Site-selective NMR measurements in single crystal PrNb2Al20

We report the result and analysis of the nuclear magnetic resonance (NMR) measurements at the magnetic field of 8.57 T and temperature of 80 K using a single crystal PrNb2Al20. Combining the field angle dependence of NMR spectra, numerical simulation, and band calculation, we deconvoluted the NMR signals from the Nb, Al 48 f, and Al 96g sites. Unfortunately, the overlapping of NMR lines prevents us to extract the NMR signals from the Al 16c site. However, the obtained nuclear quadrupole resonance (NQR) parameters for the Nb and Al 48f sites are consistent with the previous reports [T. Kubo et al., 2014 JPS Conf. Proc. 3 012031; 2015 J. Phys.: Conf. Ser. 592 012093; 2016 J. Phys. Conf.: Ser. 683 012015] and for the Al 96g site are refined to be vQ = 0.98 MHz and η = 0.46.

[1]  S. Nakatsuji,et al.  Single crystal 27Al-NMR study of the cubic Γ3 ground doublet system PrTi2Al20 , 2015, 1512.00974.

[2]  Y. Aoki,et al.  Absence of Magnetic Dipolar Phase Transition and Evolution of Low-Energy Excitations in PrNb 2 Al 20 with Crystal Electric Field Γ 3 Ground State: Evidence from 93 Nb-NQR Studies , 2015 .

[3]  S. Nakatsuji,et al.  Heavy-fermion superconductivity in the quadrupole ordered state of PrV2Al20. , 2014, Physical review letters.

[4]  Y. Tokunaga,et al.  Magnetic excitations and c - f hybridization effect in PrTi 2 Al 20 and PrV 2 Al 20 , 2013 .

[5]  S. Nakatsuji,et al.  Superconductivity in the Ferroquadrupolar State in the Quadrupolar Kondo Lattice PrTi2Al20 , 2012, 1207.0215.

[6]  Fujio Izumi,et al.  VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data , 2011 .

[7]  Nakatsuji Satoru,et al.  Kondo Effects and Multipolar Order in the Cubic PrTr2Al20 (Tr=Ti, V) , 2011 .

[8]  T. Sakakibara,et al.  Antiferroquadrupolar ordering in a Pr-based superconductor PrIr(2)Zn(20). , 2011, Physical review letters.

[9]  S. Nakatsuji,et al.  Kondo Effects and Multipolar Order in the cubic PrTr2Al20 (Tr=Ti, V) , 2011, 1104.4167.

[10]  Makoto Watanabe,et al.  Single Crystal Growth and Low Temperature Properties of PrNb2Al20 , 2011 .

[11]  P. Pyykkö Year-2008 nuclear quadrupole moments , 2008 .

[12]  P. Granger,et al.  Further conventions for NMR shielding and chemical shifts (IUPAC Recommendations 2008) , 2008, Magnetic resonance in chemistry : MRC.

[13]  Takigawa Masashi,et al.  On the Symmetry of Low-Field Ordered Phase of PrFe4P12: 31P NMR , 2007 .

[14]  H. Harima,et al.  Hyperfine Interactions in the Heavy-Fermion Superconductor UBe13: 9Be NMR Studies , 2007 .

[15]  Y. Kuramoto,et al.  Scalar Order : Possible Candidate for Order Parameters in Skutterudites(Condensed matter: electronic structure and electrical, magnetic, and optical properties) , 2006, 0804.2521.

[16]  I. Satoh,et al.  Anomalous Enhancement of Nuclear Spin Relaxation Rates of 109Ag and 115In at Low Temperatures in Cubic Γ3 Ground-State System PrAg2In –First Observation of Octupole Fluctuations of f-Electrons– , 2006 .

[17]  H. Harima EFG at Sb site of filled skutterudites , 2006 .

[18]  H. Shiba,et al.  A New Interpretation of NMR in Quadrupolar Ordering Phase of CeB6 - Consistency with Neutron Scattering - , 1997 .