Fabrication of micro- and nanostructures in thin metallic films by femtosecond laser ablation

We report maskless microfabrication of periodic structures in thin metallic films by femtosecond laser ablation. Two-dimensional (2D) triangular arrays of circular apertures with diameter of about 0.6-0.8 μm and a lattice period of 1.0 and 2.0 μm were fabricated by single- and multiple laser pulse ablation of 35 nm thick gold films sputtered on glass substrates. Optical transmission spectra of the fabricated samples exhibit transmission bands at infrared wavelengths. Theoretical modeling of the optical properties by Finite-Difference Time-Domain (FDTD) technique indicates that these bands are associated with localized and propagating surface plasmon (SP) modes. FDTD simulations also indicate substantial resonant enhancement of the near-field intensity at the metal's surface. Laser ablation of thin metallic films is therefore a promising route for fast prototyping of planar metallic micro- and nano-structures applicable as frequency-selective surfaces (FSS) and SP substrates.

[1]  Saulius Juodkazis,et al.  Femtosecond Laser Microfabrication of Photonic Crystals , 2006 .

[2]  Keiji Sasaki,et al.  Spectrally-resolved atomic-scale length variations of gold nanorods. , 2006, Journal of the American Chemical Society.

[3]  Daniel Day,et al.  A microfluidic microreactor for the synthesis of gold nanorods. , 2009, Nanotechnology.

[4]  Perry,et al.  Nanosecond-to-femtosecond laser-induced breakdown in dielectrics. , 1996, Physical review. B, Condensed matter.

[5]  T. Kondow,et al.  Formation of Gold Nanoparticles by Laser Ablation in Aqueous Solution of Surfactant , 2001 .

[6]  Kevin Barraclough,et al.  I and i , 2001, BMJ : British Medical Journal.

[7]  W. Marsden I and J , 2012 .

[8]  Saulius Juodkazis,et al.  Spatially Selective Nonlinear Photopolymerization Induced by the Near-Field of Surface Plasmons Localized on Rectangular Gold Nanorods , 2009 .

[9]  Saulius Juodkazis,et al.  Three-dimensional woodpile photonic crystal templates for the infrared spectral range. , 2004, Optics letters.

[10]  H. Misawa,et al.  Nanoparticle plasmon-assisted two-photon polymerization induced by incoherent excitation source. , 2008, Journal of the American Chemical Society.

[11]  H. Misawa,et al.  Optical properties of nanoengineered gold blocks. , 2005, Optics letters.

[12]  Saulius Juodkazis,et al.  Nano-structured materials in plasmonics and photonics , 2008 .

[13]  Carsten Rockstuhl,et al.  Light propagation in a fishnet metamaterial , 2008 .

[14]  E. Hutter,et al.  Exploitation of Localized Surface Plasmon Resonance , 2004 .

[15]  Saulius Juodkazis,et al.  Spectral sensitivity of uniform arrays of gold nanorods to dielectric environment , 2007 .

[16]  Y. Shimotsuma,et al.  Self-organized nanogratings in glass irradiated by ultrashort light pulses. , 2003, Physical review letters.

[17]  T. Ebbesen,et al.  Optical transmission in perforated noble and transition metal films , 2006 .

[18]  John L. Volakis,et al.  Frequency‐selective surface based bandpass filters in the near‐infrared region , 2004 .

[19]  Ben A. Munk,et al.  Frequency Selective Surfaces: Theory and Design , 2000 .

[20]  Hiroshi Masuhara,et al.  Laser Ablation of Individual Gold Nanoparticles in Solution , 2007 .

[21]  Keiji Sasaki,et al.  Optical characterization of plasmonic metallic nanostructures fabricated by high-resolution lithography , 2007 .

[22]  Stefan Enoch,et al.  Role of shape and localized resonances in extraordinary transmission through periodic arrays of subwavelength holes: Experiment and theory , 2005 .

[23]  Tsuneo Mitsuyu,et al.  Photowritten optical waveguides in various glasses with ultrashort pulse laser , 1997 .

[24]  Saulius Juodkazis,et al.  Suppression of ripples on ablated Ni surface via a polarization grating. , 2009, Optics express.

[25]  Saulius Juodkazis,et al.  Crosstalk in Photoluminescence Readout of Three-Dimensional Memory in Vitreous Silica by One- and Two-Photon Excitation , 2000 .

[26]  R. W. Christy,et al.  Optical Constants of the Noble Metals , 1972 .

[27]  Saulius Juodkazis,et al.  Optical and ultrasonic signatures of femtosecond pulse filamentation in fused silica , 2009 .