Direct Methanol Fuel Cells

Abstract Direct methanol fuel cells are suitable power sources for a range of mobile applications, due to the convenience of storage of the liquid fuel. The chapter reviews the principles of operation and models which have been developed to create viable methanol powered fuel cells. In particular models which consider the dynamic response of power and thermal behavior are reviewed to aid in development of control strategies. The DMFC responds quite rapidly to changes in operating conditions and is a suitable power source for portable applications where variations in operating conditions arise.

[1]  W. M. Taama,et al.  An investigation of scale-up on the response of the direct methanol fuel cell under variable load conditions , 2001 .

[2]  D. Jung,et al.  Performance of a direct methanol polymer electrolyte fuel cell , 1998 .

[3]  Kai Sundmacher,et al.  Direct methanol polymer electrolyte fuel cell : analysis of charge and mass transfer in the vapour-liquid-solid system , 1999 .

[4]  Shimshon Gottesfeld,et al.  Methanol transport through Nafion membranes : Electro-osmotic drag effects on potential step measurements , 2000 .

[5]  K. Scott,et al.  Transient Response and Steady-State Analysis of the Anode of Direct Methanol Fuel Cells Based on Dual-Site Kinetics , 2011 .

[6]  H. Gasteiger,et al.  Temperature‐Dependent Methanol Electro‐Oxidation on Well‐Characterized Pt‐Ru Alloys , 1994 .

[7]  V. S. Bagotzky,et al.  Generalized scheme of chemisorption, electrooxidation and electroreduction of simple organic compounds on platinum group metals , 1977 .

[8]  Bing-Joe Hwang,et al.  Investigations of direct methanol fuel cell (DMFC) fading mechanisms , 2007 .

[9]  Lei Zhang,et al.  A review of anode catalysis in the direct methanol fuel cell , 2006 .

[10]  E. Martin,et al.  A kinetic model for the direct methanol fuel cell anode based on surface coverage , 2006 .

[11]  D. Wilkinson,et al.  Aging mechanisms and lifetime of PEFC and DMFC , 2004 .

[12]  Eric Carlson,et al.  Cost Analysis of PEM Fuel Cell Systems for Transportation: September 30, 2005 , 2005 .

[13]  Ya-Ling He,et al.  Two-phase modeling of mass transfer characteristics of a direct methanol fuel cell , 2009 .

[14]  Hang Guo,et al.  Dynamic Characteristics of a Direct Methanol Fuel Cell , 2006 .

[15]  Ulrike Krewer,et al.  Non-isothermal dynamic modelling and optimization of a direct methanol fuel cell , 2008 .

[16]  E. Modica,et al.  Development and operation of a 150 W air-feed direct methanol fuel cell stack , 2001 .

[17]  Wenpeng Liu,et al.  Three-Dimensional Simulations of Liquid Feed Direct Methanol Fuel Cells , 2007 .

[18]  Ulrike Krewer,et al.  Direct methanol fuel cell (DMFC) : analysis of residence time behaviour of anodic flow bed , 2004 .

[19]  E. A. Lewis,et al.  Catalyst failure analysis of a direct methanol fuel cell membrane electrode assembly , 2008 .

[20]  Jeremy P. Meyers,et al.  Simulation of the Direct Methanol Fuel Cell III. Design and Optimization , 2002 .

[21]  Nam-Trung Nguyen,et al.  Micromachined polymer electrolyte membrane and direct methanol fuel cells—a review , 2006 .

[22]  Sadik Kakac,et al.  Two‐dimensional model for proton exchange membrane fuel cells , 1998 .

[23]  Antonino S. Aricò,et al.  Methanol oxidation on carbon-supported platinum-tin electrodes in sulfuric acid , 1994 .

[24]  Kai Sundmacher,et al.  A model for the liquid feed direct methanol fuel cell , 1999 .

[25]  A. Kulikovsky,et al.  The voltage–current curve of a direct methanol fuel cell: “exact” and fitting equations , 2002 .

[26]  Kai Sundmacher,et al.  Current Status of and Recent Developments in the Direct Methanol Fuel Cell , 2001 .

[27]  Brian E. Conway,et al.  Modern Aspects of Electrochemistry , 1974 .

[28]  W. Preidel,et al.  Status of the development of a direct methanol fuel cell , 1999 .

[29]  V. S. Bagotzky,et al.  Mechanism of electro-oxidation of methanol on the platinum electrode☆ , 1967 .

[30]  Shimshon Gottesfeld,et al.  Fuel cell techno-personal milestones 1984–2006 , 2007 .

[31]  E. Martin,et al.  Simplified model for the direct methanol fuel cell anode , 2007 .

[32]  C. Pu,et al.  Methanol Oxidation on Single‐Phase Pt‐Ru‐Os Ternary Alloys , 1997 .

[33]  Chao-Yang Wang,et al.  Fundamental models for fuel cell engineering. , 2004, Chemical reviews.

[34]  M. Verbrugge Methanol Diffusion in Perfluorinated Ion‐Exchange Membranes , 1989 .

[35]  A. Shukla,et al.  A 5 W liquid-feed solid-polymer-electrolyte direct methanol fuel cell stack with stainless steel , 1999 .

[36]  Kai Sundmacher,et al.  Limiting current behaviour of the direct methanol fuel cell , 1999 .

[37]  W. Visscher,et al.  Measurement of the Ru surface content of electrocodeposited PtRu electrodes with the electrochemical quartz crystal microbalance : Implications for methanol and CO electrooxidation , 1996 .

[38]  Shimshon Gottesfeld,et al.  Electro‐osmotic Drag of Water in Ionomeric Membranes New Measurements Employing a Direct Methanol Fuel Cell , 1997 .

[39]  Christopher Hebling,et al.  Fuel Cells for Low Power Applications , 2002 .

[40]  A. Shukla,et al.  Methanol oxidation on carbon-supported Pt-Sn electrodes in silicotungstic acid , 1994 .

[41]  J. Divisek,et al.  Process engineering of the direct methanol fuel cell , 2000 .

[42]  Klaus Wippermann,et al.  Experimental evaluation and semi-empirical modeling of U/I characteristics and methanol permeation of a direct methanol fuel cell , 2004 .

[43]  Musuwathi Krishnamoorthy Ravikumar,et al.  Effect of Methanol Crossover in a Liquid‐Feed Polymer‐Electrolyte Direct Methanol Fuel Cell , 1996 .

[44]  Keith Scott,et al.  A Numerical Model of a Liquid-Feed Solid Polymer Electrolyte DMFC and Its Experimental Validation , 2003 .

[45]  A. Kulikovsky,et al.  Analytical model of the anode side of DMFC: the effect of non-Tafel kinetics on cell performance , 2003 .

[46]  Keith Scott,et al.  An analysis of the influence of mass transfer on porous electrode performance , 2004 .

[47]  Hubert A. Gasteiger,et al.  Methanol electrooxidation on well-characterized Pt-Ru alloys , 1993 .

[48]  Antonino S. Aricò,et al.  DMFCs: From Fundamental Aspects to Technology Development , 2001 .

[49]  G. Lindbergh,et al.  Temperature-Dependent Kinetics of the Anode in the DMFC , 2004 .

[50]  Keith Scott,et al.  One-dimensional thermal model for direct methanol fuel cell stacks. Part I. Model development , 1999 .

[51]  K. Scott,et al.  A one dimensional model of a methanol fuel cell anode , 2004 .

[52]  Ulrike Krewer,et al.  Modelling, dynamics and control of a portable DMFC system , 2010 .

[53]  Joakim Nordlund,et al.  A Model for the Porous Direct Methanol Fuel Cells Anode , 2002 .

[54]  Jeremy P. Meyers,et al.  Simulation of the Direct Methanol Fuel Cell I. Thermodynamic Framework for a Multicomponent Membrane , 2002 .

[55]  Jian Zhang,et al.  Comparative investigation of the resistance to electrochemical oxidation of carbon black and carbon nanotubes in aqueous sulfuric acid solution , 2006 .

[56]  T. Springer,et al.  Polymer Electrolyte Fuel Cell Model , 1991 .

[57]  W. M. Taama,et al.  One-dimensional thermal model for direct methanol fuel cell stacks. Part II. Model based parametric analysis and predicted temperature profiles , 1999 .

[58]  Massimo Guarnieri,et al.  A Dynamic Circuit Model of a Small Direct Methanol Fuel Cell for Portable Electronic Devices , 2010, IEEE Transactions on Industrial Electronics.

[59]  Geping Yin,et al.  Durability studies of unsupported Pt cathodic catalyst with working time of direct methanol fuel cells , 2008 .

[60]  Mark W. Verbrugge,et al.  A Mathematical Model of the Solid‐Polymer‐Electrolyte Fuel Cell , 1992 .

[61]  Keith Scott,et al.  Modelling Transport Phenomena and Performance of Direct Methanol Fuel Cell Stacks , 2000 .

[62]  David Jollie,et al.  Report: 2004 Fuel Cell Seminar , 2005 .

[63]  Keith Scott,et al.  Performance and modelling of a direct methanol solid polymer electrolyte fuel cell , 1997 .

[64]  Siti Kartom Kamarudin,et al.  Overview on the challenges and developments of micro-direct methanol fuel cells (DMFC) , 2007 .

[65]  Jeremy P. Meyers,et al.  Simulation of the Direct Methanol Fuel Cell II. Modeling and Data Analysis of Transport and Kinetic Phenomena , 2002 .

[66]  Keith Scott,et al.  A current distribution model of a porous fuel cell electrode , 2004 .

[67]  Peter Enoksson,et al.  A micro direct methanol fuel cell demonstrator , 2004 .

[68]  Klaus Gärtner,et al.  Performance Modeling of a Direct Methanol Fuel Cell , 2003 .

[69]  Keith Scott,et al.  The degree and effect of methanol crossover in the direct methanol fuel cell , 1998 .

[70]  Eugene S. Smotkin,et al.  Methanol crossover in direct methanol fuel cells: a link between power and energy density , 2002 .

[71]  Keith Scott,et al.  A solid-polymer electrolyte direct methanol fuel cell with a mixed reactant and air anode , 2002 .

[72]  Dietmar Gerteisen,et al.  Transient and steady-state analysis of catalyst poisoning and mixed potential formation in direct methanol fuel cells , 2010 .

[73]  A. Kulikovsky Model of a Direct Methanol Fuel Cell Stack Resistive “Spots” and Stack Performance , 2006 .

[74]  A. Vahidi,et al.  A review of the main parameters influencing long-term performance and durability of PEM fuel cells , 2008 .

[75]  Mehdi Dargahi,et al.  Using Maximum Power Capability of Fuel Cell in Direct Methanol Fuel Cell / Battery Hybrid Power System , 2009 .

[76]  K. Scott,et al.  Effect of dispersion methods of an unsupported Pt-Ru black anode catalyst on the power performance of a direct methanol fuel cell , 2006 .

[77]  J. Newman,et al.  Theoretical Analysis of Current Distribution in Porous Electrodes , 1962 .

[78]  Hyunchul Ju,et al.  A global transient, one-dimensional, two-phase model for direct methanol fuel cells (DMFCs) – Part II: Analysis of the time-dependent thermal behavior of DMFCs , 2010 .

[79]  Chao-Yang Wang,et al.  Mathematical Modeling of Liquid-Feed Direct Methanol Fuel Cells , 2003 .

[80]  E. Gonzalez,et al.  Methanol electro-oxidation on gas diffusion electrodes prepared with PtRu/C catalysts , 2002 .

[81]  Jing Zhang,et al.  Transient behavior analysis of a new designed passive direct methanol fuel cell fed with highly conc , 2011 .

[82]  Kai Sundmacher,et al.  Dynamics of the direct methanol fuel cell (DMFC): experiments and model-based analysis , 2001 .

[83]  A. Kulikovsky A method for analysis of DMFC performance curves , 2003 .

[84]  Keith Scott,et al.  Dynamic response of the direct methanol fuel cell under variable load conditions , 2000 .

[85]  Jiujun Zhang,et al.  Electrocatalysis of Direct Methanol Fuel Cells , 2009 .

[86]  Alexandra M.F.R. Pinto,et al.  A comparative study of approaches to direct methanol fuel cells modelling , 2007 .

[87]  Keith Scott,et al.  An improved-performance liquid-feed solid-polymer-electrolyte direct methanol fuel cell operating at near-ambient conditions , 2002 .

[88]  D. Candusso,et al.  A review on polymer electrolyte membrane fuel cell catalyst degradation and starvation issues: Causes, consequences and diagnostic for mitigation , 2009 .

[89]  Hou-Chin Cha,et al.  Investigation on the durability of direct methanol fuel cells , 2009 .

[90]  J. Weidner,et al.  Review of Direct Methanol Fuel Cells , 2007 .

[91]  Jiujun Zhang,et al.  A review of polymer electrolyte membranes for direct methanol fuel cells , 2007 .

[92]  Roger Dougal,et al.  Mathematical Model of a Direct Methanol Fuel Cell , 2004, 2003.04083.

[93]  K. Sundmacher,et al.  Impedance spectroscopic analysis of the electrochemical methanol oxidation kinetics , 2006 .

[94]  John Davey,et al.  Recent advances in direct methanol fuel cells at Los Alamos National Laboratory , 2000 .

[95]  A. Simoglou,et al.  Dynamic modelling of the voltage response of direct methanol fuel cells and stacks Part I: Model development and validation , 2001 .

[96]  K. Scott,et al.  Analysis of the kinetics of methanol oxidation in a porous Pt–Ru anode , 2010 .

[97]  Keith Scott,et al.  Electrochemical and gas evolution characteristics of direct methanol fuel cells with stainless steel mesh flow beds , 2001 .

[98]  Subbarao Surampudi,et al.  Advances in direct oxidation methanol fuel cells , 1994 .

[99]  Pertti Kauranen,et al.  Kinetics of methanol oxidation on carbon-supported Pt and Pt + Ru catalysts , 1996 .

[100]  J. Meyers,et al.  Miniature fuel cells for portable power: Design considerations and challenges , 2002 .

[101]  A. Simoglou,et al.  Dynamic modelling of the voltage response of direct methanol fuel cells and stacks Part II: Feasibility study of model-based scale-up and scale-down , 2001 .

[102]  Keith Scott,et al.  A semi-empirical model of the direct methanol fuel cell performance. Part I. Model development and verification , 2003 .

[103]  Umit B. Demirci,et al.  Direct liquid-feed fuel cells: Thermodynamic and environmental concerns , 2007 .

[104]  K. Scott,et al.  The Influence of Mass Transfer on a Porous Fuel Cell Electrode , 2004 .

[105]  Chao-Yang Wang,et al.  Computational Fluid Dynamics Modeling of Proton Exchange Membrane Fuel Cells , 2000 .

[106]  A. Faghri,et al.  Mass transport analysis of a passive vapor-feed direct methanol fuel cell , 2010 .

[107]  In-Hwan Oh,et al.  Recent progress in passive direct methanol fuel cells at KIST , 2004 .

[108]  N. Munichandraiah,et al.  A potentiometric method of monitoring methanol crossover through polymer electrolyte membranes of direct methanol fuel cells , 2003 .

[109]  Jinsheng Xiao,et al.  Characteristics of droplet and film water motion in the flow channels of polymer electrolyte membrane fuel cells , 2006 .

[110]  Geping Yin,et al.  Investigation of the performance decay of anodic PtRu catalyst with working time of direct methanol fuel cells , 2008 .

[111]  A. A. Kulikovsky,et al.  Two-dimensional numerical modelling of a direct methanol fuel cell , 2000 .

[112]  Wenpeng Liu,et al.  Modeling water transport in liquid feed direct methanol fuel cells , 2007 .

[113]  P. Kauranen,et al.  Mixed methanol oxidation/oxygen reduction currents on a carbon supported Pt catalyst , 1996 .

[114]  Ya-Ling He,et al.  Non-isothermal modeling of direct methanol fuel cell , 2010 .

[115]  Masatoshi Nomura,et al.  Development of multi-layered microreactor with methanol reformer for small PEMFC , 2005 .

[116]  S. Srinivasan,et al.  International activities in DMFC R&D: status of technologies and potential applications , 2004 .

[117]  Karl V. Kordesch,et al.  Fuel cells and their applications , 1996 .

[118]  Siti Kartom Kamarudin,et al.  Unsteady-state modelling for a passive liquid-feed DMFC , 2009 .

[119]  Ralph E. White,et al.  Methanol Fuel Cell Model: Anode , 1999 .

[120]  Huamin Zhang,et al.  Novel electrode structure for DMFC operated with liquid methanol , 2006 .

[121]  A. Appleby The Electrochemical Engine for Vehicles , 1999 .

[122]  Angelika Heinzel,et al.  A review of the state-of-the-art of the methanol crossover in direct methanol fuel cells , 1999 .