Three-dimensional amorphous tungsten-doped nickel phosphide microsphere as an efficient electrocatalyst for hydrogen evolution

Amorphous tungsten-doped nickel phosphide (a-WNP) microspheres with three-dimensional (3D) ravine-like nanostructures on the surface were successfully fabricated via a fast and facile grain-mediated electroless method. The resulting W-doped NixP exhibits an outstanding electrocatalytic activity for hydrogen evolution reaction with a low onset potential of −50 mV, overpotential of 110 mV at 20 mA cm−2, and small Tafel slope of 39 mV dec−1. The amorphous architecture and the doping of W are considered to be major contributions for the improvement of catalytic performance. The results in this paper might promote a new route to gain both amorphous and doped materials with special electrochemical properties for advanced catalysts and other devices.

[1]  Ping Liu,et al.  Catalysts for hydrogen evolution from the [NiFe] hydrogenase to the Ni2P(001) surface: the importance of ensemble effect. , 2005, Journal of the American Chemical Society.

[2]  D. Portehault,et al.  Nanoscaled metal borides and phosphides: recent developments and perspectives. , 2013, Chemical reviews.

[3]  Nathan S Lewis,et al.  Highly active electrocatalysis of the hydrogen evolution reaction by cobalt phosphide nanoparticles. , 2014, Angewandte Chemie.

[4]  G. Huber,et al.  Raney Ni-Sn Catalyst for H2 Production from Biomass-Derived Hydrocarbons , 2003, Science.

[5]  J. Hargreaves,et al.  Alternative catalytic materials: carbides, nitrides, phosphides and amorphous boron alloys. , 2010, Chemical Society reviews.

[6]  B. V. Tilak,et al.  Interfacial processes involving electrocatalytic evolution and oxidation of H2, and the role of chemisorbed H , 2002 .

[7]  G. Yin,et al.  Tungsten doped Co–Se nanocomposites as an efficient non precious metal catalyst for oxygen reduction , 2013 .

[8]  J. Yu,et al.  Effects of annealing temperature on the crystal structure and properties of electroless deposited Ni-W-Cr-P alloy coatings , 2008 .

[9]  G. Eda,et al.  Conducting MoS₂ nanosheets as catalysts for hydrogen evolution reaction. , 2013, Nano letters.

[10]  R. E. Schaak,et al.  Trioctylphosphine: A General Phosphorus Source for the Low-Temperature Conversion of Metals into Metal Phosphides , 2007 .

[11]  Taotao Zhuang,et al.  Mixed-solution synthesis of sea urchin-like NiSe nanofiber assemblies as economical Pt-free catalysts for electrochemical H2 production , 2012 .

[12]  Mietek Jaroniec,et al.  N-doped graphene film-confined nickel nanoparticles as a highly efficient three-dimensional oxygen evolution electrocatalyst , 2013 .

[13]  K. Hashimoto,et al.  Hydrogen evolution by tungsten carbonitride nanoelectrocatalysts synthesized by the formation of a tungsten acid/polymer hybrid in situ. , 2013, Angewandte Chemie.

[14]  H. Vrubel,et al.  Fe, Co, and Ni ions promote the catalytic activity of amorphous molybdenum sulfide films for hydrogen evolution , 2012 .

[15]  Guosong Hong,et al.  MoS2 nanoparticles grown on graphene: an advanced catalyst for the hydrogen evolution reaction. , 2011, Journal of the American Chemical Society.

[16]  Qian Liu,et al.  Closely Interconnected Network of Molybdenum Phosphide Nanoparticles: A Highly Efficient Electrocatalyst for Generating Hydrogen from Water , 2014, Advanced materials.

[17]  G. Meisner,et al.  The pressure dependence of the superconducting transition temperature of LaT4P12(T = Fe, Ru, Os) , 1985 .

[18]  Daniel B. Miracle.  A structural model for metallic glasses , 2004 .

[19]  James R. McKone,et al.  Ni–Mo Nanopowders for Efficient Electrochemical Hydrogen Evolution , 2013 .

[20]  A. Frenkel,et al.  Hydrogen-evolution catalysts based on non-noble metal nickel-molybdenum nitride nanosheets. , 2012, Angewandte Chemie.

[21]  Xiaoming Ge,et al.  Molybdenum phosphide as an efficient electrocatalyst for the hydrogen evolution reaction , 2014 .

[22]  James R. McKone,et al.  Solar water splitting cells. , 2010, Chemical reviews.

[23]  F. Tao,et al.  Synthesis and catalysis of chemically reduced metal-metalloid amorphous alloys. , 2012, Chemical Society reviews.

[24]  Xile Hu,et al.  Recent developments of molybdenum and tungsten sulfides as hydrogen evolution catalysts , 2011 .

[25]  Hisato Yamaguchi,et al.  Enhanced catalytic activity in strained chemically exfoliated WS₂ nanosheets for hydrogen evolution. , 2012, Nature Materials.

[26]  Yi Chen.  Chemical preparation and characterization of metal–metalloid ultrafine amorphous alloy particles , 1998 .

[27]  James R. McKone,et al.  Nanostructured nickel phosphide as an electrocatalyst for the hydrogen evolution reaction. , 2013, Journal of the American Chemical Society.

[28]  Abdullah M. Asiri,et al.  Self-supported nanoporous cobalt phosphide nanowire arrays: an efficient 3D hydrogen-evolving cathode over the wide range of pH 0-14. , 2014, Journal of the American Chemical Society.

[29]  Shuhong Yu,et al.  Nickel/nickel(II) oxide nanoparticles anchored onto cobalt(IV) diselenide nanobelts for the electrochemical production of hydrogen. , 2013, Angewandte Chemie.

[30]  Harry B Gray,et al.  Powering the planet with solar fuel. , 2009, Nature chemistry.

[31]  N. Pradhan,et al.  Semiconducting and plasmonic copper phosphide platelets. , 2013, Angewandte Chemie.

[32]  Lain-Jong Li,et al.  Highly Efficient Electrocatalytic Hydrogen Production by MoSx Grown on Graphene‐Protected 3D Ni Foams , 2013, Advanced materials.

[33]  John A. Turner,et al.  Sustainable Hydrogen Production , 2004, Science.

[34]  S. Siffert,et al.  Total oxidation of toluene over noble metal based Ce, Fe and Ni doped titanium oxides , 2014 .

[35]  H. Shin,et al.  Recent advances in layered transition metal dichalcogenides for hydrogen evolution reaction , 2014 .

[36]  S. Kauzlarich,et al.  Colossal Magnetoresistance in a Rare Earth Zintl Compound with a New Structure Type: EuIn2P2 , 2006 .

[37]  X. Lou,et al.  Defect‐Rich MoS2 Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution , 2013, Advanced materials.

[38]  H. Shin,et al.  Two-dimensional hybrid nanosheets of tungsten disulfide and reduced graphene oxide as catalysts for enhanced hydrogen evolution. , 2013, Angewandte Chemie.

[39]  H. Vrubel,et al.  Amorphous molybdenum sulfide films as catalysts for electrochemical hydrogen production in water , 2011 .

[40]  B. Pan,et al.  Controllable disorder engineering in oxygen-incorporated MoS2 ultrathin nanosheets for efficient hydrogen evolution. , 2013, Journal of the American Chemical Society.

[41]  A. Fery,et al.  Sonochemical Activation of Al/Ni Hydrogenation Catalyst , 2012 .

[42]  Kangnian Fan,et al.  Characterization and catalytic behavior of highly active tungsten-doped SBA-15 catalyst in the synthesis of glutaraldehyde using an anhydrous approach , 2007 .

[43]  J. Cabana,et al.  Beyond Intercalation‐Based Li‐Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions , 2010, Advanced materials.

[44]  H. Vrubel,et al.  Molybdenum boride and carbide catalyze hydrogen evolution in both acidic and basic solutions. , 2012, Angewandte Chemie.