Enhancement of spectral response of visible light absorption of TiO2 synthesis by femtosecond laser ablation

In this study, we report a simple, precise, and nano-scale fabrication technique for oxide nanosphere structure rutile (TiO2) using couple hundred of femtosecond laser irradiation at MHz pulse repetition frequency in air at atmospheric pressure. Measured reflectance's through Spectroradiometer show that their couplings of incident electromagnetic irradiations are improved greatly over the broad band wavelength range. Lower reflectance intensity obtained with long dwell time is due to generate bulk quantity of TiO2 oxide nanoparticle agglomerate by fusion, and form interweaving fibrous structures that show certain degree of assembly. The X-ray diffraction test confirmed that the oxide titanium metallic nanostructure is a rutile phase (TiO2). The growth of TiO2 nanostructure is highly recommended for the applications of dye-sensitized solar cells and photovoltaic applications.

[1]  J. Downing,et al.  Room-temperature preparation of nanocrystalline TiO2 films and the influence of surface properties on dye-sensitized solar energy conversion. , 2006, The journal of physical chemistry. B.

[2]  S. Sugihara,et al.  Preparation of a visible-light-active TiO2 photocatalyst by RF plasma treatment , 2001 .

[3]  Shen-Ming Chen,et al.  Electrochemical synthesis and characterization of TiO2 nanoparticles and their use as a platform for flavin adenine dinucleotide immobilization and efficient electrocatalysis , 2008, Nanotechnology.

[4]  A. Santagata,et al.  Femtosecond pulsed laser ablation and deposition of titanium carbide , 2006 .

[5]  F. A. Grant Properties of Rutile (Titanium Dioxide) , 1959 .

[6]  Hikasa Transverse-polarization effects in e+e- collisions: The role of chiral symmetry. , 1986, Physical review. D, Particles and fields.

[7]  W. Choi,et al.  Photocatalytic reactivity of surface platinized TiO2: substrate specificity and the effect of Pt oxidation state. , 2005, The journal of physical chemistry. B.

[8]  Koji Takeuchi,et al.  Role of oxygen vacancy in the plasma-treated TiO2 photocatalyst with visible light activity for NO removal , 2000 .

[9]  S. Rodrigues,et al.  Structural defects cause TiO2-based photocatalysts to be active in visible light. , 2004, Chemical communications.

[10]  Takayuki Kitamura,et al.  Influence of TiO2 Nanoparticle Size on Electron Diffusion and Recombination in Dye-Sensitized TiO2 Solar Cells , 2003 .

[11]  R. Sonawane,et al.  Sol-gel synthesis of Au/TiO2 thin films for photocatalytic degradation of phenol in sunlight , 2006 .

[12]  M. Grätzel,et al.  A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films , 1991, Nature.

[13]  T. Lian,et al.  Effect of Trap States on Interfacial Electron Transfer between Molecular Absorbates and Semiconductor Nanoparticles , 2002 .

[14]  A. L. Patterson The Scherrer Formula for X-Ray Particle Size Determination , 1939 .

[15]  A. Atkinson Transport processes during the growth of oxide films at elevated temperature , 1985 .

[16]  Sarah Kurtz,et al.  A two junction, four terminal photovoltaic device for enhanced light to electric power conversion using a low-cost dichroic mirror , 2009 .

[17]  H. Nakano,et al.  Synthesis of TiO2 nanocrystals controlled by means of the size of magnetic elements and the level of doping with them , 2009, Journal of Physics: Condensed Matter.