Enantioselective Addition of Methyllithium to Aromatic Imines Catalyzed by C2 Symmetric Tertiary Diamines.

[1]  M. Fiorini,et al.  Aminophosphine—Rhodium complexes as catalysts in asymmetric hydrogenation. The dependence of the enantioselectivity on the structure of the chiral ligands , 1979 .

[2]  Design and reactivity of topologically unique, chiral phosphonamides. Remarkable diastereofacial selectivity in asymmetric olefination and alkylation , 1984 .

[3]  Paul von Ragué Schleyer,et al.  Ab Initio Mechanisms for the Addition of CH3Li, HLi, and Their Dimers to Formaldehyde , 1985 .

[4]  K. Tomioka,et al.  Enantioface differentiation in cis dihydroxylation of carbon-carbon double bonds by osmium tetroxide using a chiral diamine with D2 symmetry , 1987 .

[5]  M. Hirama,et al.  Highly Enantioselective Dihydroxylation of Trans-Disubstituted and Monosubstituted Olefins , 1989 .

[6]  Kenji Koga,et al.  Novel strategy of using a C2 symmetric chiral diether in the enantioselective conjugate addition of an organolithium to an .alpha.,.beta.-unsaturated aldimine , 1989 .

[7]  K. Tomioka.  Asymmetric Synthesis Utilizing External Chiral Ligands , 1990 .

[8]  T. Shono,et al.  Electroorganic chemistry. 129. Electroreductive synthesis of chiral piperazines and enantioselective addition of diethylzinc to aldehydes in the presence of the chiral piperazines , 1991 .

[9]  A. Alexakis,et al.  A new reagent for the determination of the optical purity of primary, secondary, and tertiary chiral alcohols and of thiols , 1992 .

[10]  Steric tuning in chiral ligand mediated enantioselective alkylation of imines , 1993 .

[11]  K. Morokuma,et al.  Theoretical studies on the reaction of solvated methyllithium open dimer with aldehydes , 1993 .

[12]  Theoretical studies of nucleophilic additions of monomeric and dimeric organometallics , 1994 .

[13]  Kenji Koga,et al.  Asymmetric 1,2-addition of organolithiums to aldimines catalyzed by chiral ligand , 1994 .

[14]  J. Singh,et al.  Rhodium(I)-catalysed asymmetric hydrosilylation of ketones using new diferrocenyl dichalcogenides (R,S)-{[EC5H3CHMe(NMe2)]Fe(C5H5)}2(E = S, Se, Te), as chiral ligands , 1994 .

[15]  R. Pedrosa,et al.  Enantioselective ethylation of aldehydes catalyzed by chiral C2-symmetrical β-hydroxy-m-xylylene diamines , 1994 .

[16]  M. Lemaire,et al.  Asymmetric catalytic reduction of carbonyl compounds using C2 symmetric diamines as chiral ligands , 1995 .

[17]  B. Trost,et al.  Asymmetric Transition Metal-Catalyzed Allylic Alkylations. , 1996, Chemical reviews.

[18]  S. Denmark,et al.  Ligand-mediated addition of organometallic reagents to azomethine functions , 1996 .

[19]  K. Soai,et al.  Chiral amino alcohols bound to diimines, diamines and dendrimers as chiral ligands for the enantioselective ethylation of N-diphenylphosphinylimines , 1997 .

[20]  NakamuraEiichi,et al.  Open Dimer Participation in Chelation Controlled Addition of Methyllithium Dimer to α-and β-Alkoxy Aldehydes , 1997 .

[21]  T. Hense,et al.  Enantioselective Synthesis with Lithium/(−)‐Sparteine Carbanion Pairs , 1997 .

[22]  S. Hanessian,et al.  trans-1,2-Diaminocyclohexane Derivatives as Chiral Reagents, Scaffolds, and Ligands for Catalysis: Applications in Asymmetric Synthesis and Molecular Recognition. , 1997, Chemical reviews.

[23]  A. Yoshida,et al.  Conformational Control in Proton Sources for Enantioselective Protonation of Samarium Enolate Derived from α-Methoxy-Substituted Ketones , 1998 .

[24]  R. Bloch.  Additions of Organometallic Reagents to C=N Bonds: Reactivity and Selectivity , 1998 .

[25]  J. Larrow,et al.  (R,R)‐N,N′‐Bis(3,5‐di‐tert‐Butylsalicylidene)‐1,2‐Cyclohexanediamino Manganese(III) Chloride, A Highly Enantioselective Epoxidation Catalyst , 2003 .

[26]  K. Tomioka,et al.  Design, Synthesis, and Application of a C2 Symmetric Chiral Ligand for Enantioselective Conjugate Addition of Organolithium to α,β-Unsaturated Aldimine , 1998 .

[27]  C. Mioskowski,et al.  The Chemistry of Vicinal Diamines. , 1998, Angewandte Chemie.

[28]  O. Hoshino,et al.  Enantioselective radical-mediated reduction of α-alkyl-α-iododihydrocoumarins in the presence of a chiral magnesium iodide , 1999 .

[29]  S. Matsubara,et al.  Pinacol Coupling of Benzaldehyde with TiCl2-Amine , 1999 .

[30]  J. Laumer,et al.  Enantioselective Reduction of Ketones by Polymethylhydrosiloxane in the Presence of Chiral Zinc Catalysts , 1999 .

[31]  A. Alexakis,et al.  A New Efficient Synthesis of (R,R)-2,2′-Bipyrrolidine: An Interesting Chiral 1,2-Diamine with C2 Symmetry , 2000 .

[32]  M. Hasegawa,et al.  Facile Asymmetric Synthesis of α-Amino Acids Employing Chiral Ligand-Mediated Asymmetric Addition Reactions of Phenyllithium with Imines , 2000 .

[33]  A DFT theoretical analysis of aldehyde condensation pathways onto methyllithium, lithium dimethylamide, and their aggregates , 2000, The Journal of organic chemistry.

[34]  M. Hasegawa,et al.  A facile and efficient asymmetric synthesis of (+)-salsolidine , 2000 .

[35]  S. Arrasate,et al.  ChemInform Abstract: Synthesis of Enantiomerically Enriched Amines by Chiral Ligand Mediated Addition of Organolithium Reagents to Imines. , 2001 .

[36]  A. Alexakis,et al.  Diamine-catalyzed asymmetric Michael additions of aldehydes and ketones to nitrostyrene. , 2002, Organic letters.

[37]  A. Basu,et al.  Configurational stability and transfer of stereochemical information in the reactions of enantioenriched organolithium reagents. , 2002, Angewandte Chemie.

[38]  Carol A. Mulrooney,et al.  Enantioselective oxidative biaryl coupling reactions catalyzed by 1,5-diazadecalin metal complexes: efficient formation of chiral functionalized BINOL derivatives. , 2003, The Journal of organic chemistry.

[39]  Jean‐Claude Kizirian,et al.  Conceptually new chiral tertiary C2 symmetric diamines in asymmetric synthesis , 2003 .

[40]  A. Alexakis,et al.  Asymmetric Michael Addition of α-Hydroxyketones to Nitroolefins Catalyzed by Chiral Diamine , 2003 .

[41]  A. Alexakis,et al.  Enantioselective catalytic rearrangement of cyclohexene oxide with new homochiral bis-lithium amide bases , 2004 .