Fabrication and study of lignocellulosic Hibiscus sabdariffa fiber reinforced polymer composites

Fabrication of polymer composites reinforced with lignocellulosic materials has increased considerably during the last few years. This work reports the synthesis of natural fiber reinforced phenol-formaldehyde (PF) resin matrix based polymer composite using a compression molding technique. Initially the PF resin was prepared by varying the concentration of formaldehyde with a fixed weight of phenol. Polymeric resin of different P: F ratios were subjected for optimization of their mechanical properties. The sample ratio of 1:1.5 (P: F) was found to possess maximum mechanical strength. Then reinforcing of this optimized resin was done by taking different ratios of Hibiscus Sabdariffa (HS) fiber in short form (3mm) to prepare green polymer composites. Polymer composite materials thus prepared were subjected to evaluation of their mechanical properties such as tensile strength, compressive strength, flexural strength, and wear resistance, etc. Optimum mechanical properties were obtained with a fibre loading of 30%.Thermal (TGA/DTA/DTG) and morphological studies (SEM) of the polymeric resin, and composites thus synthesized have also been studied. The results obtained suggest that these fibers can be a superior candidate for the reinforcement of high performance polymer composites.

[1]  B. Adhikari,et al.  The effect of grass fiber filler on curing characteristics and mechanical properties of natural rubber , 2004 .

[2]  I. Mondragon,et al.  Influence of the initial formaldehyde to phenol molar ratio (F/P) on the formation of a phenolic resol resin catalyzed with amine , 2000 .

[3]  A. Błędzki,et al.  Thermoplastics Reinforced with Wood Fillers: A Literature Review , 1998 .

[4]  Sabu Thomas,et al.  Dynamical mechanical analysis of sisal/oil palm hybrid fiber‐reinforced natural rubber composites , 2006 .

[5]  V. Thakur,et al.  FABRICATION OF HIBISCUS SABDARIFFA FIBRE REINFORCED POLYMER COMPOSITES , 2008 .

[6]  Sabu Thomas,et al.  Influence of interfacial adhesion on the mechanical properties and fracture behaviour of short sisal fibre reinforced polymer composites , 1996 .

[7]  A. Błędzki,et al.  Composites reinforced with cellulose based fibres , 1999 .

[8]  S. Kalia,et al.  Mercerization of Flax Fiber Improves the Mechanical Properties of Fiber-Reinforced Composites , 2008 .

[9]  M Sain,et al.  Preparation and characterization of wheat straw fibers for reinforcing application in injection molded thermoplastic composites. , 2006, Bioresource technology.

[10]  Andrzej K. Bledzki,et al.  Properties and modification methods for vegetable fibers for natural fiber composites , 1996 .

[11]  J. Jog,et al.  Natural fiber polymer composites: A review , 1999 .

[12]  Balbir Singh Kaith,et al.  Evaluation of optimum grafting parameters and the effect of ceric ion initiated grafting of methyl methacrylate on to jute fibre on the kinetics of thermal degradation and swelling behaviour , 2000 .

[13]  V. Thakur,et al.  Saccaharum Cilliare Fiber Reinforced Polymer Composites , 2008 .

[14]  V. Thakur,et al.  Pressure induced graft-co-polymerization of acrylonitrile onto Saccharum cilliare fibre and evaluation of some properties of grafted fibre , 2008 .

[15]  Hiroyuki Yano,et al.  The effect of morphological changes from pulp fiber towards nano-scale fibrillated cellulose on the mechanical properties of high-strength plant fiber based composites , 2004 .

[16]  K. Oksman,et al.  Mechanical properties and morphology of flax fiber reinforced melamine-formaldehyde composites , 2001 .

[17]  P. Grenier,et al.  Phenolic resins: 2. Influence of catalyst type on reaction mechanisms and kinetics , 1996 .