1-(3-Chlorobenzoyl)-3-(2,3-dimethylphenyl)thiourea

The title molecule, C16H15ClN2OS, exists in the solid state in its thione form with typical thiourea C—S and C—O bonds lengths, as well as shortened C—N bonds. An intramolecular N—H⋯O hydrogen bond stabilizes the molecular conformation and intermolecular N—H⋯S hydrogen bonds link the molecules into centrosymmetric dimers. The dihedral angle between the aromatic rings is 50.18 (5)°.

[1]  Anthony L. Spek,et al.  Journal of , 1993 .

[2]  F. Allen The Cambridge Structural Database: a quarter of a million crystal structures and rising. , 2002, Acta crystallographica. Section B, Structural science.

[3]  R. Blessing,et al.  An empirical correction for absorption anisotropy. , 1995, Acta crystallographica. Section A, Foundations of crystallography.

[4]  Michael Bolte,et al.  1-(3-Chlorobenzoyl)-3-(2,4,6-trichlorophenyl)thiourea , 2006 .

[5]  G. Sheldrick A short history of SHELX. , 2008, Acta crystallographica. Section A, Foundations of crystallography.

[6]  A. Badshah,et al.  1-(3-Chloro­benzo­yl)-3-(3-chloro­phen­yl)thio­urea , 2006 .

[7]  A. Badshah,et al.  1-(3-Chloro­benzo­yl)-3-(2,4,6-trichloro­phen­yl)thio­urea , 2006 .

[8]  Michael Bolte,et al.  1-(3-Chlorobenzoyl)-3-phenylthiourea , 2006 .