Integrating LIBS LIF Raman into a single multi-spectroscopic mobile device for in situ cultural heritage analysis

Heritage science aims to study cultural heritage objects through the developing and studying conservation issues to advise new restauration approach. In addition, the development of new tools is one of the major accesses, which allows to increase knowledge in archaeology and to characterize the materials. This paper is focused on the development of a Laser-Induced Breakdown Spectroscopy-Laser-Induced Fluorescence-Raman Spectroscopy (LIBS-LIF-Raman) portable instrument for supporting conservation campaigns when extensive measurements and on-site decision-making in cultural heritage. Such a multi-analytical prototype instrument is able to combine these three laser-based spectroscopic techniques to simultaneously provide complementary elemental and molecular information from the same analysis point. To that purpose, different laser sources, appropriate optics and detection modules have to be examined in order to integrate them on a mobile platform.

[1]  R. Cubeddu,et al.  Excitation emission and time-resolved fluorescence spectroscopy of selected varnishes used in historical musical instruments. , 2009, Talanta.

[2]  Ludovica Ruggiero,et al.  Characterization and Discrimination of Plastic Materials Using Laser-Induced Fluorescence , 2016, Applied spectroscopy.

[3]  Vincent Detalle,et al.  Laser-induced emission, fluorescence and Raman hybrid setup: A versatile instrument to analyze materials from cultural heritage , 2018 .

[4]  R. Fort,et al.  Laser-induced fluorescence and FT-Raman spectroscopy for characterizing patinas on stone substrates , 2012, Analytical and Bioanalytical Chemistry.

[5]  Rinaldo Cubeddu,et al.  Total synchronous fluorescence spectroscopy combined with multivariate analysis: method for the classification of selected resins, oils, and protein-based media used in paintings. , 2009, Analytical chemistry.

[6]  Qingyu Lin,et al.  Combined Laser-Induced Breakdown with Raman Spectroscopy: Historical Technology Development and Recent Applications , 2013 .

[7]  Nicoló Omenetto,et al.  Laser-Induced Breakdown Spectroscopy (LIBS), Part II: Review of Instrumental and Methodological Approaches to Material Analysis and Applications to Different Fields , 2012, Applied spectroscopy.

[8]  Costanza Miliani,et al.  Fluorescence spectroscopy: a powerful technique for the noninvasive characterization of artwork. , 2010, Accounts of chemical research.

[9]  Greg S. Mungas,et al.  Study of sub-mJ-excited laser-induced plasma combined with Raman spectroscopy under Mars atmosphere-simulated conditions , 2007 .

[10]  M. Oujja,et al.  Multianalytical characterization of Late Roman glasses including nanosecond and femtosecond laser induced breakdown spectroscopy , 2015 .

[11]  V. Detalle,et al.  Cultural Heritage Applications of LIBS , 2014 .

[12]  Demetrios Anglos,et al.  A multi-technique approach, based on mobile/portable laser instruments, for the in situ pigment characterization of stone sculptures on the island of Crete dating from Venetian and Ottoman period , 2016, Heritage Science.

[13]  Vincenzo Palleschi,et al.  Characterization of azurite and lazurite based pigments by laser induced breakdown spectroscopy and micro-Raman spectroscopy , 2001 .

[14]  D. Anglos,et al.  Portable laser-induced breakdown spectroscopy/diffuse reflectance hybrid spectrometer for analysis of inorganic pigments , 2017 .

[15]  I. Osticioli,et al.  Spectroscopic analysis of works of art using a single LIBS and pulsed Raman setup , 2009, Analytical and bioanalytical chemistry.

[16]  S. Musazzi,et al.  Laser-Induced Breakdown Spectroscopy , 2014 .

[17]  Shiv k. Sharma,et al.  Remote Raman and fluorescence studies of mineral samples. , 2005, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[18]  C. D'Andrea,et al.  Advanced non-invasive fluorescence spectroscopy and imaging for mapping photo-oxidative degradation in acrylonitrile–butadiene–styrene: A study of model samples and of an object from the 1960s , 2014 .

[19]  Demetrios Anglos,et al.  Laser-Induced Breakdown Spectroscopy in Art and Archaeology , 2001 .

[20]  Demetrios Anglos,et al.  Laser spectroscopies for elemental and molecular analysis in art and archaeology , 2012 .

[21]  Demetrios Anglos,et al.  Spectroscopic analysis using a hybrid LIBS-Raman system , 2006 .

[22]  Taesam Kim,et al.  Laser-Induced Breakdown Spectroscopy , 2012 .

[23]  Aseefhali Bankapur,et al.  A hybrid LIBS–Raman system combined with chemometrics: an efficient tool for plastic identification and sorting , 2017, Analytical and Bioanalytical Chemistry.

[24]  Angela Zoppi,et al.  A new compact instrument for Raman, laser-induced breakdown, and laser-induced fluorescence spectroscopy of works of art and their constituent materials. , 2009, The Review of scientific instruments.

[25]  Luc Moens,et al.  A Decade of Raman Spectroscopy in Art and Archaeology , 2007 .

[26]  Demetrios Anglos,et al.  The application of LIBS for the analysis of archaeological ceramic and metal artifacts , 2002 .

[27]  I. Osticioli,et al.  Analysis of natural and artificial ultramarine blue pigments using laser induced breakdown and pulsed Raman spectroscopy, statistical analysis and light microscopy. , 2009, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.

[28]  A. M. Pollard,et al.  INDUCTIVELY COUPLED PLASMA-MASS SPECTROMETRY FOR THE ANALYSIS OF ANCIENT METALS* , 1997 .

[29]  E. García-Ruiz,et al.  Laser ablation-inductively coupled plasma mass spectrometry in archaeometric research. , 2009, Mass spectrometry reviews.

[30]  V. Detalle,et al.  Chemometrics and Laser Induced Breakdown Spectroscopy (LIBS) Analyses for Identification of Wall Paintings Pigments , 2010 .

[31]  L. Ancillotti,et al.  A combined Raman-LIBS spectrometer: toward a mobile atomic and molecular analytical tool for in situ applications , 2005, Advanced Laser Technologies.

[32]  Vincent Detalle,et al.  An example of the complementarity of laser‐induced breakdown spectroscopy and Raman microscopy for wall painting pigments analysis , 2007 .

[33]  Sylvain Grégoire.  Etude et optimisation de la méthode LIBS (Laser Induced Breakdown Spectroscopy) pour l'identification de matériaux organiques appliquée au recyclage des plastiques et à la conservation du patrimoine , 2013 .

[34]  Demetrios Anglos,et al.  Pigment Identification in Painted Artworks: A Dual Analytical Approach Employing Laser-Induced Breakdown Spectroscopy and Raman Microscopy , 2000 .

[35]  M. Oujja,et al.  Analysis of heritage stones and model wall paintings by pulsed laser excitation of Raman, laser-induced fluorescence and laser-induced breakdown spectroscopy signals with a hybrid system , 2018, Journal of Cultural Heritage.

[36]  B. Gratuze,et al.  Mass spectrometry with laser sampling: A new tool to characterize archaeological materials , 2001 .

[37]  V. Detalle,et al.  Influence of ns-laser wavelength in laser-induced breakdown spectroscopy for discrimination of painting techniques , 2017, 1904.00584.

[38]  GENTNER - A Miniaturised LIBS/Raman Instrument for the Comprehensive In Situ Analysis of the Martian Surface , 2006 .

[39]  Jidong Lu,et al.  Elucidation of C 2 and CN formation mechanisms in laser-induced plasmas through correlation analysis of carbon isotopic ratio , 2014 .

[40]  J. Laserna,et al.  Vibrational emission analysis of the CN molecules in laser-induced breakdown spectroscopy of organic compounds , 2013 .

[41]  D. Cremers,et al.  Handbook of Laser-Induced Breakdown Spectroscopy: Cremers/Handbook of Laser-induced Breakdown Spectroscopy , 2006 .

[42]  Barry Lienert,et al.  Pulsed remote Raman system for daytime measurements of mineral spectra. , 2005, Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy.