .

[15]  Dan Luss,et al.  Mapping regions with different bifurcation diagrams of a reverse‐flow reactor , 1997 .

[16]  Hanns Hofmann,et al.  Modeling of chemical reactors — XVI Steady state axial heat and mass transfer in tubular reactors An analysis of the uniqueness of solutions , 1970 .

[17]  Vemuri Balakotaiah,et al.  Classification of steady-state and dynamic behavior of a well-mixed heterogeneous reactor model , 1997 .

[18]  L. Razon,et al.  Multiplicities and instabilities in chemically reacting systems — a review , 1987 .

[19]  David H. West,et al.  Analytical Criteria for Validity of Pseudohomogeneous Models of Packed-Bed Catalytic Reactors , 1999 .

[20]  Michael Menzinger,et al.  Differential-Flow-Induced Pattern Formation in the Exothermic A .fwdarw. B Reaction , 1994 .

[21]  Vemuri Balakotaiah,et al.  Multiplicity features of adiabatic autothermal reactors , 1992 .

[22]  V. Balakotaiah,et al.  Analysis and classification of reaction-driven stationary convective patterns in a porous medium , 1997 .

[23]  Vemuri Balakotaiah,et al.  Dispersion of chemical solutes in chromatographs and reactors , 1995, Philosophical Transactions of the Royal Society of London. Series A: Physical and Engineering Sciences.

[24]  Thomas F. Fairgrieve,et al.  AUTO 2000 : CONTINUATION AND BIFURCATION SOFTWARE FOR ORDINARY DIFFERENTIAL EQUATIONS (with HomCont) , 1997 .

[25]  Dan Luss,et al.  Complex dynamic features of a cooled reverse‐flow reactor , 1998 .

[26]  V. Balakotaiah,et al.  Convective instabilities induced by exothermic reactions occurring in a porous medium , 1994 .

[27]  Vemuri Balakotaiah,et al.  Effective models for packed-bed catalytic reactors , 1999 .

[28]  S. Wiggins Introduction to Applied Nonlinear Dynamical Systems and Chaos , 1989 .

[29]  Wave phenomena in the packed‐bed reactor: Their relation to the differential‐flow instability , 1996 .

[30]  G. Bunimovich,et al.  Reverse-Flow Operation in Fixed Bed Catalytic Reactors , 1996 .

[31]  A. B. Poore,et al.  On the dynamic behavior of continuous stirred tank reactors , 1974 .

[32]  V. Balakotaiah,et al.  Mode interactions in reaction-driven convection in a porous medium , 1995 .

[33]  V. Balakotaiah,et al.  Global mapping of parameter regions with a specific number of solutions , 1988 .

[34]  R. J. Field,et al.  Oscillations and Traveling Waves in Chemical Systems , 1985 .

[35]  Martin Golubitsky,et al.  A QUALITATIVE STUDY OF THE STEADY-STATE SOLUTIONS FOR A CONTINUOUS FLOW STIRRED TANK CHEMICAL REACTOR* , 1980 .

[36]  Dan Luss,et al.  Structure of the steady-state solutions of lumped-parameter chemically reacting systems , 1982 .

[37]  Dan Luss,et al.  Global analysis of the multiplicity features of multi-reaction lumped-parameter systems , 1984 .

[38]  Vemuri Balakotaiah,et al.  Classification of steady-state and dynamic behavior of distributed reactor models , 1996 .

[39]  Dan Luss,et al.  Multiplicity features of reacting systems. Dependence of the steady-states of a CSTR on the residence time , 1983 .

[40]  V. Balakotaiah,et al.  STEADY STATE MULTIPLICITY ANALYSIS OF LUMPED-PARAMETER SYSTEMS DESCRIBED BY A SET OF ALGEBRAIC EQUATIONS , 1985 .