Rubber, 2. Natural

The article contains sections titled: 1. Introduction 2. Rubber Extraction 3. Composition of Natural Rubber Latex 4. Biosynthesis of Natural Rubber 5. Commercial Extraction of Natural Latex 6. Production of Natural Rubber 6.1. Extraction by Evaporation of Water (Evaporation, Spray Drying) 6.2. Coagulation 7. Classification 7.1. Technically Classified (TC) Rubber 7.2. Standard Malaysian Rubber (SMR) 7.3. Standardized Indonesian Rubber (SIR) 8. Physical and Technological Properties of Solid Rubber 9. Uses 10. Modification 10.1. Hydrogenated Natural Rubber 10.2. Chlorinated Natural Rubber 10.3. Hydrohalogenated Natural Rubber 10.4. Cyclized Natural Rubber 10.5. Resin-Modified Natural Rubber 10.6. Poly(Methyl Methacrylate)-Grafted Natural Rubber 10.7. Superior-Processing Natural Rubber 10.8. N-Phenylcarbamoylazoformate-Modified Natural Rubber 10.9. Polystyrene-Grafted Natural Rubber 10.10. Epoxidized Natural Rubber (ENR) 10.11. Degraded Natural Rubber 10.12. Thermoplastic Natural Rubber 11. Compounding 12. Summary

[1]  J. Cunneen,et al.  New methods of crosslinking natural rubber. Part I. The introduction of carboxylic acid and ester groups into natural rubber and their subsequent utilization for crosslinking , 1960 .

[2]  H. Hoffmann The Ene Reaction , 1969 .

[3]  B. C. Sekhar Degradation and crosslinking of polyisoprene in Hevea Brasiliensis latex during processing and storage , 1960 .

[4]  F. W. Shipley,et al.  cis‐trans Isomerization in polyisoprenes. Part I. Improvement of the low temperature properties of natural rubber by reaction with thiol acids in solution and in latex , 1959 .

[5]  P. W. Allen,et al.  Polymerization of methyl methacrylate in polyisoprene solutions , 1956 .

[6]  D. Campbell,et al.  Preparation of polydiene-g-polystyrene graft copolymers , 1978 .

[7]  I. Gelling,et al.  Sulfur vulcanization and oxidative aging of epoxidized natural rubber , 1985 .

[8]  C. Harries Untersuchungen über die natürlichen und künstlichen Kautschukarten , 1919 .

[9]  P. D. Abraham,et al.  Stimulation of Latex Flow in Hevea Brasiliensis by 4-Amino—3,5,6-Trichloropicolinic Acid and 2-Chloroethanephosphonic Acid , 1972 .

[10]  W. H. Buck,et al.  Block and Graft Copolymers of Pivalolactone. I. A New Class of Elastoplastics and Thermoplastic Elastomers , 1976 .

[11]  I. Gelling Modification of Natural Rubber Latex with Peracetic Acid , 1985 .

[12]  H. Koch,et al.  128. Rubber, polyisoprenes and allied compounds. Part V. The chemical linking of rubber and of other olefins with phenol–formaldehyde resins , 1943 .

[13]  C. O. Weber Ueber die Natur des Kautschuks , 1900 .

[14]  H. Staudinger,et al.  Über Isopren und Kautschuk, 41. Mitteil.: Über die Hydrierung von Kautschuk und Balata , 1934 .

[15]  S. Wolfe,et al.  Strain crystallization in random copolymers produced by epoxidation of cis 1,4-polyisoprene , 1983 .

[16]  H. W. Jacobson,et al.  Block and Graft Copolymers of Pivalolactone. II. ABA and ABA-g-A Copolymers with Dienes , 1976 .

[17]  J. Scanlan The interaction of polymerizing systems with rubber and its homologues. Part 1.—The effect of dihydromyrcene on the polymerization of styrene, methyl methacrylate, methyl acrylate and vinyl acetate , 1954 .

[18]  A. Y. Coran,et al.  Rubber-Thermoplastic Compositions. Part I. EPDM-Polypropylene Thermoplastic Vulcanizates , 1980 .

[19]  C. Harries Über die Hydrohalogenide der künstlichen und natürlichen Kautschukarten und die daraus regenerierbaren kautschukähnlichen Stoffe , 1913 .

[20]  E. Buckler,et al.  Transient Changes in Topology and Energy on Extension of Polybutadiene Networks , 1967 .

[21]  P. Flory,et al.  Dependence of elastic properties of vulcanized rubber on the degree of cross linking , 1949 .

[22]  T. Colclough,et al.  The aminolysis and esterification of unsymmetrical epoxides , 1961 .

[23]  G. J. V. Amerongen,et al.  The Permeability of Different Rubbers to Gases and Its Relation to Diffusivity and Solubility , 1946 .

[24]  S. Ng,et al.  Reaction of natural rubber latex with performic acid , 1981 .

[25]  E. Garner,et al.  135. The crystal structure of rubber hydrochloride , 1942 .

[26]  H. L. Fisher Conversion of Rubber into Thermoplastic Products with Properties Similar to Gutta-Percha,Balata, and Shellac , 1927 .

[27]  G. Kraus,et al.  Chlorination of Natural and Synthetic Polyisoprenes , 1950 .

[28]  G. F. Bloomfield 80. Rubber, polyisoprenes, and allied compounds. Part IV. The relative tendencies towards substitutive and additive reaction during chlorination , 1943 .

[29]  J. Pendleton,et al.  New Thermoplastic Elastomers. Styrene Grafts on Lithiated Polydienes and Their Hydrogenated Counterparts , 1973 .

[30]  P. W. Allen,et al.  The interaction of polymerizing systems with rubber and its homologues. Part 3.—Transfer and retardation in the polymerization of vinyl acetate , 1955 .

[31]  F. Kirchhof Ueber die Einwirkung von konzentrierter Schwefelsäure auf natürliche und künstliche Kautschukarten , 1920 .

[32]  C. Harries Über Aggregation und Desaggregation. Hydrolyse des Schellackharzes. Hydrierung des Kautschuks , 1923 .

[33]  P. W. Allen,et al.  The interaction of polymerizing systems with rubber and its homologues. Part 4.—Acrylonitrile , 1958 .

[34]  F. Hinrichsen,et al.  Beiträge zur Chemie des Kautschuks. III. Über die Additionsverbindungen des Kautschuks mit Halogenwasserstoffsäuren und Halogenen , 1913 .

[35]  C. S. L. Baker,et al.  New Reactions for the Vulcanization of Natural Rubber , 1970 .