EFFECTS OF DIMETHYOXYMETHANE BLENDING INTO DIESEL FUEL ON SOOT IN AN OPTICALLY ACCESSIBLE DI DIESEL ENGINE

Experiments were performed in an optically accessible DI diesel engine to investigate the effects of the addition of dimethoxymethane (DMM) to diesel fuel. The DMM was blended into the baseline diesel fuel to obtain 2% and 4% oxygen by fuel mass. Laser light extinction was used to measure soot variation during combustion as well as exhaust soot levels; NOx, CO2 and CO concentrations in the exhaust were measured using gas analyzers. In addition heat release analysis and direct photography were used to characterize the combustion process. The addition of DMM led to significant reductions in soot, but heat release analysis showed that it also caused significant changes in combustion characteristics, with increases of up to 1.7° of crank angle in ignition delay as well as increases in the fraction of premixed burn. Then, 2-ethylhexylnitrate was used to compensate for the effects on heat release characteristics to determine the relative importance of chemical and heat release effects in reducing soot. A fuel blend of 2,2-dimethylbutane in the diesel fuel was studied to estimate the effects of boiling point on soot and combustion characteristics.

[1]  R. Santoro,et al.  Suppression of soot formation in ethene laminar diffusion flames by chemical additives , 1994 .

[2]  S. Senkan,et al.  Effect of Oxygen Addition on Polycyclic Aromatic Hydrocarbon Formation in 1,3 Butadiene Counter-Flow Diffusion Flames , 2001 .

[3]  Robert W. Dibble,et al.  Methylal and Methylal-Diesel Blended Fuels for Use in Compression-Ignition Engines , 1999 .

[4]  T. Litzinger,et al.  Quantitative Imaging Study of the Effects of Intake Air Temperature on Soot Evolution in an Optically-Accessible D.I. Diesel Engine , 1994 .

[5]  Takeyuki Kamimoto,et al.  Combustion processes in diesel engines , 1991 .

[6]  W. J. D. Annand,et al.  Heat Transfer in the Cylinders of Reciprocating Internal Combustion Engines , 1963 .

[7]  J. Dec,et al.  The effect of water-emulsified fuel on diesel soot formation , 2000 .

[8]  Thomas A. Litzinger,et al.  Effects of oxygenated additives on aromatic species in fuel-rich, premixed ethane combustion: a modeling study , 2003 .

[9]  Leonard Kuo-Liang Shih,et al.  Comparison of the Effects of Various Fuel Additives on the Diesel Engine Emissions , 1998 .

[10]  T. Litzinger,et al.  Effects of dimethoxymethane and dimethylcarbonate on soot production in an optically-accessible DI diesel engine , 2000 .

[11]  E. C. Owens,et al.  Emissions comparison of alternative fuels in an advanced automotive diesel engine. Interim report, October 1997--April 1998 , 1998 .

[12]  Thomas A. Litzinger,et al.  A chemical kinetic modelling study of the mechanism of soot reduction by oxygenated additives in diesel engines , 2001 .

[13]  Takayuki Ito,et al.  Detailed Chemical Kinetic Modeling of Diesel Spray Combustion with Oxygenated Fuels , 2001 .

[14]  H. M. Spiers Technical data on fuel , 1930 .

[15]  Werner Hentschel,et al.  Time-Resolved Analysis of Soot Formation and Oxidation in a Direct-Injection Diesel Engine for Different EGR-Rates by an Extinction Method , 1995 .

[16]  Selim M. Senkan,et al.  Effects of oxygenate additives on polycyclic aromatic hydrocarbons(pahs) and soot formation , 2002 .

[17]  C. Westbrook,et al.  Diesel combustion: an integrated view combining laser diagnostics, chemical kinetics, and empirical validation , 1999 .

[18]  John E. Dec,et al.  Soot Distribution in a D.I. Diesel Engine Using 2-D Imaging of Laser-induced Incandescence, Elastic Scattering, and Flame Luminosity , 1992 .

[19]  Christoph Espey,et al.  Ignition and early soot formation in a DI diesel engine using multiple 2-D imaging diagnostics , 1995 .

[20]  Hongsheng Guo,et al.  The chemical effects of carbon dioxide as an additive in an ethylene diffusion flame: implications for soot and NOx formation , 2001 .

[21]  M. Thomson,et al.  The Effect of Oxygenated Additives on Soot Precursor Formation in a Counterflow Diffusion Flame , 1999 .

[22]  Robert W. Dibble,et al.  Emissions Performance of Oxygenate-in-Diesel Blends and Fischer-Tropsch Diesel in a Compression Ignition Engine , 1999 .

[23]  Takayuki Ito,et al.  Extraction of the suppression effects of oxygenated fuels on soot formation using a detailed chemical kinetic model , 2001 .

[24]  Pierre-Alexandre Glaude,et al.  Detailed Chemical Kinetic Modeling of Diesel Combustion with Oxygenated Fuels , 2001 .

[25]  M. Maricq,et al.  The Effect of Dimethoxy Methane Additive on Diesel Vehicle Particulate Emissions , 1998 .

[26]  T. H. Fleisch,et al.  A New Clean Diesel Technology: Demonstration of ULEV Emissions on a Navistar Diesel Engine Fueled with Dimethyl Ether , 1995 .

[27]  Thomas A. Litzinger,et al.  The Effects of Simulated EGR via Intake Air Dilution on Combustion in an Optically Accessible DI Diesel Engine , 1993 .

[28]  D. Daly,et al.  Combustion Modeling of Soot Reduction in Diesel and Alternate Fuels using CHEMKIN , 2001 .

[29]  K. T. Rhee,et al.  Engine Performance and Exhaust Characteristics of Direct-injection Diesel Engine Operated with DME , 1997 .