Nanorecycling: Monolithic Integration of Copper and Copper Oxide Nanowire Network Electrode through Selective Reversible Photothermochemical Reduction

Laser induced selective photothermochemical reduction is demonstrated to locally and reversibly control the oxidation state of Cu and Cu oxide nanowires in ambient conditions without any inert gas environment. This new concept of "nanorecycling" can monolithically integrate Cu and Cu oxide nanowires by restoring oxidized Cu, considered unusable for the electrode, back to a metallic state for repetitive reuse.

[1]  F. Zaera Nanostructured materials for applications in heterogeneous catalysis. , 2013, Chemical Society reviews.

[2]  A. El Mel,et al.  Highly ordered hollow oxide nanostructures: the Kirkendall effect at the nanoscale. , 2013, Small.

[3]  M. El‐Kady,et al.  Laser Scribing of High-Performance and Flexible Graphene-Based Electrochemical Capacitors , 2012, Science.

[4]  B. Beaudoin,et al.  Homogeneous and heterogeneous nucleations in the polyol process for the preparation of micron and submicron size metal particles , 1989 .

[5]  Daeho Lee,et al.  Vacuum-free, maskless patterning of Ni electrodes by laser reductive sintering of NiO nanoparticle ink and its application to transparent conductors. , 2014, ACS nano.

[6]  B. Wiley,et al.  Solution-processed copper-nickel nanowire anodes for organic solar cells. , 2014, Nanoscale.

[7]  B. Wiley,et al.  Optically transparent hydrogen evolution catalysts made from networks of copper–platinum core–shell nanowires , 2014 .

[8]  G. Račiukaitis,et al.  Reduction of graphite oxide to graphene with laser irradiation , 2013 .

[9]  Yonggang Huang,et al.  Materials and Mechanics for Stretchable Electronics , 2010, Science.

[10]  Daihua Zhang,et al.  Transparent, conductive, and flexible carbon nanotube films and their application in organic light-emitting diodes. , 2006 .

[11]  G. Whitesides,et al.  Self-Assembly at All Scales , 2002, Science.

[12]  B. Blin,et al.  Oxydation duplicative de l'éthylène glycol dans un nouveau procédé de préparation de poudres métalliques , 1989 .

[13]  Chanseok Lee,et al.  Ultrasensitive mechanical crack-based sensor inspired by the spider sensory system , 2014, Nature.

[14]  B. Wiley,et al.  Metal Nanowire Networks: The Next Generation of Transparent Conductors , 2014, Advanced materials.

[15]  Ha Beom Lee,et al.  Room‐Temperature Nanosoldering of a Very Long Metal Nanowire Network by Conducting‐Polymer‐Assisted Joining for a Flexible Touch‐Panel Application , 2013 .

[16]  V. R. Raju,et al.  Paper-like electronic displays: Large-area rubber-stamped plastic sheets of electronics and microencapsulated electrophoretic inks , 2001, Proceedings of the National Academy of Sciences of the United States of America.

[17]  B. Wiley,et al.  The Synthesis and Coating of Long, Thin Copper Nanowires to Make Flexible, Transparent Conducting Films on Plastic Substrates , 2011, Advanced materials.

[18]  M. Abdel Rafea,et al.  Determination of the optical band gap for amorphous and nanocrystalline copper oxide thin films prepared by SILAR technique , 2009 .

[19]  Seung Hwan Ko,et al.  Fast Plasmonic Laser Nanowelding for a Cu‐Nanowire Percolation Network for Flexible Transparent Conductors and Stretchable Electronics , 2014, Advanced materials.

[20]  Benjamin J Wiley,et al.  The Growth Mechanism of Copper Nanowires and Their Properties in Flexible, Transparent Conducting Films , 2010, Advanced materials.

[21]  Costas P. Grigoropoulos,et al.  Laser-Induced Reductive Sintering of Nickel Oxide Nanoparticles under Ambient Conditions , 2015 .

[22]  Ja Hoon Koo,et al.  Highly Skin‐Conformal Microhairy Sensor for Pulse Signal Amplification , 2014, Advanced materials.

[23]  S. Asher,et al.  Polymerized colloidal crystal hydrogel films as intelligent chemical sensing materials , 1997, Nature.

[24]  Liang Li,et al.  Core/Shell semiconductor nanocrystals. , 2009, Small.

[25]  S. Ko,et al.  One-Step Fabrication of Copper Electrode by Laser-Induced Direct Local Reduction and Agglomeration of Copper Oxide Nanoparticle , 2011 .

[26]  Suk Won Cha,et al.  Performance enhancement in bendable fuel cell using highly conductive Ag nanowires , 2014 .