Internally and Partially Heat-Integrated Distillation System for Ternary Separation

A partially heat-integrated distillation system is introduced for ternary separation. The lower section of the first column and the upper section of the second column in a conventional two column system for a ternary separation are thermally integrated using an internally heat-integrated column. The proposed system has been applied to two example processes, hexane and BTX processes, for performance evaluation, and heat duty savings of 17.1% and 16.7%, respectively, are yielded from the proposed system. However, the comparison of entropy production rate between the proposed and conventional systems is split in the two processes. Though the heat integration is partial in the proposed system, no compressor is required, making the column operation easier than the fully heat-integrated system of binary separation.

[1]  Y. H. Kim A new fully thermally coupled distillation column with postfractionator , 2006 .

[2]  J. P. Schmal,et al.  Internal Versus External Heat Integration: Operational and Economic Analysis , 2006 .

[3]  Sigurd Skogestad,et al.  Operation of Integrated Three-Product (Petlyuk) Distillation Columns , 1995 .

[4]  Yasuki Kansha,et al.  Self-Heat Recuperation Technology for Energy Saving in Chemical Processes , 2009 .

[5]  Karl Heinz Hoffmann,et al.  Comparison of entropy production rate minimization methods for binary diabatic distillation , 2002 .

[6]  Masaru Nakaiwa,et al.  Internally Heat-Integrated Distillation Columns: A Review , 2003 .

[7]  Laureano Jiménez,et al.  A thermo-hydraulic approach to conceptual design of an internally heat-integrated distillation column (i-HIDiC) , 2007, Comput. Chem. Eng..

[8]  Signe Kjelstrup,et al.  The second law optimal state of a diabatic binary tray distillation column , 2005 .

[9]  W. Luyben Dynamics and control of recycle systems. 2. Comparison of alternative process designs , 1993 .

[10]  Kejin Huang,et al.  Externally Heat-Integrated Double Distillation Column (EHIDDiC): Basic Concept and General Characteristics , 2010 .

[11]  Kyu Suk Hwang,et al.  Application of a fully thermally coupled distillation column for fractionation process in naphtha reforming plant , 2004 .

[12]  B. Linnhoff,et al.  The pinch design method for heat exchanger networks , 1983 .

[13]  Kejin Huang,et al.  A Simplified Scheme of Externally Heat-Integrated Double Distillation Columns (EHIDDiC) with Three External Heat Exchangers , 2010 .

[14]  C. Triantafyllou,et al.  The design and optimisation of fully thermally coupled distillation columns : Process design , 1992 .

[15]  Francesca Ferrara,et al.  Design of heat integrated distillation systems for a light ends separation plant , 2007 .

[16]  R. Rivero,et al.  Simulation, exergy analysis and application of diabatic distillation to a tertiary amyl methyl ether production unit of a crude oil refinery , 2004 .