Fibrous CdS/CdSe quantum dot co-sensitized solar cells based on ordered TiO2 nanotube arrays

A new kind of fibrous quantum dot sensitized solar cell has been designed and fabricated by using CdS and CdSe co-sensitized TiO(2) nanotubes on Ti wire as the photoanode and highly active Cu(2)S as the counter electrode. By optimizing the CdSe deposition time and the length of the nanotube, a power conversion efficiency of 3.18% has been obtained under AM 1.5 illumination (100 mW cm(-2)). The potential application of this kind of solar cell has also been discussed in this paper.

[1]  Anusorn Kongkanand,et al.  Quantum dot solar cells. Tuning photoresponse through size and shape control of CdSe-TiO2 architecture. , 2008, Journal of the American Chemical Society.

[2]  J. Bisquert,et al.  Improving the performance of colloidal quantum-dot-sensitized solar cells , 2009, Nanotechnology.

[3]  Low-Cost Flexible Nano-Sulfide/Carbon Composite Counter Electrode for Quantum-Dot-Sensitized Solar Cell , 2010, Nanoscale research letters.

[4]  F. Fabregat‐Santiago,et al.  Recombination in quantum dot sensitized solar cells. , 2009, Accounts of chemical research.

[5]  Kai Zhu,et al.  Enhanced charge-collection efficiencies and light scattering in dye-sensitized solar cells using oriented TiO2 nanotubes arrays. , 2007, Nano letters.

[6]  Yuh‐Lang Lee,et al.  Highly Efficient Quantum‐Dot‐Sensitized Solar Cell Based on Co‐Sensitization of CdS/CdSe , 2009 .

[7]  Jin Zhai,et al.  TiO(2) porous electrodes with hierarchical branched inner channels for charge transport in viscous electrolytes. , 2007, Chemphyschem : a European journal of chemical physics and physical chemistry.

[8]  Wonjoo Lee,et al.  Co-sensitization of vertically aligned TiO2 nanotubes with two different sizes of CdSe quantum dots for broad spectrum , 2008 .

[9]  Q. Shen,et al.  High efficiency of CdSe quantum-dot-sensitized TiO2 inverse opal solar cells , 2007 .

[10]  Valery Shklover,et al.  Nanocrystalline titanium oxide electrodes for photovoltaic applications , 2005 .

[11]  B. Fang,et al.  Hierarchical nanostructured spherical carbon with hollow core/mesoporous shell as a highly efficient counter electrode in CdSe quantum-dot-sensitized solar cells , 2010 .

[12]  Heejoon Ahn,et al.  The performance of coupled (CdS:CdSe) quantum dot-sensitized TiO2 nanofibrous solar cells , 2009 .

[13]  Chao Zhang,et al.  Fibrous flexible solid-type dye-sensitized solar cells without transparent conducting oxide , 2008 .

[14]  Chao Zhang,et al.  Wire‐Shaped Flexible Dye‐sensitized Solar Cells , 2008 .

[15]  Craig A. Grimes,et al.  A new benchmark for TiO2 nanotube array growth by anodization , 2007 .

[16]  A. Nozik Multiple exciton generation in semiconductor quantum dots , 2008 .

[17]  P. Liska,et al.  Fabrication of thin film dye sensitized solar cells with solar to electric power conversion efficiency over 10 , 2008 .

[18]  Yuh‐Lang Lee,et al.  Chemical bath deposition of CdS quantum dots onto mesoscopic TiO2 films for application in quantum-dot-sensitized solar cells , 2007 .

[19]  Junya Kobayashi,et al.  Effect of ZnS coating on the photovoltaic properties of CdSe quantum dot-sensitized solar cells , 2008 .

[20]  Craig A. Grimes,et al.  Synthesis and application of highly ordered arrays of TiO2 nanotubes , 2007 .

[21]  Xiaoming Huang,et al.  Application of carbon counterelectrode on CdS quantum dot-sensitized solar cells (QDSSCs) , 2010 .

[22]  Gary Hodes,et al.  Comparison of Dye-and Semiconductor-Sensitized Porous Nanocrystalline Liquid Junction Solar Cells , 2008 .

[23]  Juan Bisquert,et al.  CdSe Quantum Dot-Sensitized TiO2 Electrodes: Effect of Quantum Dot Coverage and Mode of Attachment , 2009 .

[24]  D. Cahen,et al.  Chemical bath deposited CdS/CdSe-sensitized porous TiO2 solar cells , 2006 .