Solid Oxide Fuel Cells coupled with a biomass gasification unit

A possibility of fuelling a solid oxide fuel cell stack (SOFC) with biomass fuels can be realized by coupling a SOFC system with a self-standing gasification unit. Such a solution enables multi-fuel operation, elasticity of the system as well as the increase of the efficiency of small-scale biomass-to-electricity conversion units. A system of this type, consisting of biomass gasification unit, gas purification unit, SOFC stack, anode off-gas afterburner and peripherals was constructed and operated successfully. During the process, biomass fuel (wood chips) was gasified with air as gasification agent. The gasifier was capable of converting up to 30 kW of fuel to syngas with efficiencies up to 75%. Syngas leaving the gasification unit is delivered to a medium temperature adsorber for sulphur compounds removal. Steam is added to the purified fuel to maintain steam to carbon ratio higher than 2. The syngas then is passed to a SOFC stack through a fuel preheater. In such a configuration it was possible to operate a commercial 1.3 kW stack within its working regime. Conducted tests confirmed successful operation of a SOFC stack fuelled by biomass-sourced syngas.

[1]  George E. Marnellos,et al.  From biomass to electricity through integrated gasification/SOFC system-optimization and energy balance , 2007 .

[2]  Saffa Riffat,et al.  Development of small-scale and micro-scale biomass-fuelled CHP systems – A literature review , 2009 .

[3]  Nigel P. Brandon,et al.  Use of gasification syngas in SOFC: Impact of real tar on anode materials , 2012 .

[4]  Jakub Kupecki,et al.  Use of NaNiCl battery for mitigation of SOFC stack cycling in base-load telecommunication power system - a preliminary evaluation , 2016 .

[5]  S. Sieniutycz,et al.  Power generation in thermochemical and electrochemical systems – A thermodynamic theory , 2012 .

[6]  Nigel P. Brandon,et al.  Modelling system efficiencies and costs of two biomass-fuelled SOFC systems , 2004 .

[7]  I. Yentekakis,et al.  Open-and closed-circuit study of an intermediate temperature SOFC directly fueled with simulated biogas mixtures , 2006 .

[8]  I. Dincer,et al.  Effect of gasification agent on the performance of solid oxide fuel cell and biomass gasification systems , 2010 .

[9]  Jarosław Milewski,et al.  Dynamic numerical analysis of cross-, co-, and counter-current flow configuration of a 1 kW-class solid oxide fuel cell stack , 2015 .

[10]  Stefano Cordiner,et al.  Biomass fueling of a SOFC by integrated gasifier: Study of the effect of operating conditions on system performance , 2013 .

[11]  Erich Podesser Electricity production in rural villages with a biomass Stirling engine , 1999 .

[12]  M. J. Huang,et al.  Comparative techno-economic analysis of biomass fuelled combined heat and power for commercial buildings , 2013 .

[13]  Hiroshi Iwai,et al.  Performance evaluation of an integrated small-scale SOFC-biomass gasification power generation system , 2012 .