Impedance Acquisition of Proton Exchange Membrane Fuel Cell Using Deeper Learning Network

Electrochemical impedance is a powerful technique for elucidating the multi-scale polarization process of the proton exchange membrane (PEM) fuel cell from a frequency domain perspective. It is advantageous to acquire frequency impedance depicting dynamic losses from signals measured by the vehicular sensor without resorting to costly impedance measurement devices. Based on this, the impedance data can be leveraged to assess the fuel cell’s internal state and optimize system control. In this paper, a residual network (ResNet) with strong feature extraction capabilities is applied, for the first time, to estimate characteristic frequency impedance based on eight measurable signals of the vehicle fuel cell system. Specifically, the 2500 Hz high-frequency impedance (HFR) representing proton transfer loss and 10 Hz low-frequency impedance (LFR) representing charge transfer loss are selected. Based on the established dataset, the mean absolute percentage errors (MAPEs) of HFR and LFR of ResNet are 0.802% and 1.386%, respectively, representing a superior performance to other commonly used regression and deep learning models. Furthermore, the proposed framework is validated under different noise levels, and the findings demonstrate that ResNet can attain HFR and LFR estimation with MAPEs of 0.911% and 1.610%, respectively, even in 40 dB of noise interference. Finally, the impact of varying operating conditions on impedance estimation is examined.

[1]  H. Eichlseder,et al.  Experimental Investigation of the Influence of NO on a PEM Fuel Cell System and Voltage Recovery Strategies , 2023, Energies.

[2]  Haifeng Dai,et al.  Advanced Online Broadband Impedance Spectrum Acquisition of Fuel Cells by S-Transform , 2023, IEEE Transactions on Industrial Electronics.

[3]  Fengchun Sun,et al.  Simultaneous prediction of impedance spectra and state for lithium-ion batteries from short-term pulses , 2023, Electrochimica Acta.

[4]  Q. Meyer,et al.  Operando monitoring of the evolution of triple-phase boundaries in proton exchange membrane fuel cells , 2023, Journal of Power Sources.

[5]  Yunhong Che,et al.  Battery impedance spectrum prediction from partial charging voltage curve by machine learning , 2023, Journal of Energy Chemistry.

[6]  Xinjie Xu,et al.  A Closed-Loop Water Management Methodology for PEM Fuel Cell System Based on Impedance Information Feedback , 2022, Energies.

[7]  Haifeng Dai,et al.  A new insight into the effects of agglomerate parameters on internal dynamics of proton exchange membrane fuel cell by an advanced impedance dimension model , 2022, Energy.

[8]  Fengxiang Chen,et al.  Humidity estimation of vehicle proton exchange membrane fuel cell under variable operating temperature based on adaptive sliding mode observation , 2022, Applied Energy.

[9]  Jaeyeon Kim,et al.  Observation of flooding-induced performance enhancement in PEMFCs , 2021, International Journal of Hydrogen Energy.

[10]  Haifeng Dai,et al.  Quantitative analysis of internal polarization dynamics for polymer electrolyte membrane fuel cell by distribution of relaxation times of impedance , 2021 .

[11]  Haifeng Dai,et al.  Understanding dynamic behavior of proton exchange membrane fuel cell in the view of internal dynamics based on impedance , 2021, Chemical Engineering Journal.

[12]  H. Ju,et al.  Impedance modeling for polymer electrolyte membrane fuel cells by combining the transient two-phase fuel cell and equivalent electric circuit models , 2021, Energy.

[13]  Xuezhe Wei,et al.  Online impedance spectrum measurement of fuel cells based on Morlet wavelet transform , 2021, International Journal of Hydrogen Energy.

[14]  Xuezhe Wei,et al.  A fuzzy extend state observer-based cascade decoupling controller of air supply for vehicular fuel cell system , 2021 .

[15]  Ming Cong,et al.  Impedance prediction model based on convolutional neural networks methodology for proton exchange membrane fuel cell , 2021 .

[16]  Haifeng Dai,et al.  Internal polarization process revelation of electrochemical impedance spectroscopy of proton exchange membrane fuel cell by an impedance dimension model and distribution of relaxation times , 2021 .

[17]  Levent Burak Kara,et al.  Prediction of high frequency resistance in polymer electrolyte membrane fuel cells using long short term memory based model , 2021, Energy and AI.

[18]  D. Beretta,et al.  Study of the impact of reactants utilization on the performance of PEMFC commercial stacks by impedance spectroscopy , 2021 .

[19]  Daniel Hissel,et al.  A review of DC/DC converter-based electrochemical impedance spectroscopy for fuel cell electric vehicles , 2019, Renewable Energy.

[20]  Chizhou Yan,et al.  On-line fault diagnosis for proton exchange membrane fuel cells based on a fast electrochemical impedance spectroscopy measurement , 2019, Journal of Power Sources.

[21]  P. Pei,et al.  Diagnosis of water failures in proton exchange membrane fuel cell with zero-phase ohmic resistance and fixed-low-frequency impedance , 2019, Applied Energy.

[22]  S. Jakubek,et al.  Online estimation of the electrochemical impedance of polymer electrolyte membrane fuel cells using broad-band current excitation , 2018, Journal of Power Sources.

[23]  Ellen Ivers-Tiffée,et al.  Advanced impedance study of polymer electrolyte membrane single cells by means of distribution of relaxation times , 2018, Journal of Power Sources.

[24]  Raghunathan Rengaswamy,et al.  Rapid impedance measurement using chirp signals for electrochemical system analysis , 2017, Comput. Chem. Eng..

[25]  Samuel Simon Araya,et al.  An EIS alternative for impedance measurement of a high temperature PEM fuel cell stack based on current pulse injection , 2017 .

[26]  Zhi Wen,et al.  Liquid water transport characteristics of porous diffusion media in polymer electrolyte membrane fuel cells: A review , 2015 .

[27]  Xueguan Song,et al.  Numerical analysis of the optimum membrane/ionomer water content of PEMFCs: The interaction of Nafion® ionomer content and cathode relative humidity , 2015 .

[28]  Janko Petrovčič,et al.  Fast measurement of proton exchange membrane fuel cell impedance based on pseudo-random binary sequence perturbation signals and continuous wavelet transform , 2014 .

[29]  Jaeyeon Kim,et al.  Real-time detection of flooding in polymer electrolyte membrane fuel cells using high-frequency electrochemical impedance , 2023, Journal of Power Sources.

[30]  Jian Chen,et al.  Adaptive Condition Monitoring for Fuel Cells Based on Fast EIS and Two-Frequency Impedance Measurements , 2023, IEEE Transactions on Industrial Electronics.

[31]  Tiancai Ma,et al.  Stack shut-down strategy optimisation of proton exchange membrane fuel cell with the segment stack technology , 2020 .