Palladium Phosphinothiolato Complexes. Syntheses and Crystal Structures of Mononuclear [PdCl(SC(2)H(4)PPh(2))PPh(3)] and Binuclear [Pd(2)Cl(2)(&mgr;-SC(3)H(6)PPh(2))(2)] and Their Performance in Catalytic Carbonylation.