Probing the Critical Region of Conductive Filament in Nanoscale HfO2 Resistive-Switching Device by Random Telegraph Signals

Resistive-switching random access memory (RRAM) is widely considered as a disruptive technology. Despite tremendous efforts in theoretical modeling and physical analysis, details of how the conductive filament (CF) in metal-oxide-based filamentary RRAM devices is modified during normal device operations remain speculative, because direct experimental evidence at defect level has been missing. In this paper, a random-telegraph-signal-based defect-tracking technique (RDT) is developed for probing the location and movements of individual defects and their statistical spatial and energy characteristics in the CF of state-of-the-art hafnium-oxide RRAM devices. For the first time, the critical filament region of the CF is experimentally identified, which is located near, but not at, the bottom electrode with a length of nanometer scale. We demonstrate with the RDT technique that the modification of this key constriction region by defect movements can be observed and correlated with switching operation conditions, providing insight into the resistive switching mechanism.

[1]  Hyuck-In Kwon,et al.  Extraction of trap location and energy from random telegraph noise in amorphous TiOx resistance random access memories , 2011 .

[2]  O. Richard,et al.  10×10nm2 Hf/HfOx crossbar resistive RAM with excellent performance, reliability and low-energy operation , 2011, 2011 International Electron Devices Meeting.

[3]  J. Yang,et al.  Anatomy of a Nanoscale Conduction Channel Reveals the Mechanism of a High‐Performance Memristor , 2011, Advanced materials.

[4]  R. Dittmann,et al.  Redox‐Based Resistive Switching Memories – Nanoionic Mechanisms, Prospects, and Challenges , 2009, Advanced materials.

[5]  M. Pickett,et al.  A scalable neuristor built with Mott memristors. , 2013, Nature materials.

[6]  D. Jeong,et al.  Emerging memories: resistive switching mechanisms and current status , 2012, Reports on progress in physics. Physical Society.

[7]  D. Strukov,et al.  Thermophoresis/diffusion as a plausible mechanism for unipolar resistive switching in metal–oxide–metal memristors , 2012, Applied Physics A.

[8]  X. Y. Liu,et al.  Oxide-based RRAM: Requirements and challenges of modeling and simulation , 2015, 2015 IEEE International Electron Devices Meeting (IEDM).

[9]  Chia-En Huang,et al.  Electron trapping effect on the switching behavior of contact RRAM devices through random telegraph noise analysis , 2010, 2010 International Electron Devices Meeting.

[10]  Gregory S. Snider,et al.  ‘Memristive’ switches enable ‘stateful’ logic operations via material implication , 2010, Nature.

[11]  R. Degraeve,et al.  RTN insight to filamentary instability and disturb immunity in ultra-low power switching HfOx and AlOx RRAM , 2013, 2013 Symposium on VLSI Technology.

[12]  Jason Cong,et al.  FPGA-RPI: A Novel FPGA Architecture With RRAM-Based Programmable Interconnects , 2014, IEEE Transactions on Very Large Scale Integration (VLSI) Systems.

[13]  F. A. Kröger,et al.  Relations between the concentrations of imperfections in solids , 1958 .

[14]  Pritish Narayanan,et al.  Experimental Demonstration and Tolerancing of a Large-Scale Neural Network (165 000 Synapses) Using Phase-Change Memory as the Synaptic Weight Element , 2014, IEEE Transactions on Electron Devices.

[15]  Tibor Grasser,et al.  Stochastic charge trapping in oxides: From random telegraph noise to bias temperature instabilities , 2012, Microelectron. Reliab..

[16]  J. Robertson,et al.  Materials selection for oxide-based resistive random access memories , 2014 .

[17]  Takuro Tamura,et al.  Rate-Limiting Processes Determining the Switching Time in a Ag2S Atomic Switch , 2010 .

[18]  Malgorzata Jurczak,et al.  Complementary Role of Field and Temperature in Triggering ON/OFF Switching Mechanisms in ${\rm Hf}/{\rm HfO}_{2}$ Resistive RAM Cells , 2013, IEEE Transactions on Electron Devices.

[19]  R. Dittmann,et al.  Resistive Switching Mechanisms on TaOx and SrRuO3 Thin-Film Surfaces Probed by Scanning Tunneling Microscopy. , 2016, ACS nano.

[20]  L. Goux,et al.  Dynamic ‘hour glass’ model for SET and RESET in HfO2 RRAM , 2012, 2012 Symposium on VLSI Technology (VLSIT).

[21]  L.W. Cheng,et al.  The observation of trapping and detrapping effects in high-k gate dielectric MOSFETs by a new gate current Random Telegraph Noise (IG-RTN) approach , 2008, 2008 IEEE International Electron Devices Meeting.

[22]  L. Chua Memristor-The missing circuit element , 1971 .

[23]  Shimeng Yu,et al.  Metal–Oxide RRAM , 2012, Proceedings of the IEEE.

[24]  Chrong Jung Lin,et al.  Modeling of electron conduction in contact resistive random access memory devices as random telegraph noise. , 2012, Journal of applied physics.

[25]  S. S. Chung,et al.  The physical insights into an abnormal erratic behavior in the resistance random access memory , 2013, 2013 IEEE International Reliability Physics Symposium (IRPS).

[26]  S. Ambrogio,et al.  Understanding switching variability and random telegraph noise in resistive RAM , 2013, 2013 IEEE International Electron Devices Meeting.

[27]  Investigation of random telegraph noise amplitudes in hafnium oxide resistive memory devices , 2014, 2014 IEEE International Reliability Physics Symposium.

[28]  Jae Sung Lee,et al.  Resistive switching phenomena: A review of statistical physics approaches , 2015 .

[29]  O. Richard,et al.  Imaging the Three-Dimensional Conductive Channel in Filamentary-Based Oxide Resistive Switching Memory. , 2015, Nano letters.

[30]  S. O. Park,et al.  Highly scalable nonvolatile resistive memory using simple binary oxide driven by asymmetric unipolar voltage pulses , 2004, IEDM Technical Digest. IEEE International Electron Devices Meeting, 2004..

[31]  M. J. Kirton,et al.  Noise in solid-state microstructures: A new perspective on individual defects, interface states and low-frequency (1/ƒ) noise , 1989 .

[32]  R. Waser,et al.  Nanoionics-based resistive switching memories. , 2007, Nature materials.

[33]  Kinam Kim,et al.  In situ observation of filamentary conducting channels in an asymmetric Ta2O5−x/TaO2−x bilayer structure , 2013, Nature Communications.

[34]  Wilfried Vandervorst,et al.  Three-dimensional observation of the conductive filament in nanoscaled resistive memory devices. , 2014, Nano letters.

[35]  Andrea Padovani,et al.  A Complete Statistical Investigation of RTN in HfO2-Based RRAM in High Resistive State , 2015, IEEE Transactions on Electron Devices.