Predicting the Hydrate Stability Zones of Natural Gases Using Artificial Neural Networks

A feed-forward artificial neural network with 19 input variables (temperature, gas hydrate structure, gas composition and inhibitor concentration in aqueous phase) and 35 neurons in single hidden layer has been developed for estimating hydrate dissociation pressures of natural gases in the presence/absence of inhibitor aqueous solutions. The model has been developed using 3296 hydrate dissociation data gathered from the literature. The reliability of the method has been examined using independent experimental data (not used in training and developing the model). It is shown that the results of predictions are in acceptable agreement with experimental data indicating the capability of the artificial neural network for estimating hydrate stability zones of natural gases.

[1]  Roger Josef Zemp,et al.  Artificial neural networks for the solution of the phase stability problem , 2006 .

[2]  E. Frost,et al.  Gas hydrate composition and equilibrium data. [Direct and calculated measurements are in close agreement; CO/sub 2/, CH/sub 4/, C/sub 2/H/sub 6/, C/sub 3/H/sub 8/ used] , 1946 .

[3]  Donald B. Robinson,et al.  Hydrate formation in systems containing methane, ethane, propane, carbon dioxide or hydrogen sulfide in the presence of methanol , 1985 .

[4]  Fabien Rivollet Etude des propriétés volumétriques (PVT) d'hydrocarbures légers (C1-C4), du dioxyde de carbone et de l'hydrogène sulfuré. Mesures par densimétrie à tube vibrant et modélisation. , 2005 .

[5]  B. Tohidi,et al.  A novel predictive technique for estimating the hydrate inhibition effects of single and mixed thermodynamic inhibitors , 2008 .

[6]  Carolyn A. Koh,et al.  Clathrate hydrates of natural gases , 1990 .

[7]  E. Dendy Sloan,et al.  A changing hydrate paradigm—from apprehension to avoidance to risk management , 2005 .

[8]  D. Robinson,et al.  Hydrate Formation in Systems Containing Methane, Hydrogen Sulphide and Carbon Dioxide , 1967 .

[9]  Alan F. Murray,et al.  International Joint Conference on Neural Networks , 1993 .

[10]  Ali Elkamel,et al.  A new correlation for predicting hydrate formation conditions for various gas mixtures and inhibitors , 1998 .

[11]  D. Marquardt An Algorithm for Least-Squares Estimation of Nonlinear Parameters , 1963 .

[12]  D. Richon,et al.  Modeling of thermodynamic properties using neural networks: Application to refrigerants , 2002 .

[13]  G. D. Holder,et al.  Hydrate dissociation pressures of (methane + ethane + water) existence of a locus of minimum pressures , 1980 .

[14]  Dominique Richon,et al.  Enhancement of the extended corresponding states techniques for thermodynamic modeling. I. Pure fluids , 2006 .

[15]  Tao Xiong,et al.  A combined SVM and LDA approach for classification , 2005, Proceedings. 2005 IEEE International Joint Conference on Neural Networks, 2005..