Hard red winter wheat (1.4 t) at 11.1 or 13.5% moisture content (wet basis) and 20, 25, or 30 degrees C was fumigated with tablets of an aluminum phosphide formulation in unsealed, cylindrical grain bins of corrugated metal. The fumigant leakage rate was manipulated to approximate that commonly encountered in farm and commercial-scale bins of this type. Phosphine concentration profiles were recorded and phosphine loss and sorption were characterized to determine which conditions provided the greatest probability of successful fumigation in these bins. Phosphine leakage and sorption were both positively related to grain temperature and moisture content. The fumigant concentration profiles were compared with previously-published data relating temperature to the developmental rate and fumigant susceptibility of lesser grain borer eggs, which are phosphine-resistant but become less resistant as they age. The mean phosphine concentration observed at the time corresponding to one-half of the calculated egg development time was compared to the lethal concentration (LC(99)) for a 2-day exposure at each temperature-moisture combination. In the low-moisture grain at 20 degrees C, the observed fumigant concentration was below the lethal concentration, due to the long development time under these conditions. At 25 and 30 degrees C in the low-moisture wheat, the likelihood of complete kill appeared more favorable because the fumigant concentration remained above the published LC(99) for more than half of the egg development time. In the wheat with 13.5% moisture content, rapid fumigant sorption and loss resulted in phosphine concentrations below the LC(99) at one-half of the development time at 20 or 25 degrees C. At 30 degrees C, due to the very rapid development rate, the observed phosphine concentration exceeded the LC(99) half-way through the egg development period despite the rapid rate of fumigant sorption and loss. Repeated fumigation of the same grain reduced the rate at which phosphine sorbed into the grain.
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